Guidance on labelling and packaging in accordance with

G U I D A N C E

Guidance on labelling and packaging in

accordance with Regulation (EC) No 1272/2008

Version 4.2

March 2021

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Legal Notice

This document aims to assist users in complying with their obligations under the CLP

Regulation. However, users are reminded that the text of the CLP Regulation is the only

authentic legal reference and that the information in this document does not constitute

legal advice. Usage of the information remains under the sole responsibility of the user.

The European Chemicals Agency does not accept any liability with regard to the use that

may be made of the information contained in this document.

Guidance on labelling and packaging in accordance with Regulation (EC) No

1272/2008

Reference: ECHA-21-G-02-EN

Catalogue Number: ED-03-21-082-EN-N

ISBN: 978-92-9481-834-8

DOI: 10.2823/697587

Publication date: March 2021

Language: EN

If you have questions or comments in relation to this document please, send them

(quote the reference and issue date) using the information request form. The

information request form can be accessed via the Contact ECHA page at:

https://echa.europa.eu/contact

European Chemicals Agency

Mailing address: P.O. Box 400, FI-00121 Helsinki, Finland

Visiting address: Annankatu 18, Helsinki, Finland

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Document History

Version

Changes

Date

Version 1.0

(originally

unnumbered)

First edition

April 2011

Version 2.0

Full revision of the guidance addressing the content and structure.

Main changes in the guidance document include the following:

• Alignment with the 4

Adaptation to Technical Progress

(ATP) to the CLP Regulation (Commission Regulation (EU)

No 487/2013) bringing the CLP in line with the 4

revised

edition of the UN Globally Harmonised System (GHS);

• Addressing the provisions of the 5

ATP to the CLP

Regulation (Commission Regulation (EU) No 944/2013)

amending precautionary statement P210 to fully align it

with the changes arising from the 5

Revision of the UN

GHS;

• Addition of new section 3.5.1 on child-resistant fastening

(CRF) and tactile warnings of danger (TWD);

• Addition of new section 3.5.2 including information on

additional safety measures for liquid laundry detergents in

soluble capsules adopted by the Commission through

Regulation (EU) No 1297/2014;

• Addition of new sections 4.2.1 and 4.2.2 clarifying the

provisions of CLP Article 18(3) with regard to product

identifiers for substances and mixtures;

• Re-organisation of information in section 4.3 by inclusion of

new sections 4.3.1, 4.3.2, 4.3.3;

• Addition of new section 4.3.4 describing the issue of blank

pictograms;

• Re-organisation and clarification of information on

supplemental labelling in section 4.8 by inclusion of new

sections 4.8.1 and 4.8.2;

• Inclusion of clarification on the issue of “readability” and

“minimum letter size” in section 5.2;

• Re-organisation and update of the text in section 5.3 to

reflect the provisions of CLP Article 29 and sections 1.5.1

and 1.5.2 of Annex I to CLP;

• Inclusion of information on general and specific

requirements for fold-out labels in section 5.3.1.1;

• Section 6: Update of the labels and the text in examples in

line with the provisions of the 4

and 5

ATPs to CLP;

• Deletion of Example 6.6 (Single language label of a plant

protection product for supply & use in form of a fold-out

booklet);

• Inclusion of new Example 6 (fold-out label for a mixture

supplied to the general public);

September

2016

Guidance on Labelling and Packaging

Version 4.2 – March 2021

• Addition of section 6.1 separating the examples of labels on

packagings that are small or difficult to label;

• Addition of a new section 6.1 describing labelling of two-

component products;

• Clarification and extension of the text in section 7.2;

• Section 7.3: Update of the precautionary statements in

selection tables according to the provisions of the 4

and

ATPs to CLP;

• Section 7.4: Update of the practical examples in line with

the provisions of the 4

and 5

ATPs to CLP;

• Deletion of the outdated references to past deadlines and

to the DSD and DPD provisions thorough the whole

document;

• Alignment of the document with the latest ECHA corporate

image requirements.

Version 3.0

Full revision of the guidance. Main changes in the guidance

document include the following:

• Alignment with the 8

Adaptation to Technical Progress

(ATP) to the CLP Regulation (Commission Regulation (EU)

2016/918);

• Addition of a new section 5.4.2 clarifying the issue of

packaging used for consolidation of supply packaging

during transport;

• Update of the precautionary statements according to the

provisions of 8

ATP (section 6, section 7.3 and section

7.4).

July 2017

Version 4.0

Full revision of the guidance. Main changes in the guidance

document include the following:

• Alignment with Commission Regulation (EU) 2017/542,

which amends the CLP Regulation by adding an Annex on

harmonised information relating to emergency health

response;

• Addition of a new section 6.2 describing the labelling of

multi-component products with label examples;

• Deletion of the outdated paragraph “Limited derogation for

re-labelling and re-packaging” in Section 2.4 and deletion

of outdated section 3.4 on the “Differences between CLP

and DSD/DPD labelling rules”;

• Editorial changes and reformatting of the document;

• “Preamble” renamed “Preface” and moved before the table

of contents;

• Update of broken and outdated hyperlinks;

• Renumbering of sections, tables and figures.

March 2019

Version 4.1

Update via fast track to implement the amendment of the legal text

May 2020

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Preface

This document describes specific provisions for the labelling and packaging of chemical

substances and mixtures under Titles III and IV of the Regulation (EC) No 1272/2008

(the CLP Regulation or “CLP”). The aim of this document is to assist manufacturers,

importers, downstream users and distributors of substances and mixtures in the effective

application of the CLP Regulation.

This guidance includes relevant amendments from the 2

, 4

, 5

and 8

Adaptations to

Technical Progress (ATPs) to the CLP Regulation, as well as the changes brought about

by the ATP to the CLP Regulation related to labelling and packaging of liquid laundry

detergents in a soluble packaging for single use (Regulation (EU) No 1297/2014).

This document also includes relevant changes introduced by Commission Regulation (EU)

2017/542, which amends the CLP Regulation by adding Annex VIII on harmonised

information relating to emergency health response.

All current ECHA guidance documents are available on the ECHA website at:

https://echa.europa.eu/support/guidance.

Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December

2008 on classification, labelling and packaging of substances and mixtures, amending and

repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006;

OJ L 353 31.12.2008, p. 1 (http://eur-lex.europa.eu/legal-

content/en/TXT/?uri=CELEX%3A02008R1272-20150601)

due to Commission Delegated Regulation 2020/11 of 29 October

2019. In particular:

• Clarification of labelling requirements with regards to the

UFI code in standard situations (in section 4.8.1.1);

• Clarification of labelling requirements with regards to the

UFI code in particular cases of fold-out labels, tie-on tags

or outer packaging (section 5.3.1);

• Minor changes and clarification in the labelling examples

concerning mixtures (section 6).

Version 4.2

Update to implement the amendment of the legal text due to

Commission Delegated Regulation 2020/1677 and Commission

Delegated Regulation 2020/1676 of 31 August 2020 (the

“workability amendments”) and limited to:

• Clarification of exemption from labelling requirements for

bespoke paints (new section 5.3.3);

• New example of application of the labelling requirements

for a bespoke paint (new section 6.3);

Minor changes and clarification in the rest of the document.

March 2021


Guidance on Labelling and Packaging 
Version 4.2 – March 2021  
 
Table of Contents 
PREFACE ............................................................................................................................ 5 
INTRODUCTION ....................................................................................................... 10 
1 Who should read this document?................................................................................ 10 
2 What is in this document? ............................................................................................. 10 
GENERAL OVERVIEW ............................................................................................. 11 
1 Legal background .............................................................................................................. 11 
2 Scope of labelling and packaging under the CLP Regulation .......................... 12 
3 Derogations from labelling requirements for special cases ............................. 13 
4 Timelines for classification, labelling, packaging and updating of CLP 
hazard labels ............................................................................................................................... 13 
REQUIREMENTS OF LABELLING AND PACKAGING IN ACCORDANCE 
WITH THE CLP REGULATION ................................................................................... 14 
1 General labelling rules ..................................................................................................... 14 
2 Elements of the CLP hazard label ............................................................................... 14 
3 Location of information on the CLP hazard label.................................................. 15 
4 CLP rules on packaging of substances and mixtures .......................................... 17 
4.1 Child-resistant fastening and tactile warnings of danger ......................................... 18 
4.2 Liquid consumer laundry detergents in soluble packaging for single use.......... 21 
RULES FOR THE APPLICATION OF THE CLP LABEL ELEMENTS ............... 23 
1 Contact details of the supplier ..................................................................................... 23 
2 Product identifiers ............................................................................................................. 23 
2.1 Substances .................................................................................................................................. 23 
2.2 Mixtures ........................................................................................................................................ 25 
3 Hazard pictograms ............................................................................................................ 27 
3.1 General information ................................................................................................................. 27 
3.2 Shape, colour and dimensions ............................................................................................. 27 
3.3 Precedence rules ....................................................................................................................... 28 
3.4 Blank pictograms ...................................................................................................................... 29 
4 Signal words ........................................................................................................................ 30 
5 Hazard statements ............................................................................................................ 30 
6 Precautionary statements .............................................................................................. 32 
7 Codes for hazard and precautionary statements ................................................. 33 
8 Supplemental labelling information ........................................................................... 33 
8.1 Obligatory supplemental labelling information ............................................................ 34 
8.1.1 Unique formula identifier (UFI) ............................................................................................................. 40 
8.2 Non-obligatory supplemental labelling information ................................................... 43 
GUIDANCE ON PARTICULAR ASPECTS OF CLP HAZARD LABELLING .... 43 
1 Further aspects to consider for the CLP hazard label ......................................... 43 
2 Size of the label and of the label elements ............................................................. 44 
3 Exemptions from the labelling and packaging requirements .......................... 46 

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5.3.1 Use of fold-out labels, tie-on tags and outer packaging ........................................... 46 
5.3.1.1 Fold-out labels and tie-on tags ............................................................................................................. 47 
5.3.1.2 Outer packaging ...................................................................................................................................... 50 
5.3.2 Omission of certain label elements.................................................................................... 50 
5.3.2.1 Labelling of packages when the contents do not exceed 125 ml .................................................... 50 
5.3.2.2 Labelling of soluble packaging for single use which does not exceed a volume of 25 ml........... 52 
5.3.2.3 Labelling of inner packaging when the contents do not exceed 10 ml .......................................... 52 
5.3.2.4 Unpackaged hazardous substances or mixtures supplied to the general public .......................... 52 
5.3.2.5 Environmental labelling .......................................................................................................................... 53 
5.3.3 Labelling exemptions for bespoke paints ........................................................................ 53 
5.4 Interaction between the CLP and the transport labelling rules ..................... 54 
5.4.1 Specific rules for labelling of outer packaging, inner packaging and single 
packaging ................................................................................................................................................ 54 
5.4.2 Packaging used for consolidation of supply packaging during transport ........... 55 
6. EXAMPLE LABELS .................................................................................................... 58 
Example 1: Single language label for a substance (not for the general public)
 .......................................................................................................................................................... 58 
Example 2: Multi-language label for a substance containing non-obligatory 
supplemental information (not for the general public) ............................................ 60 
Example 3: Single language label for a mixture containing both obligatory 
and non-obligatory supplemental information (supplied to the general public)
 .......................................................................................................................................................... 62 
Example 4: Single language label for a substance containing supplemental 
hazard statements (not for the general public) ........................................................... 64 
Example 5: Multi-language label for a mixture containing both obligatory and 
non-obligatory supplemental information (supplied to the general public) .... 65 
Example 6: Fold-out label for a mixture (supplied to the general public) ........ 67 
6.1 Packaging that is small or difficult to label ............................................................ 70 
Example 7: Substance in a 8 ml bottle (not for the general public) ................................ 70 
Example 8: Hazardous solid substance in a 100 ml bottle (not intended for the 
general public) ...................................................................................................................................... 72 
Example 9: Supply and transport label for a single package (not intended for the 
general public) ...................................................................................................................................... 74 
Example 10: Labelling for a mixture that is transported on land in outer and inner 
packaging (not intended for the general public) ..................................................................... 76 
Example 11: Labelling for a mixture that is transported on land in single packaging 
(not intended for the general public) ........................................................................................... 77 
6.2 Specific case: labelling of two-component products .......................................... 79 
Example 12: Labelling of a two-component adhesive sold as a kit .................................. 79 
Example 13: Labelling of a co-axial cartridge ........................................................................... 80 
6.3 Specific case: labelling of a bespoke paint ............................................................. 83 
Example 14: Labelling of a bespoke paint where colours are added on a tailor-made 
basis at the point of sale ................................................................................................................... 83 
7. GUIDANCE ON THE SELECTION OF PRECAUTIONARY STATEMENTS FOR 
THE CLP HAZARD LABEL ............................................................................................ 84 
7.1 Introduction ......................................................................................................................... 84 
7.2 Methodology ........................................................................................................................ 85 
7.3 Selection tables .................................................................................................................. 88 
7.3.1 General precautionary statements .................................................................................... 90 
7.3.2 Specific precautionary statements for physical hazards ........................................... 91 
7.3.2.1 Explosives ................................................................................................................................................. 91 
7.3.2.1 Explosives (continued) ........................................................................................................................... 93 


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3.2.1 Explosives (continued) ........................................................................................................................... 96 
3.2.1 Explosives (continued) ........................................................................................................................... 98 
3.2.2 Flammable gases (including chemically unstable gases) ............................................................... 101 
3.2.2 Flammable gases (including chemically unstable gases) (continued) .......................................... 102 
3.2.3 Aerosols .................................................................................................................................................. 103 
3.2.3 Aerosols (continued) ............................................................................................................................. 104 
3.2.4 Oxidising gases ...................................................................................................................................... 105 
3.2.5 Gases under pressure ........................................................................................................................... 106 
3.2.5 Gases under pressure (continued) ..................................................................................................... 107 
3.2.6 Flammable liquids ................................................................................................................................. 108 
3.2.7 Flammable solids ................................................................................................................................... 111 
3.2.8 Self-reactive substances and mixtures .............................................................................................. 113 
3.2.8 Self-reactive substances and mixtures (continued) ........................................................................ 115 
3.2.8 Self-reactive substances and mixtures (continued) ........................................................................ 117 
3.2.9 Pyrophoric liquids .................................................................................................................................. 119 
3.2.10 Pyrophoric solids ................................................................................................................................. 121 
3.2.11 Self-heating substances and mixtures ............................................................................................ 123 
3.2.12 Substances and mixtures which, in contact with water, emit flammable gases ...................... 124 
3.2.12 Substances and mixtures which, in contact with water, emit flammable gases (continued) 126 
3.2.13 Oxidising liquids .................................................................................................................................. 127 
3.2.13 Oxidising liquids (continued) ............................................................................................................. 129 
3.2.14 Oxidising solids .................................................................................................................................... 130 
3.2.14 Oxidising solids (continued) .............................................................................................................. 131 
3.2.15 Organic peroxides ............................................................................................................................... 132 
3.2.15 Organic peroxides (continued) ......................................................................................................... 134 
3.2.15 Organic peroxides (continued) ......................................................................................................... 136 
3.2.16 Corrosive to metals............................................................................................................................. 138 
3.3 Specific precautionary statements for health hazards............................................. 139 
3.3.1 Acute Toxicity – Oral ............................................................................................................................ 139 
3.3.1 Acute Toxicity – Oral (continued) ....................................................................................................... 141 
3.3.1 Acute Toxicity – Dermal ....................................................................................................................... 142 
3.3.1 Acute Toxicity – Dermal (continued) ................................................................................................. 144 
3.3.1 Acute Toxicity – Dermal (continued) ................................................................................................. 146 
3.3.1 Acute Toxicity - Inhalation ................................................................................................................... 148 
3.3.1 Acute Toxicity – Inhalation (continued) ............................................................................................ 150 
3.3.1 Acute Toxicity – Inhalation (continued) ............................................................................................ 151 
3.3.2 Skin corrosion/irritation ....................................................................................................................... 152 
3.3.2 Skin corrosion/irritation (continued) .................................................................................................. 155 
3.3.3 Serious eye damage - only .................................................................................................................. 157 
3.3.3 Eye irritation – only .............................................................................................................................. 158 
3.3.4 Respiratory sensitisation ...................................................................................................................... 159 
3.3.4 Skin sensitisation .................................................................................................................................. 160 
3.3.5 Germ cell mutagenicity ........................................................................................................................ 162 
3.3.6 Carcinogenicity ...................................................................................................................................... 164 
3.3.7 Reproductive toxicity ............................................................................................................................ 166 
3.3.7 Reproductive toxicity (continued) ...................................................................................................... 168 
3.3.8 Specific target organ toxicity after single exposure ........................................................................ 170 
3.3.8 Specific target organ toxicity after single exposure (continued) .................................................. 172 
3.3.8 Specific target organ toxicity after single exposure (continued) .................................................. 174 
3.3.9 Specific target organ toxicity after repeated exposure ................................................................... 175 
3.3.9 Specific target organ toxicity after repeated exposure (continued) ............................................. 177 
3.3.10 Aspiration hazard ................................................................................................................................ 178 
3.4 Specific precautionary statements for environmental hazards ............................ 179 
3.4.1 Hazardous to the aquatic environment – short-term (acute) aquatic hazard ............................ 179 
3.4.1 Hazardous to the aquatic environment – long-term (chronic) aquatic hazard ........................... 180 
3.4.1 Hazardous to the aquatic environment – long-term (chronic) aquatic hazard (continued) ..... 181 
3.5 Additional hazards.................................................................................................................. 182 
3.5.1 Hazardous to the ozone layer ...................................................................................................... 182 
4. Examples for the selection of precautionary statements for the label .... 183 
Example A. Substance X assigned a physical and various health hazard 
classifications ...................................................................................................................................... 183 
Example B. Substance Y assigned a severe physical and health hazard classification
 .................................................................................................................................................................. 185 
Example C. Substance Z assigned physical, health and environmental classifications
 .................................................................................................................................................................. 186 
Example D. Mixture ABC for use by the general public ....................................................... 189 

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APPENDIX: GLOSSARY OF SELECTED TERMS USED IN THIS GUIDANCE 
DOCUMENT ................................................................................................................... 191 
 
Table of Figures 
Figure 1: Blackened out empty diamonds ............................................................... 30 
Figure 2: Readability ........................................................................................... 45 
Figure 3: Decision flowchart for the application of CLP and transport labelling for single 
packaging (left) and combination packaging (right) ................................................. 55 
Figure 4: Application of CLP labelling on packaging used for supply and transport ....... 56 
 
Table of Tables 
Table 1: CLP labelling requirements versus discretion of the supplier ......................... 16 
Table  2:  The  hazard  classifications  that  trigger  the  CLP  provisions  for  child-resistant 
fastenings and/or tactile warnings ......................................................................... 20 
Table 3: Substances that directly trigger the CLP provisions for child-resistant fastenings 
and/or tactile warnings when they are contained in other substances or in mixtures at or 
above the denoted concentration .......................................................................... 21 
Table 4:  Code ranges of hazard and precautionary statements under the CLP Regulation
......................................................................................................................... 33 
Table 5: Obligatory supplemental labelling information pursuant to CLP Articles 25 and 32
......................................................................................................................... 36 
Table 6: Minimum dimensions of labels and pictograms under the CLP Regulation ....... 44 
Table 7: Labelling exemptions for packages of a capacity of 125 ml or less ................ 51 
 
 
 
 
 
 
 
 
 
 
 

Guidance on Labelling and Packaging

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1. Introduction

1.1 Who should read this document?

This document is relevant for suppliers of chemical substances and mixtures, namely for:

• manufacturers and importers of substances;

• importers of mixtures;

• downstream users of substances and mixtures, including formulators;

• distributors of substances and mixtures, including retailers.

All suppliers must ensure that their substances and mixtures are labelled and packaged

in accordance with the provisions of the CLP Regulation (or CLP) before they are placed

on the EU market.

1.2 What is in this document?

This document provides guidance on the labelling and packaging requirements of

substances and mixtures set out in the CLP Regulation. The guidance opens in section 2

with a general overview, including legal background, scope of the CLP Regulation and

updating of CLP labels. That section also includes information about timelines for

classification, labelling, packaging and updating of CLP labels. The guidance continues in

section 3 and section 4 with an explanation of the requirements for labelling and

packaging and rules for the application of the CLP label elements. Section 5 provides

guidance on particular aspects of CLP hazard labelling (e.g. exemption from certain

labelling and packaging requirements, interaction between the CLP and transport

labelling rules, labelling requirements for specific cases of unique packaging). Finally,

section 6 and section 7 of the guidance provide practical examples illustrating different

situations that may be encountered when designing labels.

In particular, this guidance aims to clarify:

• what aspects to consider when estimating the label size needed;

• what types of supplemental information are possible, and where to place this

information on the label (section 4.8 of this guidance document);

• the conditions for small packaging exemptions;

• the interaction between CLP and the transport labelling rules;

• the technical requirements for liquid laundry detergents in a soluble packaging for

single use;

• how to select the most appropriate set of precautionary statements for the

label;

• how to structure the information on the label for appropriate readability.

For specific information on the application of the CLP criteria for physical, health and

environmental hazards, the reader is advised to consult the Guidance on the application

of the CLP criteria. For a general overview of basic features and procedures laid down in

the CLP Regulation, it might be useful to consult the Introductory Guidance on the CLP

Regulation.

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Note: All ECHA Guidance documents referred to in this document are available in the

support pages of the ECHA website at https://echa.europa.eu/guidance-

documents/guidance-on-clp

2. General overview

2.1 Legal background

The CLP Regulation is the EU Regulation on classification, labelling and packaging of

substances and mixtures. It is based on the United Nations Globally Harmonized System

of Classification and Labelling of chemicals (UN GHS). The CLP Regulation entered into

force on 20 January 2009 in the European Union and is now legally binding also in the

countries of the European Economic Area (EEA) (Norway, Iceland and Liechtenstein)

The CLP Regulation replaced the provisions of the Dangerous Substances Directive

67/548/EEC (DSD) and the Dangerous Preparations Directive 1999/45/EC (DPD) as of 1

June 2015 (see section 2.4 of this guidance document). The CLP Regulation is directly

applicable to suppliers in the EU who manufacture, import, use or distribute chemical

substances and mixtures.

This guidance explains the labelling and packaging rules of CLP and illustrates with

some examples how labels could be laid out.

In general, the CLP label must display certain label elements taken over from UN GHS,

including hazard pictogram(s), signal word, hazard and precautionary statements along

with supplemental information, where applicable, which reflect the assigned classification

of the substance or mixture. At the same time, the CLP Regulation retains some of the

labelling concepts of the DSD and DPD, such as the small packaging exemptions. In

order to accommodate certain hazard information not yet covered by the UN GHS, as

well as further label elements that are required by other EU legislation, the CLP

Regulation introduces the concept of “supplemental information” for the label.

All supplied substances and mixtures classified as hazardous and contained in a

packaging must be labelled in accordance with Title III (Hazard communication in the

form of labelling) and their packaging must be in accordance with Title IV (Packaging) of

the CLP Regulation.

In addition to the label, another key tool for hazard communication, intended for

professional/industrial users only, is the safety data sheet (SDS). The required SDS

format and content are defined in Article 31 and Annex II

to Regulation (EC) No

1907/2006 (REACH Regulation). These have been adapted to align them with the UN

GHS, as well as to be fully in line with the CLP Regulation. The information provided on

The CLP Regulation was incorporated in the EEA Agreement by Decision of the EEA Joint

Committee No 106/2012 of 15 June 2012 amending Annex II (Technical regulations, standards,

testing and certification) to the EEA Agreement (OJ L 309, 8.11.2012, p. 6–6).

Commission Regulations No 453/2010 and No 2015/830 have amended the REACH Regulation by

replacing Annex II to the REACH Regulation with the annexes to these regulations, to align the

requirements for safety data sheets with the rules for safety data sheets of the UN GHS, see:

http://www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html.

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the hazard label and in Section 2.2 of the SDS, for the same substance or mixture, must

be consistent

For further information on the compilation of the SDS, please consult the Guidance on

the compilation of safety data sheets.

2.2 Scope of labelling and packaging under the CLP Regulation

In general, substances and mixtures that are placed on the market are supplied in a

packaging with the necessary labelling information. A substance or mixture has to be

labelled according to the CLP rules where

• the substance or mixture is classified as hazardous;

• the mixture, even if not classified as hazardous, is addressed in CLP Article 25(6).

In this case the supplemental label elements as set out in Part 2 of Annex II to

CLP must be indicated together with the product identifier, name and telephone

number of the supplier.

In addition, an explosive article (i.e. an article containing one or more explosive

substances or mixtures) that meets the criteria as described in section 2.1 of Annex I to

CLP must be labelled according to the CLP rules.

Substances and mixtures within the scope of Regulation (EC) No 1107/2009

(Plant

Protection Products Regulation or PPPR) or Regulation (EU) No 528/2012 (Biocidal

Products Regulation or BPR) have to carry CLP labelling elements as appropriate.

Substances and mixtures within the scope of the PPPR also need to display the

supplemental statement EUH401 ‘To avoid risks to human health and the environment,

comply with the instructions for use’ (see CLP Article 25(2)). However, the labelling

provisions of these acts remain fully applicable to any product within their respective

scope (see Recital 47 of the CLP Regulation). For example, there are separate provisions

for updating labels for such substances and mixtures in these acts, and their suppliers

must apply these provisions instead of the CLP rules (see also CLP Article 30(3)).

Another deviation from the CLP Regulation is that different rules apply as to which

information may be presented in the form of a leaflet as an alternative way to

accommodate the required labelling information (see section 5.3.1.1 of this guidance

document).

The CLP Regulation also includes exemptions from labelling and packaging requirements,

for example for a packaging that is so small, or in such a shape that it is impossible to

meet the general rules for the application of labels (see section 5.3.1 of this guidance

document). In addition, the CLP Regulation allows suppliers to omit certain label

elements (see section 5.3.2 of this guidance document).

Certain substances and mixtures may also be supplied to the general public without

packaging, in which case a copy of the label elements is required to accompany the

substance or mixture, for example on an invoice. Currently, this only applies to

Note that there is no default requirement to place the Unique Formula Identifier (UFI) in the SDS

(except for unpackaged mixtures). When relevant, the UFI is to be included in Section 1.1 of the

SDS. For further details on UFI, please see section 4.8.1.1 of this guidance document.

Regulation (EC) No 1107/2009 of the European Parliament and of the Council of 21 October

2009 concerning the placing of plant protection products on the market repeals Council

Directives 79/117/EEC and 91/414/EEC with effect from 14 June 2011. However, Article 80 of

Regulation (EC) No 1107/2009 specifies that Directive 91/414/EEC must continue to apply with

respect to active substances included in Annex I to that Directive for certain transitional periods.

Guidance on Labelling and Packaging

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substances listed in Part 5 of Annex II to CLP (see section 5.3.2.4 of this guidance

document).

2.3 Derogations from labelling requirements for special cases

The CLP Regulation defines derogations from the CLP labelling requirements for special

cases and the conditions under which these derogations apply. One example of such a

special case is metals in massive form. CLP Article 23(d) provides that, in specific

cases, exemptions from the labelling requirements apply to: “metals in massive form,

alloys, mixtures containing polymers, mixtures containing elastomers”.

Section 1.3.4.1 of Annex I to CLP elaborates further on CLP Article 23 and gives

conditions when labelling is not required, namely: “if they do not present a hazard to

human health by inhalation, ingestion or contact with skin or to the aquatic environment

in the form in which they are placed on the market”.

The CLP legal text does not specify when a form of metal should be considered massive.

A default particle size limit cannot be specified to determine whether or not CLP Article

23 applies to any metal.

To apply the exemption from the labelling provisions, the manufacturer or supplier must

be able to demonstrate the lack of hazard in the form the metal or alloy is placed on the

market. Section 2.1 of the SDS must contain the classification of the metal and

information on the application of the labelling exemption for the form as placed on the

market.

In relation to the other cases described in CLP Article 23, please consult the Article and

section 1.3 of Annex I to CLP, as further guidance on these is not provided in this

document.

Another special case is that of bespoke paints. Annex VIII and Article 25(8) of CLP

provide for special provisions with regard to the Unique Formula Identifier (UFI) for

bespoke paints. More details are provided in sections 4.8.1.1 and 5.3.3.

2.4 Timelines for classification, labelling, packaging and updating

of CLP hazard labels

The CLP Regulation was introduced gradually before its full application as of 1 June

2015. During this transitional period, some of the rules of the CLP Regulation and the

previous legislation (DSD and DPD) were applicable in parallel to give companies time to

migrate to the CLP rules. However, companies were allowed to apply the CLP Regulation

in full on a voluntary basis, from its entry into force.

For substances, it has been obligatory to classify, label and package according to the CLP

Regulation since 1 December 2010. The same obligations have applied for mixtures since

1 June 2015. The transitional period for mixtures classified, labelled and packaged

according to DPD and already placed on the market before 1 June 2015 ended on 1 June

2017.

DSD and DPD are no longer applicable in any context and both substances

and mixtures must now be classified, labelled and packaged in accordance

with the CLP Regulation. This classification must be provided in the SDS for

substances and mixtures. There is no longer a requirement to provide either DSD

classifications of substances themselves or of component substances in mixtures or

the DPD classifications for mixtures in the SDS. Only the corresponding information

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Following any changes to the classification and labelling where the revised classification

is more severe or where new supplemental label elements are required, CLP Article 30

requires a supplier to update this information on the label without undue delay, i.e. as

soon as reasonably practicable.

Where labelling changes other than those described above are required (e.g. where the

revised classification will be less severe or the contact details of the supplier have

changed) the supplier has 18 months to update the label.

Where a new or updated harmonised classification arises from an Adaptation to Technical

Progress (ATP) to the CLP Regulation, the ATP provides the date of applicability.

Further label changes to be implemented within 18 months would also include the

update of labelling information for certain mixtures for which special rules for

supplemental labelling in accordance with Part 2 of Annex II to CLP apply.

However, there are separate provisions for updating labels in the BPR and the PPPR and

suppliers of substances or mixtures within the scope of these acts must apply these

provisions.

3. Requirements of labelling and packaging in

accordance with the CLP Regulation

3.1 General labelling rules

General and specific rules regarding the content and application of a CLP label are set

out in CLP Article 31.

The CLP Regulation requires that the labels are firmly affixed to one or more surfaces of

the immediate container of the substance or mixture and that they must be readable

horizontally when the package is set down normally. The label elements themselves, in

particular the hazard pictograms, must stand out clearly from the background.

Furthermore, all label elements must be of such size and spacing as to be easily read.

They must be clearly and indelibly marked. A physical label is not required when the

label elements are shown clearly on the packaging itself.

3.2 Elements of the CLP hazard label

According to CLP Article 17, a substance and mixture classified as hazardous must bear a

label including the following elements:

• Name, address and telephone number of the supplier(s);

• The nominal quantity of the substance or mixture in the package where this is

being made available to the general public, unless this quantity is specified

elsewhere on the package;

• Product identifiers;

• Hazard pictograms, where applicable;

• The relevant signal word, where applicable;

• Hazard statements, where applicable;

according to the CLP Regulation need be provided (see also the Guidance on the

compilation of safety data sheets).

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• Appropriate precautionary statements where applicable;

• A section for supplemental information, where applicable.

According to Annex VIII to CLP

, a Unique Formula Identifier (UFI), if applicable, must

also be added to, i.e. printed on or affixed to, the label of mixtures falling under the

scope of CLP Article 45 and Annex VIII to CLP (see section 4.8.1.1 of this guidance

document).

It should be noted that for particular label elements precedence rules apply. These rules

are further explained in the sections below.

• The CLP Regulation requires the label to be written in the official language or

languages of the Member States where the substance or mixture is placed on the

market, unless the Member State concerned provides otherwise

. Suppliers may

accomplish this either by producing multi-language labels covering the official

languages of several of the countries where the substance or mixture is supplied,

or by producing separate labels for each country, each with the appropriate

language or languages.

Suppliers may use more languages than those required on their labels if they wish,

provided that the same details appear in all languages. However, this should not impact

the legibility of the obligatory labelling information, nor can it trigger exemptions from

the labelling requirements (see section 5.3.1 of this guidance document).

3.3 Location of information on the CLP hazard label

CLP Article 32 provides some limited rules that define the location of information on the

label. However, further details as to how label elements are arranged are left to the

discretion of the person responsible for compiling the label. As a general rule, the

information should be structured in a way that is easy to read and understand. Examples

are outlined in Table 1 below:

See Commission Regulation (EU) 2017/542.

Please consult the table “Languages required for labels and safety data sheets”, which is available

on the ECHA website web at: https://echa.europa.eu/regulations/clp/labelling.

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Table 1: CLP labelling requirements versus discretion of the supplier

CLP requirement (Article 32)

Example of decision left to the discretion

of the supplier

The hazard pictograms, signal word, hazard

statements and precautionary statements

must be kept together on the label.

The supplier is free to choose the

arrangement of the pictograms.

Hazard statements must be grouped together

on the label.

The supplier may choose the order of the

hazard statements.

The supplier may choose whether these

groups are to be presented on the left, on the

right or elsewhere on the label.

Precautionary statements must be grouped

together on the label.

The supplier may choose the order of the

precautionary statements, but should ensure

that they are grouped with the hazard

statements.

The supplier may choose whether these

groups are to be presented on the left, on the

right or elsewhere on the label.

In case more than one language is used on

the label, the hazard and precautionary

statements of the same language must be

grouped together on the label.

Where the supplier needs to use alternative

means to meet the requirements of CLP

Article 31 in relation to the language(s)

required in a particular Member State, he

may choose whether to accomplish this using

fold-out labels, tie-on tags or on an outer

packaging, in accordance with section 1.5.1 of

Annex I to CLP.

Any supplemental information as referred to

in CLP Article 25 must be included in the

section for supplemental labelling and placed

alongside the label elements referred to in

CLP Article 17(1)(a)–(g).

The supplier may choose how to visibly

separate this section from the section

containing the label elements referred to in

CLP Article 17(1)(a)-(g). He may also decide

to place this information in more than one

location on the label.

The label elements must be easily readable

(Article 31(3)).

It is recommended to keep full sentences

together and in one line, if possible. The font

size and spacing must be large enough and in

relation to the dimensions of the label.

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3.4 CLP rules on packaging of substances and mixtures

Before continuing to describe in more detail the CLP requirements for packaging, the

reader should be introduced to the three CLP definitions:

CLP Article 35 includes the requirements for packaging containing hazardous substances

or mixtures. These provisions are to ensure that:

• the packaging is designed, constructed and fastened so that the contents cannot

escape;

• the materials of the packaging and fastening are not damaged by the contents

and are not liable to form hazardous compounds with the contents;

• the packaging and fastenings are strong and solid throughout to ensure that they

will not loosen;

• packaging fitted with replaceable fastening devices is properly designed to allow

repeated refastening without the contents escaping;

• the packaging does not attract or arouse the curiosity of children or mislead the

consumer when supplied to the general public;

• the packaging does not have a similar presentation or a design used for foodstuff

or animal feed stuff or medicinal or cosmetic products which would mislead the

consumers.

Packaging that meets the requirements of the transport legislation is deemed to comply

with the requirements set out in the bullet points above (Note however that fulfilling the

conditions in the above bullet points alone is usually not enough to comply with the

requirements of the transport legislation).

For substances and mixtures to be supplied to the general public, the CLP Regulation

sets out rules for:

• the use of child-resistant fastening (CRF), also referred to as child-resistant

closure (see section 3.4.1 of this guidance document);

• the use of tactile warnings of danger (TWDs) (see section 3.4.1 of this guidance

document);

• liquid consumer laundry detergents in soluble packaging for single use (see

section 3.4.2 of this guidance document).

The first two provisions are triggered by either a specific hazard class/category or by the

concentration of specific substances contained in other substances or in mixtures (see

Tables 2 and 3 of this guidance document).

Article 2 (35): ‘package’ means the complete product of the packing operation,

consisting of the packaging and its contents;

Article 2 (36): ‘packaging’ means one or more receptacles and any other components

or materials necessary for the receptacles to perform their containment and other

safety functions;

Article 2 (37): ‘intermediate packaging’ means packaging placed between inner

packaging, or articles, and outer packaging;

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3.4.1 Child-resistant fastening and tactile warnings of danger

The provisions described in this section apply only for product packaging intended for the

general public, for example: products on sale/offer at a retailer’s or an outlet where the

general public have open access to them, products sold to the general public through a

website.

The requirements for CRF and TWD do not apply to product packaging which is for

professional users only.

Child-resistant fastening

A child-resistant package

is a package consisting of a container and an appropriate

closure which is difficult to open (or gain access to the contents) for young children

under the age of fifty-two months, but which is not difficult for adults to use properly

Annex II to CLP refers to two types of CRF for packages:

• non-reclosable package - a package that, when all or part of the contents have

been removed, cannot be properly closed again, for example a blister pack or air

freshener refills;

• reclosable package - a package (for example a one litre bottle or a five litre

container) that, after it has been initially opened, can be reclosed and re-used

numerous times without loss of security.

For fastening of the above-mentioned packages, Annex II to CLP requires conformity

with the following standards, as amended:

• EN ISO 8317 (reclosable packages), and

• CEN EN 862 (non-reclosable packages).

Conformity with these standards may only be certified by laboratories that conform to

EN ISO/IEC 17025, as amended. The EN ISO/IEC 17025 standard relates to the

competence of testing laboratories and the requirements that they must meet to

demonstrate that they are technically competent and can generate technically valid

results. In specific cases referred to in section 3.1.4.2 of Annex II to CLP, i.e. if it seems

obvious that packaging is sufficiently safe for children because they cannot get access to

the contents without the help of a tool, the above tests on non-reclosable and reclosable

packages do not need to be performed

A packaging of whatever capacity supplied to the general public must be fitted with CRF

for substances or mixtures:

• classified for acute toxicity 1-3 – oral (H300 and H301), dermal (H310 and H311)

or inhalation (H330 and H331); STOT-SE 1 (H370); STOT-RE 1 (H372); skin

corrosion 1, subcategories 1A, 1B, 1C (H314), or

• classified as presenting an aspiration hazard (H304), with the exception of

Please note that the terminology differs between the CLP legal text and the EN standard. The CLP

Regulation refers to packaging fitted with child-resistant fastening, whereas EN ISO 8317 refers to

child-resistant packages.

According to EN ISO 8317.

See also the Report on the Forum pilot project on Child-resistant fastenings.

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substances and mixtures that are placed on the market in the form of aerosols or

in a container fitted with a sealed spray attachment, or

• containing methanol at a concentration greater or equal to 3% or

dichloromethane at a concentration greater or equal to 1% (see also Table 3 of

this guidance document).

Tactile warnings of danger (TWDs)

Packages provided with a TWD enables blind or visually impaired people to ascertain if

the packages contains a hazardous substance or mixture. A TWD must be placed on the

packaging, so that it can be felt before accessing the contents. The warning must be

located in such a way that any other embossed patterns do not cause confusion. The

exact location of the TWD must be according to EN ISO standard 11683.

The TWD must also remain tactile during the expected period of use of the package

under normal handling conditions. The TWD is not required on outer packaging such as

for example a cardboard box protecting a glass bottle

Annex II to CLP requires the TWD to conform to standard EN ISO 11683, as amended.

The required standard TWD symbol (the “normal” symbol under the ISO standard) is an

equilateral triangle. In exceptional cases (if the application of the normal symbol is not

physically possible), the three dots symbol may be used. If it is not physically possible to

even use the three dots symbol, the three mm symbol may be used

A packaging of whatever capacity supplied to the general public must be fitted with TWD

for substances or mixtures classified for:

• acute toxicity 1-4 – oral (H300, H301 and H302), dermal (H310, H311 and

H312) or inhalation (H330, H331 and H332);

• skin corrosion 1, subcategories 1A, 1B and 1C (H314);

• germ cell mutagenicity 2 (H341);

• carcinogenicity 2 (H351);

• reproductive toxicity 2 (H361);

• respiratory sensitisation 1, 1A and 1B (H334);

• STOT SE 1 or 2 (H370, H371);

• STOT RE 1 or 2 (H372 and H373);

• aspiration hazard 1 (H304);

• flammable gases 1 and 2 (H220 and H221);

• flammable liquids 1 and 2 (H224 and H225); or

• flammable solids 1 and 2 (H228).

According to section 3.2.1.2 of Annex II to CLP, a TWD is not required for transportable

gas receptacles. A TWD is also not required for aerosols and containers fitted with a

According to EN ISO 11683.

The arrangement and layout of the triangle, three dots as well as the three mm symbol are

specified in EN ISO 11683.

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sealed spray attachment containing substances or mixtures classified as presenting an

aspiration hazard, unless they are classified for one or more of the other hazards

mentioned above.

Table 2 provides an overview of the hazard classifications triggering the CLP provisions

for CRF and/or TWD. Table 3 lists substances that can trigger the CLP provisions for CRF

and/or TWD if they are present in other substances or in mixtures at a certain

concentration.

Table 2: The hazard classifications that trigger the CLP provisions for child-

resistant fastenings and/or tactile warnings

Hazard Class, Category

Child-

resistant

Fastenings

Tactile

Warnings

Acute toxicity 1 to 3

✓

Acute toxicity 4

✓

STOT SE 1

✓

STOT SE 2

✓

STOT RE 1

✓

STOT RE 2

✓

Skin corrosion (category 1, subcategories: 1A, 1B and 1C)

✓

Respiratory sensitisation (category 1, subcategories: 1A and 1B)

✓

Aspiration hazard 1

Note that a CRF and TWD are not required if the substance or mixture

is supplied in the form of an aerosol or in a container fitted with a

sealed spray attachment and if the substance or mixture is not

classified for another hazard triggering CRF or TWD

✓

Germ cell mutagenicity 2

✓

Carcinogenicity 2

✓

Reproductive toxicity 2

✓

Flammable gases 1 and 2

✓

Flammable liquids 1 and 2

✓

Flammable solids 1 and 2

✓

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Table 3: Substances that directly trigger the CLP provisions for child-resistant

fastenings and/or tactile warnings when they are contained in other

substances or in mixtures at or above the denoted concentration

Identification of the substance

Concentration limit

Child-

resistant

Fastenings

Tactile

Warnings

Methanol

 3%

✓

✓*

Dichloromethane

 1%

✓

✓**

* It should be noted that above a certain concentration, methanol mixtures also need a tactile warning because

the mixtures would then have to be classified as flammable liquid category 2, STOT SE category 1 or 2.

** In addition, mixtures containing dichloromethane at a concentration above 1% would be classified as

carcinogenic category 2 and thereby need a tactile warning.

3.4.2 Liquid consumer laundry detergents in soluble packaging for

single use

Additional safety measures for liquid laundry detergents in soluble capsules are in place.

They aim to ensure better protection of the general public, especially young children who

can be tempted to put the capsules into their mouth.

These safety requirements make the packaging less attractive and more difficult to open

for children. In addition, the packaging is to display warnings to alert parents and child-

care providers that such products have to be kept out of reach of children.

Beside these specific rules, the supplier is responsible, according to CLP Article 35(2), for

taking all necessary steps to make sure that the design of the packaging is not attractive

to children, so that, for instance, it cannot be mistaken for foodstuff or toys.

A consumer laundry detergent is a detergent used for laundry, placed on the market for

use by non-professionals, including public launderettes

CLP Article 35(2) and section 3.3 of Annex II to CLP provide the following requirements

on packaging and labelling of liquid laundry detergents in dosages for single use

contained in a soluble packaging:

Obligation to market liquid consumer laundry detergents in an outer packaging

Liquid consumer laundry detergents contained in soluble packaging for single use (for

example liquid capsules or liquitabs for use in washing machines) must be contained in

an outer packaging. Failure to do so is considered as non-compliant with CLP Article

35(1) and section 3.3.1 of Annex II to CLP.

Provisions on the outer packaging

In order to reduce the attractiveness to children of liquid consumer laundry detergents

contained in soluble packaging for single use, the outer packaging must be opaque or

obscure (for example non-see through container of a block colour(s)) to prevent visibility

of the contents, i.e. the product or individual doses.

The outer packaging must bear precautionary statement P102 (“Keep out of reach of

children”) at a visible place and in a format that attracts attention.

Article 2(1a) of Regulation (EC) No 648/2004 on detergents.

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Furthermore, the outer packaging must be a self-standing container that is easily re-

closable, i.e. the pack closure must be easily re-closable in one single movement (for

example with one finger pressure for a tub packaging). This measure aims to avoid the

risk that the container will simply be left open if closing is too difficult.

As the main cause of incidents seems to be the easy access to the detergent capsules,

the outer packaging must be fitted with a closure that impedes the ability of young

children to open the packaging. Such a closure should require a coordinated action of

both hands with a certain strength that makes it difficult for young children to open it. It

should be noted that this requirement does not necessarily correspond with the closure

requirement for CRF described in section 3.4.1 of this guidance document.

In addition, the pack closure must be designed for repeated use to maintain its

functionality under conditions of repeated opening and closing for the entire life span of

the outer packaging.

Provisions on the soluble (inner) packaging

Additional technical requirements (mechanical resistance and water dissolution) were

introduced to make the soluble packaging more resistant.

In addition to the requirements for the outer packaging, the soluble packaging must

contain an aversive (e.g. bittering or other repulsive) agent against oral exposure. The

aversive agent must be added in a concentration that is safe and that causes oral

repulsive behaviour within a maximum time of six seconds.

The soluble film must also meet minimum mechanical and dissolution resistance criteria.

It must retain the liquid content for at least 30 seconds when placed in water at 20°C. It

must also resist mechanical compression of at least 300 N under standard test

conditions.

Soluble packaging for single use with a volume of contents equal to 25 ml or less may

benefit from a labelling exemption under the conditions specified in section 1.5.2.2 of

Annex I to CLP (see section 5.3.2.2 of this guidance document); the labelling

requirements of CLP Article 17 apply to soluble packaging where the volume of

contents is more than 25 ml.

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4. Rules for the application of the CLP label elements

4.1 Contact details of the supplier

According to CLP Article 17, the contact details of one or several suppliers must be

included on the label. In principle, there can be more than one supplier of the same

substance or mixture in the supply chain, e.g. in case a mixture has been supplied by

the formulator to a distributor who would supply it to third parties as well. However, CLP

Article 17 does not specify whether the contact details of both suppliers are needed in

such cases. Nor does it specify whether the contact details of one particular supplier

have precedence.

Following from CLP Article 4(4), each supplier must ensure that a hazardous substance

or mixture is labelled and packaged in accordance with Titles III and IV of the CLP

Regulation before it is placed on the market. On the way through the supply chain the

labelling for the same substance or mixture may vary depending on the volume of the

package or as a consequence of further layers of packaging (see section 5.2, section 5.3

and section 5.4 of this guidance document).

Where a supplier changes the packaging so that the label elements set out in CLP Article

17 have to be displayed differently than on the label/packaging supplied to him, they

take the responsibility for re-packaging and re-labelling and should add their own name

and contact information on the label. In this case, the supplier may also replace the

contact information of their supplier with their own contact details.

When the supplier does not change the packaging, they do not need to add their contact

details to the label or replace the contact information of their supplier with their own

contact details. They may do so if they wish to. In case the supplier changes the

languages(s) displayed on a label, they should add their contact details to the contact

details of the relevant supplier who issued the original label, as they are then responsible

for the correct translation of the label content.

4.2 Product identifiers

This section provides guidance on the requirements for the product identifiers for

substances (CLP Article 18(2)) and mixtures (CLP Article 18(3)). As a general rule, the

same product identifier(s) as selected for the label must be used in the SDS

for a

substance or mixture. Any product identifiers selected for the label must be written in

the official language(s) of the Member State(s) where the substance or mixture is placed

on the market, unless the Member State concerned provides otherwise (see CLP Article

17(2)).

4.2.1 Substances

The product identifier for a substance must consist of at least the following:

• a name and an identification number as given in Part 3 of Annex VI to CLP

For further information, please consult the Guidance on the compilation of safety data sheets.

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The name can be any of the names stated as International Chemical Identification

in column 2 of the tables in Part 3 of Annex VI to CLP

. The identification number

is typically the Index number, the EC number or the CAS number. It is

recommended to use the number that warrants an unambiguous identification of

the substance; in some cases it may be warranted to use two numbers, e.g. the

CAS and the EC number. When translating the name of an Annex VI substance

into the required language(s), it may be useful to check whether an appropriate

translation is already available in a public database, for example in ECHA’s

Classification and Labelling (C&L) Inventory (see

https://echa.europa.eu/information-on-chemicals/cl-inventory-database). If there

is a translated name available in Annex VI to CLP or in the C&L Inventory, this

name should be given preference; or

• if the substance is not included in Part 3 of Annex VI to CLP, a name and an

identification number as they appear in the C&L Inventory.

The name is typically the IUPAC name

, the EC name or the CAS name. The

identification number must be the EC or the CAS number or the Index number

(originating from Table 3 of Annex VI to CLP). It is recommended to use the

number or numbers that warrant(s) an unambiguous identification of the

substance. The choice of an identifier such as (where applicable) the EC number

or CAS number is advisable to minimise the need for revision of the SDS; or

• if the substance is neither included in Part 3 of Annex VI to CLP nor in the C&L

Inventory database, the CAS number and the IUPAC name, or the CAS number

and another international chemical name, e.g. the name in INCI nomenclature

where applicable; or

• if no CAS number is available and none of the above apply, the IUPAC name or

another international chemical name, e.g. the name in INCI nomenclature, where

applicable.

Please note that Commission Regulation (EU) 2018/669 of 16 April 2018 (11

ATP to CLP)

introduces translations of the chemical names of substances subject to harmonised classification

and labelling listed in Table 3 of Annex VI to CLP in all languages. The 11

ATP was based on the

consolidated text of the CLP Regulation up to the 6

ATP, as in the later ATPs the chemical names

are already translated. All other information, apart from the chemical names, remains applicable

as stated in the relevant ATPs, in particular that related to classification and labelling, unless an

entry has been modified by an ATP that has been adopted after the 6

ATP and is already

applicable. The 11

ATP will apply from 1 December 2019 but can be used voluntarily ahead of

that date.

Where the IUPAC name exceeds 100 characters, suppliers can use one of the other names

(usual name, trade name or abbreviation) referred to in section 2.1.2 of Annex VI REACH provided

that a C&L notification to ECHA, in accordance with CLP Article 40(1)(b), includes both the IUPAC

name and the other name used.

The International Nomenclature Cosmetic Ingredients (INCI) name is mandatory in the

European Union (EU) according to Regulation (EC) No 1223/2009 for labelling the names of

ingredients on cosmetic products. The INCI system was introduced in the European Community in

1996/97 and is well established for cosmetic products. It is also used in many non-EU countries.

Since 2004, the INCI system is also mandatory in the EU for labelling of preservatives and

allergenic perfume ingredients according to the Detergents Regulation (EC) No 648/2004.

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4.2.2 Mixtures

The product identifiers for mixtures must include both:

• the trade name or the designation of the mixture; and

• the identity of all substances in the mixture that contribute to the classification of

the mixture as regards acute toxicity, skin corrosion or serious eye damage, germ

cell mutagenicity, carcinogenicity, reproductive toxicity, respiratory or skin

sensitisation, specific target organ toxicity (STOT), or aspiration hazard.

The CLP Regulation does not specify the type of chemical names

that should be used to

identify the chemical substances in the mixture. It only mentions the approach used for

identification of substances in the mixture that contribute to the classification of the

mixture (see CLP Article 18(3)(b) and the second paragraph of CLP Article 18(3)).

Nevertheless, when choosing a chemical name, it is recommended that the approach

outlined in CLP Article 18(2) is followed. On that basis, if a name of the substance is

shorter than other names available to the user/consumer or better recognised by the

user/consumer in the language of the Member State where the mixture is placed on the

market, this name should be used. This is often the case for common or basic

ingredients. Furthermore, if there is a translated name available in Annex VI to CLP

in the C&L Inventory, this name should be given preference.

In cases where another international chemical name (for example an INCI name) is

better known by the user/consumer, it is possible to deviate from the CLP Article 18(2)

approach. It is preferable to use the name that is regarded as well-known. The name of

the substance needs to unambiguously define its identity. Where an INCI name does not

sufficiently define the substance identity compared to, for example, the requirements of

CLP Article 18 (2) or the requirements for SDSs under the REACH Regulation, a clearer

identification should be preferred.

If the trade name or the designation of the mixture already includes the name(s) of the

substance(s) contributing to the classification of the mixture as defined in paragraph

3(b) of CLP Article 18, they do not need to be repeated. Moreover, if the supplemental

information on the label already contains the chemical name of the substance, e.g. in the

list of allergens and preservatives required by Regulation (EC) No 648/2004 on

detergents, it is advisable to use the same name. This approach should apply to both

consumer and professional products.

The selected chemical names must identify the substances primarily responsible for the

major health hazards that have caused the classification of the mixture and the

assignment of the corresponding hazard statements.

To reduce the number of substance (‘chemical’) names on the label, no more than four

names should be provided on the label for a mixture, unless necessary due to the nature

and severity of the hazards. This may be the case where a mixture contains more than

The terms used for identification of the mixture and the substances in the mixture must be the

same as those used in the safety data sheet.

Please note that Commission Regulation (EU) 2018/669 of 16 April 2018 (11

ATP to CLP)

introduces translations of the chemical names of substances subject to harmonised classification

and labelling listed in Table 3 of Annex VI to CLP in all languages. The 11

ATP was based on the

consolidated text of the CLP Regulation up to the 6

ATP, as in the later ATPs the chemical names

are already translated. All other information, apart from the chemical names, remains applicable

as stated in the relevant ATPs, in particular that related to classification and labelling, unless an

entry has been modified by an ATP that has been adopted after the 6

ATP and is already

applicable. The 11

ATP will apply from 1 December 2019 but can be used voluntarily ahead of

that date.

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four substances present in significant concentrations and contributing to the

classification of the mixture for one or several of the hazards mentioned under CLP

Article 18(3)(b). As explained in CLP FAQ ID=1050 (available at

https://echa.europa.eu/support/qas-support/qas), there are no strict rules on how to

decide which substances should take precedence to be named on the label, but the

following may help in the selection. For non-additive health hazards (e.g. germ cell

mutagenicity, carcinogenicity, reproductive toxicity, respiratory or skin sensitisation and

specific target organ toxicity categories 1 and 2), all ingredients present in the mixture

at or above the generic concentration limit (GCL) or specific concentration limit (SCL)

should be considered as "primarily responsible for the major health hazards" within the

meaning of Article 18(3)(b) CLP and included on the label. For the additive health

hazards mentioned in Article 18 (3)(b) CLP (e.g. acute toxicity, skin corrosion, serious

eye damage, specific target organ toxicity category 3 and aspiration hazard), all

ingredients present in the mixture at or above the GCL or SCL should be included on the

label. However, where there are several ingredients contributing to classification for one

hazard endpoint, only the ingredients primarily contributing to the classification, for

example, those with the highest concentrations or closest to the GCL or SCL, need to be

included on the label, and therefore the names of other ingredients with limited

contribution to the classification are not required. In addition, specific labelling rules

apply to mixtures containing skin and respiratory sensitisers (see Table 3.4.3 of Annex I

to CLP and point 2.8 of Annex II to CLP).

Note that, although the UFI is an element of identification used for the purpose of Annex

VIII to CLP, it is not a product identifier within the meaning of CLP Article 18. The UFI is

part of the (obligatory) supplemental information (CLP Article 25(7)). Nevertheless

specific provisions may apply (see section 4.8.1.1 of this guidance document and the

Guidance on harmonised information relating to emergency health response – Annex

VIII to CLP).

The manufacturer, importer or downstream user of certain less hazardous substances

contained in a mixture may conclude that disclosing substance identifiers that are

required for the label or the SDS can put the confidential nature of his business or

intellectual property rights at risk. In such cases, he may submit a request to ECHA to be

granted permission to use an alternative chemical name in accordance with CLP Article

24. The alternative name should be a more general name identifying the most important

functional groups or an alternative designation. The conditions under which the use of an

alternative name may be granted are given in Part 1, section 1.4 of Annex I to CLP.

The above requests are subject to a fee, in accordance with Article 3 of Commission

Regulation (EU) No 440/2010 (the Fee Regulation). Where the request is submitted by a

micro, small or medium-sized enterprise (SME)

, ECHA will levy a reduced fee as set out

in Article 24(2) and Annex I to the Fee Regulation.

For more information on how to request the use of an alternative chemical name for a

substance in a mixture, please follow the technical instructions set out in the manual on

preparation of REACH and CLP dossiers: How to prepare a request for use of an

alternative chemical name for a substance in a mixture available in the Manuals section

of the ECHA website at https://echa.europa.eu/manuals. It is also advised to visit the

following section on the ECHA website: https://echa.europa.eu/support/dossier-

submission-tools/reach-it/requesting-an-alternative-chemical-name-in-mixtures.

SME is defined in Commission Recommendation 2003/361/EC.

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4.3 Hazard pictograms

4.3.1 General information

A hazard pictogram is a pictorial presentation to communicate information on the hazard

concerned (see also the definition provided in CLP Articles 2(3) and 31(2)). According to

CLP Article 19, the classification of a substance or mixture determines the hazard

pictograms that have to be displayed on a label. Information on the assignment of

hazard pictograms to specific hazard classes and categories/differentiations can also be

found in Annex V to CLP.

Currently, there are nine different pictograms. While normally only one pictogram is

assigned to an individual hazard class or category, a few hazard differentiations have to

carry two pictograms, namely substances and mixtures classified as self-reactive Type B

or as organic peroxide Type B (see also the below sections). It should also be noted that

some pictograms cover several hazard classes and categories.

4.3.2 Shape, colour and dimensions

The colour and presentation of a label must allow the hazard pictogram and its

background to be clearly visible. Hazard pictograms must be in the shape of a square set

at a point, i.e. they must appear as a diamond shape when the label is read horizontally,

and must have a black symbol on a white background with a red frame (see section

1.2.1 of Annex I to CLP). The exact type of red, i.e. the Pantone colour number, is not

defined, and labellers are free to use their discretion.

Each hazard pictogram must cover at least one fifteenth of the minimum surface area of

the label dedicated to the information required by CLP Article 17, but the minimum area

of the pictogram must not be less than 1 cm

. The minimum dimensions of labels and

pictograms are given in Table 1.3 of Annex I to CLP. For pictograms, these minimum

dimensions refer to the sides of the red frame of the pictogram itself, and not to the

sides of the virtual square within which the pictogram is placed:

Correct measurement Wrong measurement

Below is the exclamation mark (pictogram GHS07) as an example pictogram. It is

assigned to various health hazard classes and categories of lower severity (see Part 2 of

Annex V to CLP):

Printable pictograms are provided free of charge for download at

http://www.unece.org/trans/danger/publi/ghs/pictograms.html.

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4.3.3 Precedence rules

For substances and mixtures classified for more than one hazard, several pictograms

may be required on the label. In such cases, the applicability of the precedence rules set

out in CLP Article 26 need to be checked. As a general rule, the pictograms that reflect

the most severe hazard category of each hazard class must be included on the label.

This would also apply where a substance has both a harmonised and a non-harmonised

(i.e. self-) classification (see CLP Article 26(2)).

Further to this, the CLP Regulation sets out precedence rules relating to particular hazard

pictograms and classifications:

• For physical hazards, if the label carries the pictogram GHS01 (exploding bomb),

then GHS02 (flame) and GHS03 (flame over circle) are optional …

mandatory optional optional

… except in cases where more than one pictogram is compulsory, namely for

substances and mixtures classified as self-reactive Type B or as organic peroxide

Type B (see Annex I to CLP);

• For physical and health hazards, if the label carries the pictogram GHS02 (flame)

or GHS06 (skull and crossbones), then GHS04 (gas cylinder) is optional

mandatory mandatory optional

• For health hazards, if the label carries the pictogram GHS06 (skull and

crossbones), then GHS07 (exclamation mark) must not appear:

This precedence rule was introduced by the Commission Regulation (EU) No 286/2011 of 10 March

2011 (2

ATP to the CLP Regulation).

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• For health hazards, if the label carries the pictogram GHS05 (corrosion), then

GHS07 (exclamation mark) must not be used for skin or eye irritation…

… but still has to be used for other hazards.

• For health hazards, if the label carries the pictogram GHS08 (health hazard) for

respiratory sensitisation, then GHS07 (exclamation mark) must not be used for skin

sensitisation or for skin or eye irritation …

… but still has to be used for other hazards.

In case a substance or mixture is assigned the supplemental hazard statement EUH071

(“Corrosive to the respiratory tract”), a corrosivity pictogram (GHS05) may be assigned

(see Note 1 of Table 3.1.3 in Annex I to CLP). Where this is done, the pictogram GHS07

(exclamation mark) for STOT SE category 3 (respiratory tract irritation) must be omitted

from the label, as well as the hazard statement H335 (“May cause respiratory

irritation”).

For substances and mixtures that have to be labelled in accordance with both the CLP

Regulation and the rules on the transport of dangerous goods, the CLP pictogram(s) may

be omitted from the label on the outer or single packaging when the CLP pictogram(s)

and the pictogram(s) for transport of dangerous goods relate to the same hazard (see

section 5.4 of this guidance document).

4.3.4 Blank pictograms

When preparing hazard labels, a common practice is to use pre-printed label stocks of

the diamonds (the label background is printed first before it is overprinted with the

specific label information). This may result in labels with a number of pre-printed empty

diamonds, not all of which may then be needed by a company that has purchased pre-

printed labels. In such a situation, one or more pre-printed diamonds may have to be

left empty.

The CLP Regulation does not explicitly forbid blank diamonds. However, any information

given in addition to the minimum mandatory labelling must not contradict or cast doubt

on the mandatory label information (CLP Article 25(3)), while empty red frames might

raise questions. If empty red frames are unavoidable, it is recommended to cover them

up with a solid overprint which blacks them out completely (see the example in Figure

1).

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Figure 1: Blackened out empty diamonds

Blacking-out of empty diamonds aims to avoid the impression that relevant hazard

symbols may have been left off the label through a printing mistake.

Please refer also to CLP FAQ ID=240 available at https://echa.europa.eu/support/qas-

support/qas.

4.4 Signal words

A signal word indicates the relative level of severity of a particular hazard. The label

must include the relevant signal word in accordance with the classification of the

hazardous substance or mixture: more severe hazards require the signal word ‘Danger’

while less severe hazards require the signal word ‘Warning’ (see CLP Article 20).

The signal word relevant for each specific classification is set out in the tables indicating

the label elements required for each hazard class as set out in Parts 2 to 5 of Annex I to

CLP. Some hazard categories, like explosives, division 1.6, do not have a signal word.

Where a substance or mixture is classified for more than one hazard, the label must only

bear one single signal word. In such cases, the signal word ‘Danger’ takes precedence

and the signal word ‘Warning’ must not appear.

4.5 Hazard statements

CLP hazard labels must also bear the relevant hazard statements describing the nature

and severity of the hazards of a substance or mixture (see CLP Article 21).

The hazard statements relevant for each hazard class and category/differentiation are

set out in the tables contained in Parts 2 to 5 of Annex I to CLP. An example is the

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hazard statement H302 (“Harmful if swallowed”) assigned to acute oral toxicity, category

4. The wording for hazard statements is given in Tables 1.1, 1.2 and 1.3 of Annex III to

CLP.

In some cases, additional information to complement a hazard statement

may need to

be provided, such as the specification of the route of exposure or of the target organ for

certain health hazards, i.e. for the CMR, STOT SE (categories 1 and 2) and STOT RE

hazard classes. For example:

• for STOT RE category 1, the hazard statement H372 (“Causes damage to organs

through prolonged or repeated exposure”) must be complemented by the organs

affected if known and by the route of exposure if it is conclusively proven that no

other routes of exposure cause the hazard, e.g. H372 (“Causes damage to the

liver through prolonged or repeated dermal exposure”);

• for STOT SE category 1, the route of exposure or the target organ may have to

be included in the statement as well, e.g. H370 (“Causes damage to the liver via

ingestion”).

For reproductive toxicity, hazard statements H360 (“May damage fertility or the unborn

child”) and H361 (“Suspected of damaging fertility or the unborn child”) indicate a

general concern. These general hazard statements can be replaced by the hazard

statements indicating the specific effect of concern, if known, in accordance with section

1.1.2.1.2 of Annex VI to CLP (e.g. H360F “May damage fertility”, H361d “Suspected of

damaging the unborn child”, H360Df “May damage the unborn child. Suspected of

damaging fertility”).

If a substance classification is harmonised and included in Part 3 of Annex VI to CLP, the

corresponding hazard statement(s) relevant for this classification have to be used on the

label. Note that certain harmonised classifications marked with an asterisk in Part 3 of

Annex VI to CLP are minimum classifications and, based on available data, a more

severe classification as well as the corresponding hazard statement may need to be

assigned. Also, hazard statements may need to be included for the non-harmonised

parts of the classification of the same substance, i.e. for the hazard classes or

differentiations not covered in the Annex VI listing (see CLP Article 4(3)).

Table 1.2 of Annex III to CLP defines which combined hazard statements are allowed

Currently, combinations are allowed for acute toxicity hazard statements that relate to

different routes of exposure, but to the same category. Such statements can appear on

the label and in the SDS, for example for category 3 for the oral and dermal route

H301+H311 (“Toxic if swallowed or in contact with skin”).

If a substance or mixture is classified in several hazard classes or differentiations of a

hazard class, all hazard statements resulting from the classification must appear on the

label, unless there is evident duplication or redundancy (see CLP Article 27). For

example, if the hazard statement H314 (“Causes severe skin burns and eye damage”) is

assigned, H318 (“Causes serious eye damage”) may be omitted (see also section 3.3.4

of the Guidance on the application of the CLP criteria). Similarly, if the hazard statement

H410 (“Very toxic to aquatic life with long lasting effects”) is assigned, H400 (“Very toxic

to aquatic life”) may be omitted (see also section 4.1.6 of the Guidance on the

application of the CLP criteria). Duplication or redundancy should also be avoided for a

substance or mixture that is assigned the supplemental hazard statement EUH071

Please note that this does not constitute supplemental labelling information in the meaning of

CLP Article 25. It is rather additional hazard information that is required to be included within the

hazard statement itself, beyond the standardised wording.

Commission Regulation (EU) No 286/2011 of 10 March 2011.

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(“Corrosive to the respiratory tract”)

. In this case, the hazard statement H335 (“May

cause respiratory irritation”) for STOT SE category 3 (respiratory tract irritation) should

be omitted from the label. Please note that the information provided on the hazard label

and in Section 2.2 of the SDS, for the same substance or mixture, must be consistent.

The correct wording of the hazard statements as it has to appear on the label is given in

Annex III to CLP, in all EU languages. The hazard statements of one language must be

grouped together with the precautionary statements of the same language on the label

(see section 3.3 of this guidance document).

4.6 Precautionary statements

CLP hazard labels must bear the relevant precautionary statements giving advice on

measures to prevent or minimise adverse effects to human health or the environment

arising from the hazards of a substance or mixture (see CLP Article 22). An example is

the precautionary statement P373 (“DO NOT fight fire when fire reaches explosives”).

The complete set of precautionary statements relevant for each hazard class and

category/differentiation is listed by alphanumeric code in the tables indicating the label

elements required for each hazard class in Parts 2 to 5 of Annex I to CLP.

Precautionary statements must be selected in line with the provisions set out in CLP

Articles 22 and 28 and with Part 1 of Annex IV to CLP: any selection must take into

account the hazard statements used, the intended or identified use(s) of the substance

or mixture, as well as the basic instructions specified in the “conditions for use” columns

in Tables 6.1 – 6.5 of Annex IV to CLP. Duplication and redundancy should be avoided.

Where the substance or mixture is supplied to the general public, one precautionary

statement addressing the disposal of that substance or mixture as well as the disposal of

packaging must in general

appear on the label (see CLP Article 28(2)). Normally, not

more than six precautionary statements must appear on the label, unless necessary to

reflect the nature and the severity of the hazards (see Example C in section 7.4 of this

guidance document).

For assistance with the selection of the most appropriate P-statements, please refer to

section 7 of this guidance document.

Part 2 of Annex IV to CLP lists, in all EU languages, the correct wording of the

precautionary statements as it must appear on a label. Where there are different

translations of P-statements, the translation in the national version of the CLP Regulation

usually gives the most relevant wording. The precautionary statements of one language

have to be grouped together with the hazard statements of the same language on the

label (see section 3.3 of this guidance document).

See also Note 1 of Table 3.1.3 in Annex I to CLP.

If it is clear that the disposal of the substance or mixture or the packaging does not present a

hazard to human health or the environment, a P-statement addressing disposal is not required.

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4.7 Codes for hazard and precautionary statements

Hazard and precautionary statements are codified using a unique alphanumerical code,

which consists of one letter and three numbers, as follows:

• the letter “H” for “hazard statement” or “P” or “precautionary statement”;

• for hazard statements, the first digit designating the type of hazard (2 for physical

hazards, 3 for health hazards and 4 for environmental hazards) and the next two

digits corresponding to the sequential numbering of hazards, as the codes from 200

to 210 for explosivity, the codes from 220 to 230 for flammability, etc.

• risk phrases carried through from the DSD and DPD, but which are not yet included

in the UN GHS, are codified as “EUH”;

• for precautionary statements, a digit reflecting one of the five types of statements,

namely general statements (1), prevention statements (2), response statements (3),

storage statements (4) and disposal statements (5), followed by two digits for the

sequential numbering of the statements themselves.

The code ranges for the hazard and precautionary statements under the CLP Regulation

are set out in Table 4 below:

Table 4: Code ranges of hazard and precautionary statements under the CLP

Regulation

Hazard Statements: H

Precautionary Statements: P

200 – 299 Physical hazard

100 – 199 General

300 – 399 Health hazard

200 – 299 Prevention

400 – 499 Environmental hazard

300 – 399 Response

400 – 499 Storage

500 – 599 Disposal

The codes of the hazard and precautionary statements and EUH statements are not

necessary for the label. The CLP Regulation only requires the actual phrasing of the

applicable statements on the label.

4.8 Supplemental labelling information

CLP Article 25 defines the concept of ‘supplemental information’ which is intended to

incorporate additional labelling information over and above that listed in CLP Article

17(a) to (g). This additional labelling information can be divided into two categories,

namely obligatory and non-obligatory information. Please note that, according to CLP

Article 25(6), supplemental labelling information might be obligatory for a mixture, even

if not classified as hazardous.

All ‘supplemental information’ must generally be located in the section for supplemental

information on the label. Both obligatory and non-obligatory supplemental information

have to appear in the same languages as the other CLP label elements.

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As it is obligatory to place this information alongside the label elements required by CLP

Article 17(a) to (g), these supplemental label elements need to be considered carefully

as to the location and the space they need when preparing a CLP label for a substance or

mixture (see also Example 3 under section 6 of this guidance document).

Commission Regulation (EU) 2017/542 amended CLP to include the requirement for a

Unique Formula Identifier (UFI) as supplemental information on the label under Article

25(7) (see section 4.8.1.1 of this guidance document)

. However, there are no fixed

rules concerning the positioning of the UFI on the label: it can either be located in the

section for ‘supplemental information’ on the label, as described above, or be placed

(with the “UFI:” marker) in proximity of the product name or trade name. For practical

reasons, the UFI could also be printed on the packaging, as long as it remains in

proximity of the other labelling information. In any case, the UFI should be clearly visible

and easy to locate in case of an emergency (its main function is to help the emergency

responder in the identification of the mixture contained in the product). In the case of

bespoke paints for which a submission in accordance of Annex VIII has not been made

(and no UFI has been generated), the UFIs of the hazardous components have to be

included on the label (see section 5.3.3 for more details on special provisions for

bespoke paints).

4.8.1 Obligatory supplemental labelling information

Obligatory supplemental labelling information includes:

• Supplemental hazard statements relating to particular physical and health

properties. These are codified as “EUH” statements, e.g. EUH014 “Reacts

violently with water”. For some substances with harmonised classifications, the

supplemental hazard statements are included in Part 3 of Annex VI to CLP;

• Supplemental statements for certain mixtures, e.g. EUH204 “Contains

isocyanates. May produce an allergic reaction” (see Part 2 of Annex II to CLP).

These phrases are assigned EUH codes as well, to align their presentation with

the above supplemental hazard statements;

• The supplemental statement EUH401 “To avoid risks to human health and the

environment, comply with the instructions for use” for hazardous substances and

mixtures within the scope of Directive 91/414/EEC

(see Part 4 of Annex II to

CLP);

• Label elements resulting from other EU acts (see CLP Article 32(6)), for example:

– the authorisation number requested by the REACH Regulation;

Commission Regulation (EU) 2017/542 (as amended by Commission Delegated Regulation (EU)

2020/11 and Commission Delegated Regulation 2020/1677 and Commission Delegated Regulation

2020/1676 of 31 August 2020 (the “workability amendments”) also amended the CLP Regulation

by adding Annex VIII.

Repealed and replaced by Regulation (EC) No 1107/2009 of the European Parliament and of the

Council of 21 October 2009 concerning the placing of plant protection products on the market with

effect from 14 June 2011.

Obligatory supplemental information, when included, must be easy to identify

and read. Naturally, it has precedence over any non-obligatory supplemental

information if space on the label is limited.

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– the listing of surfactants and perfumes according to the Regulation (EC)

No 648/2004 on detergents, as amended;

– the authorisation number of the biocidal product according to the Biocidal

Products Regulation (EU) No 528/2012;

– the labelling provisions (i.a. flammability) of the Aerosol Dispensers

Directive 75/324/EEC (ADD), as amended; or

– the content of volatile organic compounds (VOCs) in accordance with

Directive 2004/42/EC

Further additional obligatory information can include:

• Specific response information as referred to in the brackets of the precautionary

statements P320 “Specific treatment is urgent (see … on this label)”, P321

“Specific treatment (see … on this label)” in Annex IV to CLP, e.g. “see

supplemental first aid instructions on this label” or “see supplemental instructions

on the administration of antidotes on this label”. See also Table 5 below and the

selection tables in section 7.3 of this guidance document;

• For mixtures containing components of unknown acute toxicity at a concentration

of 1% or greater, the statement “x percent of the mixture consists of

component(s) of unknown acute toxicity” (see section 3.1.3.6.2.2 of Annex I to

CLP). This statement has also to be included in the SDS, when this is provided

In addition, it may be appropriate to differentiate the hazard based on the route

of exposure, for example “x percent of the mixture consists of ingredient(s) of

unknown acute (oral/dermal/inhalation) toxicity”, in particular where the

substance is also classified for other hazards and where it is important to specify

the route of exposure (see also the Guidance on the application of the CLP

criteria);

• For mixtures for which no useable information on the short-term (acute) and/or

long-term (chronic) aquatic hazard is available for one or more of the relevant

components, the statement “Contains x percent of components with unknown

hazards to the aquatic environment” (see section 4.1.3.6.1 of Annex I to CLP).

This statement has to be included on the label and in the SDS;

• For mixtures subject to submission requirements under CLP Article 45 and Annex

VIII to CLP, a UFI, where applicable. Special provisions may apply to bespoke

paints. (see section 4.8.1.1 of this guidance document).

The CLP Regulation requires supplemental label information to be located in a specific

supplemental information section on the label. A supplier may also choose to place the

supplemental information in several locations, taking into account the requirements of

CLP Article 25 (see Example 3 and Example 5 in section 6 of this document).

Similarly, the section for supplemental label information should be visibly separated from

the labelling elements according to CLP Article 17(a) to (g), e.g. by placing it in another

section of the label, by putting it in a text box, using a different colour or using a

Directive 2004/42/EC of the European Parliament and of the Council of 21 April 2004 on the

limitation of emissions of volatile organic compounds due to the use of organic solvents in certain

paints and varnishes and vehicle refinishing products and amending Directive 1999/13/EC.

For further information on the compilation of the SDS, please consult the Guidance on the

compilation of safety data sheets.

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different letter size. However, on a case-by-case basis, it may not be advisable to make

a visible differentiation between the CLP elements and obligatory supplemental labelling

information that is requested by another legislation, where the latter supports the safe

handling and use of a substance or mixture. For example, where additional EUH

statements express a warning similar to that contained in the hazard statements that

reflect a classification, it is even advisable to group both types of statements together on

the label so that they reinforce each other. For example, for a substance that is classified

as water-reactive category 1, the hazard statement EUH014 “Reacts violently with

water.” is very similar to H260 “In contact with water releases flammable gases which

may ignite spontaneously.” (see also Example 4 in section 6 of this guidance document).

In relation to readability, obligatory labelling information required by other EU legislation

(e.g. the content of volatile organic compounds as required by Directive 2004/42/EC or

the listing of specified constituents as required by Regulation (EC) No 648/2004) must

not be treated differently from other obligatory labelling information required by the CLP

Regulation itself. Obligatory information must be easy to identify and read and must take

precedence on the CLP label over any other non-obligatory supplemental information. An

overview of the obligatory supplemental label elements to be included in the section for

supplemental information on the label is provided in Table 5.

Table 5: Obligatory supplemental labelling information pursuant to CLP Articles

25 and 32

Legal Reference

Type and Applicability

Code

Content / Phrasing

CLP Article

25(1) and Annex

II, Part 1,

section 1.1

a) Supplemental hazard statements relating to certain physical

properties of substances and mixtures. They need to be assigned in

accordance with the conditions specified in Annex II to CLP when a

substance or mixture has already been classified on the basis of the

criteria in Annex I to CLP. For some substances with harmonised

classifications, supplemental hazard statements are included in Part 3

of Annex VI to CLP.

EUH014

‘Reacts violently with water’

EUH018

‘In use, may form flammable/

explosive vapour-air mixture’

EUH019

‘May form explosive peroxides’

EUH044

‘Risk of explosion if heated

under confinement’

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Legal Reference

Type and Applicability

Code

Content / Phrasing

CLP Article

25(1) and Annex

II, Part 1,

section 1.2

b) Supplemental hazard statements relating to health properties of

substances and mixtures. They need to be assigned in accordance

with the conditions specified in Annex II to CLP, Part 1, section 1.2,

when a substance or mixture has already been classified on the basis

of the criteria in Annex I to CLP. For some substances with

harmonised classifications, supplemental hazard statements are

included in Part 3 of Annex VI to CLP. For EUH071, see also Annex I to

CLP, Table 3.1.3, Note 1.

EUH029

‘Contact with water liberates

toxic gas’

EUH031

‘Contact with acids liberates

toxic gas’

EUH032

‘Contact with acids liberates

very toxic gas’

EUH066

‘Repeated exposure may cause

skin dryness or cracking’

EUH070

‘Toxic by eye contact’

EUH071

‘Corrosive to the respiratory

tract’

CLP Article

25(6) and Annex

II, Part 2

Supplemental statements for certain mixtures. They need to be assigned to

mixtures in accordance with the conditions specified in Annex II to CLP, Part

1. Mixtures containing lead

EUH201

‘Contains lead. Should not be

used on surfaces liable to be

chewed or sucked by children’

– for packaging content

less than 125 ml

EUH201A

‘Warning! Contains lead’

2. Mixtures containing

cyanoacrylates

EUH202

‘Cyanoacrylate.

Danger.

Bonds skin and eyes in

seconds.

Keep out of the reach of

children.’

3. Cement and cement

mixtures

EUH203

‘Contains chromium (VI). May

produce an allergic reaction’

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Legal Reference

Type and Applicability

Code

Content / Phrasing

4. Mixtures containing

isocyanates

EUH204

‘Contains isocyanates.

May produce an allergic

reaction’

5. Mixtures containing

epoxy constituents with

an average molecular

weight ≤ 700

EUH205

‘Contains epoxy constituents.

May produce an allergic

reaction’

6. Mixtures sold to the

general public which

contain active chlorine

EUH206

‘Warning!

Do not use together with other

products.

May release dangerous gases

(chlorine)’

7. Mixtures containing

cadmium (alloys) and

intended to be used for

brazing or soldering

EUH207

‘Warning!

Contains cadmium. Dangerous

fumes are formed during use.

See information supplied by the

manufacturer.

Comply with the safety

instructions.’

8. Mixtures not classified as

sensitising but

containing at least one

sensitising substance

EUH208

‘Contains (name of sensitising

substance). May produce an

allergic reaction’

9. Liquid mixtures

containing halogenated

hydrocarbons

EUH209

EUH209A

‘Can become highly flammable

in use

Can become flammable in use’

10. Mixtures not intended

for the general public

EUH210

‘Safety data sheet available on

request’

11. Aerosols

Aerosols are also subject to the

labelling provisions of Directive

75/324/EEC

According to the last paragraph of Section 2.8 of Annex II to CLP (introduced by Commission

Regulation (EU) No 286/2011 (2

ATP to the CLP Regulation)), mixtures classified as sensitising

containing other substance(s) classified as sensitising (in addition to the one that leads to the

classification of the mixture) and present in a concentration equal to or greater than that specified

in Table 3.4.6 of Annex I to CLP must bear the name(s) of that/those substance(s) on the label.

This (these) name(s) should be placed together with the name(s) of the substance(s) relevant to

classification of the mixture. Note that EUH208 must be used when a mixture not classified as

sensitising contains sensitising substances. However, according to Commission Regulation (EU)

2016/918 (8

ATP to the CLP Regulation), where a mixture is labelled with EUH204 in accordance

with Section 2.4 of Annex II to CLP or EUH205 in accordance with Section 2.5 of Annex II, the

statement EUH208 may be omitted from the label when the only substances triggering EUH208

are isocyanates or epoxy constituents.

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Legal Reference

Type and Applicability

Code

Content / Phrasing

CLP Annex IV

Substances and mixtures

assigned the precautionary

statements:

• P320 - Specific treatment

is urgent (see … on this

label)

• P321 - Specific treatment

(see … on this label)

Supplemental first aid

instruction (e.g. administration

of an antidote or immediate

measures such as specific

cleansing agent) referred to in

the brackets of the

precautionary statements

CLP Annex I,

section

3.1.3.6.2.2

Mixture containing

ingredient(s) of unknown

acute toxicity at a

concentration at 1% or

greater

‘x percent of the mixture

consists of component(s) of

unknown acute toxicity’

(also for safety data sheet)

CLP Annex I,

section 4.1.3.6.1

Mixture where no useable

information on the

short-term (acute) and/or

long-term (chronic) aquatic

hazard is available for one

or more of the relevant

components

‘Contains x percent of

components with unknown

hazards to the aquatic

environment’.

(also for safety data sheet)

CLP Article

25(2)

Supplemental statement for

substances and mixtures

within the scope of Directive

91/414/EEC

EUH401

‘To avoid risks to human health

and the environment, comply

with the instructions for use’.

Label elements

resulting from

other

Community acts

pursuant to CLP

Article 32(6)

Examples:

 Regulation (EC) No

1907/2006 (REACH)

 Regulation (EC) No

648/2004 (detergents)

 Directive 75/324/EEC on

aerosol dispensers (ADD)

 authorisation number

 labelling statements related

to restrictions in Annex XVII

of REACH, e.g. 'Restricted

to professional users'

 listing of specified

constituents such as anionic

surfactants, oxygen

bleaching agents, enzymes,

disinfectants, optical

brighteners and perfumes

 i.a. flammability labelling

 content of volatile organic

compounds

Repealed by Regulation (EC) No 1107/2009 of the European Parliament and of the Council of 21

October 2009 concerning the placing of plant protection products on the market with effect from

14 June 2011.

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Legal Reference

Type and Applicability

Code

Content / Phrasing

 Directive 2004/42/EC on

volatile organic

compounds (VOCs)

 Biocidal Products

Regulation (EU) No

528/2012

 for example: authorisation

number of the biocidal

product

CLP Article

25(7) and

Section 5, Part A

of Annex VIII

Unique formula identifier

(UFI) for mixtures classified

for health or physical effects

and subject to submission

requirements following CLP

Article 45 (see section

4.8.1.1 of this guidance

document)

n/a

Unique 16-digit alphanumeric

code

, for example:

UFI: VDU1-414F-1003-1862

CLP Article

25(8) and

Section 2.2.a,

Part B of Annex

VIII,

Unique formula identifier

(UFI) for mixture

components of bespoke

paints, subject to Article 45

and present in a

concentration exceeding

0.1% (see section 5.3.3 of

this Guidance document).

n/a

See above

4.8.1.1 Unique formula identifier (UFI)

A Unique Formula Identifier (UFI) is a unique alphanumeric code that links the

information on a mixture submitted under CLP Article 45 to a specific product placed on

the market (for further information, see ECHA’s Poison Centres website at:

https://poisoncentres.echa.europa.eu/).

The UFI is mandatory for all hazardous mixtures that require the submission of

information according to CLP Article 45, i.e. all the mixtures that are placed on the EU

market and classified under CLP as hazardous based on their health or physical effects.

Importers and downstream users are duty holders under Article 45 and are required to

include the UFI on the label of the mixture before placing it on the market. Distributors

may also have obligations under CLP Article 4(10), see section 3.1 of the Guidance on

harmonised information relating to emergency health response – Annex VIII to CLP.

Certain exemptions apply, more details are given in the same section of that guidance.

The UFI is considered as obligatory supplemental labelling information according to

Article 25(7) of the CLP Regulation, and should be included in the label section dedicated

to supplemental information. However, by way of derogation from Article 25(7) of the

See Commission Regulation (EU) 2017/542.

For more information, see the User guide for the UFI generator and additional support material

available on the ECHA Poison Centres website at at https://poisoncentres.echa.europa.eu/ufi-

generator.

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CLP Regulation, Article 29(4a)

allows to include the UFI in another way. The different

options are specified in Part A Section 5 of Annex VIII. Hence, while normally

supplemental labelling information should be located in the section for ‘supplemental

information’ on the label, the UFI can alternatively even be placed outside the label, by

being printed or affixed directly onto the inner packaging. The UFI must however be

located with the obligatory CLP label elements such as the product identifiers or hazard

information. The UFI should be clearly identifiable

. Where a UFI is added separately to

a label or packaging, the person responsible should ensure that it remains firmly

attached during normal handling and use.

When the inner packaging is in such a shape or so small that it is not possible to affix

the UFI on it, then the label elements including the UFI should be provided either on

fold-out labels, or tie-on tags, or an outer packaging (in accordance with section 1.5.1 of

Annex I to CLP, see section 5.3.1 of this guidance document), always with the other

label elements.

It should be noted that although CLP considers the UFI as supplemental information, it is

included in Section 1.1 (product identifier) of the SDS, in accordance with Annex II to

REACH, where applicable. Please note that the inclusion of the UFI in the SDS is only

required in specific cases, otherwise it is voluntary, see section 4.2 of the Guidance on

harmonised information relating to emergency health response – Annex VIII to CLP).

The UFI code must be preceded by the acronym “UFI:”, i.e. in capital letters, followed by

a colon.

The UFI must be clearly visible, legible and indelibly marked (see section 5.2 of this

guidance document where legibility, readability and size of the label elements are

described).

For mixtures not yet notified under national legislation, the use of a UFI will apply from 1

January 2021, in a stepwise manner, depending on the use of the mixture (see section

3.4.1 of the Guidance on harmonised information relating to emergency health response

– Annex VIII to CLP for more details on the compliance dates). If there is a need to

update an existing notification, please see section 3.5.2 of the Guidance on harmonised

information relating to emergency health response – Annex VIII to CLP.

Mixtures already notified under the national schemes where the submitted information

was not in accordance with Annex VIII, do not need to be re-labelled for the purpose of

including a UFI until 1 January 2025. However, if a submission update is needed before

that date, e.g. the mixture composition changes in accordance with certain criteria

(reasons for update are listed in Section 4.1, Part B of Annex VIII, see further details in

section 4.2.7 of Guidance on harmonised information relating to emergency health

response – Annex VIII to CLP), the company is required to comply with the Annex VIII

requirements and to re-label its mixtures with the UFI codes or affix the UFI codes to the

label (or on packaging right next to other obligatory CLP label elements) before placing

the mixtures, as changed, on the market. If a company voluntarily submits the

Regulation (EU) 2020/11 amended CLP by adding the new paragraph 4a to Article 29 (Exemption

from labelling and packaging requirements).

See specific section 5.3.1.1. for specific cases when the use of fold-out labels and tie-on tags are

allowed.

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information in accordance with Annex VIII to CLP ahead of the applicable deadline

even

if has no obligation to do so, it is recommended to include the UFI on the label without

undue delay.

Please note that:

• For hazardous mixtures that are subject to the submission of information under

CLP Article 45, the UFI needs to be reflected on the label or on the packaging

located with other obligatory CLP labelling information.

• For hazardous mixtures used at industrial sites

, the UFI may alternatively be

indicated in Section 1.1 of the SDS.

• For hazardous mixtures sold unpackaged

, the UFI must be indicated in Section

1.1 (product identifier) of the SDS in accordance with Annex II of REACH

• For hazardous mixtures listed in Part 5 of Annex II to CLP the UFI must be

included in a copy of the label elements provided for in Article 29(3), e.g.

attached to the delivery note.

• For hazardous mixtures used for scientific research and development (SR&D), or

for product and process oriented research and development, a UFI is not required

as they are outside the scope of Annex VIII.

• For mixtures classified as ‘gases under pressure’ and/or ‘explosives (unstable

explosive and Divisions 1.1 to 1.6)’ only, a UFI is not required as these hazard

classes outside the scope of Annex VIII.

• For mixtures classified as hazardous to the environment only, a UFI is generally

not required as these hazard classes are outside the scope of CLP Article 45.

However, companies can voluntarily make a submission and include a UFI on the

label and are recommended to do so.

• In the case of multi-layered packaging, the UFI is allowed to be included on the

inner packaging only (by way of derogation from Article 25(7) of the CLP), on the

label or on the packaging located with the obligatory CLP label elements;

• A company may consider making submissions for mixtures that are outside the

scope of CLP Article 45 (for example, hazardous for the environment only). In

that case, the UFI may voluntarily be submitted and put on the label of these

mixtures (and it is recommended).

The readiness of each appointed body to receive the submission in the new format should be

checked with the relevant authority. ECHA has published on the Poison Centres website an

Overview of Member States decisions on implementing Annex VIII (at

https://poisoncentres.echa.europa.eu/echa-submission-portal).

Regardless of its possible inclusion downstream in mixtures intended for professional or

consumer uses.

e.g. mixtures listed in Part 5 of Annex II to CLP.

Annex II to REACH as amended by Commission Regulation (EU) 2020/878 which includes

reference to the UFI.

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An online tool to create and validate UFI codes, the UFI Generator, is available on the

Poison Centres website at https://poisoncentres.echa.europa.eu/ufi-generator. More

information and Manuals are available at https://poisoncentres.echa.europa.eu/ufi-

generator.

4.8.2 Non-obligatory supplemental labelling information

In some cases, suppliers may need to include certain elements on the label that are not

obligatory but are necessary for the handling and use of the product, for example

specific product information, basic instructions for use or P-statements that do not arise

directly from the classification of the product (e.g. “Read label before use” or “Do not get

in eyes” for eye irritant mixtures). Such non-obligatory supplemental labelling

information, the content of which is at the discretion of the supplier, is not part of the

labelling requirements under the CLP Regulation.

The need for non-obligatory information should also be taken into account when deciding

how to lay out the label. The non-obligatory supplemental information may also be

placed alongside the label elements required in CLP Article 17(a) to (g) and the

obligatory supplemental information, when applied. However, such information must not

be confusing to the user or contradict the obligatory label elements. It should also

provide further necessary details (see CLP Article 25(3)).

Additional labelling elements that come from the UN GHS but are not implemented in the

CLP Regulation may be included in the section for non-obligatory supplemental

information. These elements must not confuse the user.

In addition, any non-obligatory supplemental information, either included on the label or

on the packaging, must be consistent with the classification of the substance or mixture

(see CLP Article 25(4)). This means that statements such as ‘non-toxic’, ‘non-polluting’

or ‘ecological’, or other statements suggesting that the substance/mixture is not

hazardous or statements that are incompatible with the assigned classification must not

appear on the label or packaging of a classified substance or mixture.

5. Guidance on particular aspects of CLP hazard labelling

5.1 Further aspects to consider for the CLP hazard label

To enable the supplier to design labels in compliance with the CLP Regulation while at

the same time allowing for as much freedom in arranging labels as possible, further

labelling aspects should be considered.

• Label size: the CLP Regulation defines minimum dimensions for the size of the

label and some of its elements (see section 5.2 of this guidance document);

• Specific labelling rules that refer to specific labelling and packaging situations,

for example:

– a substance or mixture is contained in awkwardly shaped or small

packaging (see CLP Article 29),

– the packaging consists of multiple layers, and/or

– a substance or mixture is subject to the labelling provisions of the CLP

Regulation and to labelling provisions in accordance with the rules

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on the transport of dangerous goods according to the UN

Recommendations on the Transport of Dangerous Goods – Model

Regulations (the so-called "Orange Book")

. The person responsible for

compiling a CLP label needs to consider all of these rules before making a

final decision on the label of the substance or mixture (see CLP Article 33);

• Selection of precautionary statements:

The selection of the most appropriate set of precautionary statements for the

label is largely at the discretion of the supplier. Please refer to section 7 of this

guidance document.

5.2 Size of the label and of the label elements

Section 1.2 of Annex I to CLP defines the label size, setting out minimum dimensions

for the label, with the pictogram size being linked to these minimum dimensions (see

also Table 6 below)

. Nevertheless, the label should be large enough to contain all the

label elements defined by the CLP Regulation while remaining legible. As a result, the

label may need to be larger than the minimum area specified.

Table 6: Minimum dimensions of labels and pictograms under the CLP

Regulation

Capacity of the package

Dimensions of the label

(in millimetres) for the

information required by CLP

Article 17

Dimensions of the

pictogram (in

millimetres)

≤ 3 litres

If possible, at least 52 x 74

Not smaller than 10 x 10

If possible, at least 16 x 16

> 3 litres but ≤ 50 litres

At least 74 x 105

At least 23 x 23

> 50 litres but ≤ 500 litres

At least 105 x 148

At least 32 x 32

> 500 litres

At least 148 x 210

At least 46 x 46

The CLP Regulation requires that the label elements as referred to in CLP Article 17(1)

be of such size and spacing as to be easily read.

Readability is determined by the combination of font size, letter spacing, spacing

between lines, stroke width, type colour, typeface, width-height ratio of the letters, the

surface of the material and significant contrast between the print and the background.

Some examples of the influence of these parameters on readability are shown in Figure 2

below.

Implemented in the EU through international modal agreements and Directive 2008/68/EC.

The size of the pictogram relates here to the dimensions of the pictogram itself, and not to the

size of the virtual square into which the pictogram is placed.

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Figure 2: Readability

A label may accommodate more language(s) than those required by the Member State

where the substance or mixture is placed on the market. As long as the label complies

with the (minimum) dimensions set out in Table 6 above and as long as legibility of the

text elements is warranted, the decision on the number of languages is at the discretion

of the respective supplier.

The exact size of the letters of the signal words, hazard statements, precautionary

statements and any supplemental information is not further defined in the legal text, i.e.

it is up to the supplier to determine the size of the letters that allows the label elements

to be easily read. However, the minimum letter size of 1.2 mm (‘x-height’) can be used

as a reference. A supplier may decide whether to increase the letter size with the overall

volume of the packaging and dimensions of the label, or to fix it more or less for all

volumes and labels.

Similarly, a supplier may decide whether to have larger letter sizes for certain label

elements while others are presented in smaller letters. Some practical options often

chosen are for example:

• providing the signal word “Danger” or “Warning” in larger letters on the label than

for the hazard and precautionary statements,

• presenting the obligatory label elements in larger letters than for the non-

obligatory labelling information.

Both of the above-mentioned options are in principle compatible with the CLP legal text

as long as the obligatory information on the label can be easily read.

The CLP Regulation links the size of the hazard pictograms to the minimum

dimensions of the label. Each hazard pictogram must cover at least one fifteenth of the

minimum surface area of the label dedicated to obligatory labelling information. The

minimum dimensions of labels and pictograms are given in Table 1.3 of Annex I to CLP.

The area of the pictogram for the smallest capacity of the package should be at least 16

mm x 16 mm, if possible, but must never be less than 1 cm

. The pictogram size should

be increased from the minimum dimensions where the actual label size allows this. The

idea behind this is that the label size and the size of the pictograms should remain

proportional to the size of the packaging.

A pictogram covering one fifteenth of the minimum surface area, obtained by multiplying

the dimensions as defined in Table 1.3 of Annex I to CLP, is considered to be legible. The

pictogram size has to be increased in all cases where it occupies less than one fifteenth

of the surface area of the label dedicated to the obligatory labelling information. For

small packaging, one fifteenth of the minimum size label is 16 mm x 16 mm. However,

sometimes even the minimum label size cannot be applied or the minimum size label can

only accommodate 10 mm x 10 mm pictograms (e.g. due to several pictograms). These

1-cm

pictograms are the smallest allowed and can be used only if there is no space for

the larger ones. A pictogram of at least 16 mm x 16 mm must always be used if

possible. “If possible” refers to the size of the label and thus if the label size allows for a

larger pictogram, then this must be used. However, where a supplier chooses to use a

label that is larger than the minimum dimensions for a certain capacity of the package, it

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is not necessary to increase also the size of the pictogram, provided it covers one

fifteenth of the relevant minimum dimensions.

In principle, a label complying with the minimum dimensions set out above should be

large enough to contain all the label elements defined in CLP Article 17 while remaining

legible. Precedence must be given to the obligatory label elements and any obligatory

supplemental information required by the CLP Regulation and other EU legislation. If a

supplier chooses to add non-obligatory supplemental label elements, legibility may be

affected when more than just a small amount of such information is added. For larger

amounts of non-obligatory information the supplier should consider limiting this

information or increasing the size of the label. When the size of the label is increased,

the supplier should also consider increasing the size of the different obligatory label

elements. This should serve the purpose of facilitating their identification and

maintaining their legibility.

Any additional area gained by increasing the size of the label can be used for further

information which is considered important by the supplier. However, this should be

weighed against the requirement of CLP Article 25(3), namely that non-obligatory

supplemental information must not make it more difficult to identify the obligatory label

elements.

5.3 Exemptions from the labelling and packaging requirements

Not all packages allow the necessary labelling information on the label or on the

packaging to be displayed in line with the requirements of CLP Article 31.

CLP Article 29(1) and section 1.5.1 of Annex I to CLP provide derogations for a

packaging that is so small or in such a shape or form that it is impossible to meet the

requirements of CLP Article 31.

If the provisions of Article 29(1) cannot be applied, CLP Article 29(2) and section 1.5.2 of

Annex I to CLP allow the omission of certain label elements (see section 5.3.2 of this

guidance document).

5.3.1 Use of fold-out labels, tie-on tags and outer packaging

The packaging of a substance or mixture can be so small or in such a shape or form that

it is impossible to display the label elements in line with the requirements of CLP Article

31. This could be either because the Member State where the substance or mixture is

being placed on the market requires more than one language on the label, or simply

because the packaging is too small or difficult to label because of its form/shape so that

the full range of labelling elements even in a single language cannot be displayed.

Example:

For a container of a capacity > 50 litres, but ≤ 500 litres, the minimum size of a

pictogram must be 32 mm x 32 mm, which is one fifteenth of the area obtained by

multiplying the minimum dimensions (105 mm x 148 mm). (105 mm x 148 mm =

10.5 cm x 14.8 cm = 155.5 cm

. Then one fifteenth of 155 cm

= 10.36 cm2;

√10.36 cm

= 3.22 cm = 32.2 mm (rounded to 32 mm) for each dimension of each

pictogram). If the size of the label increases while the capacity of the container

remains the same (>50 litres, but ≤500 litres) the minimum size of each pictogram

should be at least one fifteenth of the minimum area related to obligatory

information required by CLP Article 17, i.e. 32 mm x 32 mm.

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In particular, it may be impossible for the label to be read horizontally when the package

is set down normally or the label elements are of insufficient size and spacing as to be

easily read.

In this situation the label elements defined in CLP Article 17 may be provided either on:

• fold-out labels; or

• tie-on tags; or

• outer packaging.

When one of the above-mentioned alternatives is used, the label on any inner packaging

or the part of the fold-out label that is directly attached to the packaging must contain at

least: the hazard pictogram(s), the product identifier referred to in CLP Article 18 and

the name and telephone number of the supplier of the substance or mixture. In this

case, the signal word, the hazard and precautionary statements as well as the

supplemental label information may be omitted. However, the use of these alternatives

is not allowed if a label becomes unreadable only because the supplier wishes to add

more languages on a label than are required in the Member State where the substance

or mixture is placed on the market.

5.3.1.1 Fold-out labels and tie-on tags

When a supplier recognises the need to use fold-out labels or tie-on tags, he should

consider the following aspects:

Compared to tie-on tags, the use of fold-out labels will probably be the preferred option

as this will offer most space for the label elements in many cases. Some information

relating to the content, quality and design of a fold-out label is given below. See also

Example 6 of this guidance document where a multilingual, fold-out label for a mixture

for supply and use is presented.

Fold-out labels can also be an option (and are in fact commonly used) when the amount

of obligatory supplemental labelling information required by other legislation would result

General requirements for fold-out labels and tie-on tags

The CLP Regulation does not foresee any separate provisions for tie-on tags or fold-

out labels. Both types of label must meet the same performance standards as any

other “normal” label, namely:

• the label elements (including the UFI, if applicable) must be indelible, easy to

read and stand out from the background;

• the size of the pictograms must be the same as the pictograms on the

equivalent, normal label.

The fold-out label or tie-on tag must be securely attached to the packaging, i.e. the

label remains attached to the packaging during reasonably expected handling of the

package.

At least the following CLP information must be firmly attached to the immediate

container:

• hazard pictograms,

• the product identifier,

• the name and telephone number of the supplier of the substance or mixture.

In addition, the UFI should be attached to the immediate container.

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in a label that is too large for the packaging. Fold-out labels may help clearly structure

the labelling information by using different pages for different types of information (see

below).

Content, quality and design of a fold-out label

Content

A fold-out label generally consists of three parts, namely the front page (top leaf), inside

page(s) and the back page (firmly attached to the packaging).

The label elements and information required by CLP Articles 17 and 32(6) should be

included on the fold-out label as described below. In accordance with CLP Article 29(1),

the labelling information can only be provided using fold-out labels when it is not

possible to meet the requirements of CLP Article 31 for a label in the languages of the

Member State in which the substance or mixture is placed on the market.

• The front page must contain at least:

o the product identifier (CLP Article 18(2) for substances, CLP Article

18(3)(a) for mixtures); Please note that for mixtures, the product

identifier on the front and back page does not need to specify all the

components contributing to the classification of the mixture;

o hazard pictogram(s) (CLP Article 17(1)(d));

o signal words in all languages of the label (CLP Article 17(1)(e));

o nominal quantity (packages made available to the general public, unless

specified elsewhere in the package) (CLP Article 17(1)(b));

o contact details of supplier(s) (name, address and phone number) (CLP

Article 17(1)(a));

o a reference to the full safety information inside the fold-out label, for

example: “safety information, see inside” in all languages of the label or a

symbol to inform a user that the label can be opened and to illustrate that

additional information is available on inside pages (not in CLP Article

17(1));

o an abbreviation of the language (country code or language code) for all

the languages that are used in the inside pages; to avoid non-standard or

confusing abbreviations it is recommended to use the language code

according to e.g. ISO 639-1;

• Inside page(s) should contain:

o full labelling information (except for the hazard pictogram and the supplier

identification) as required by CLP Article 17(1) (including supplemental

information) for each language mentioned on the front page and grouped

by language, for example one language per page;

o an abbreviation of the language featured at the top of each of the inside

pages (country code or language code).

• The back page should repeat the information given on the front page, except for

the indication of the different languages in the inner layers.

Regarding the UFI, it is advised to include it on the back page (i.e. attached to the

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immediate container) or affixed directly to the inner packaging right next to the other

labelling elements. This will allow the identification of the UFI in case when the other

pages of the fold-out label would for some reason no longer be attached.

In addition, it is recommended to include the UFI also on the front page to be easily

identifiable.

The use of several UFI codes on the same label is not recommended. A single UFI put on

the label should be notified in all MSs where the mixture is on the market. There is always

a possibility to notify a mixture in a “new” MS with a same “old” UFI which is already

notified in another MS, and this approach is highly recommended, giving possibility to

include only one UFI on the label. However, if different UFIs are used for different market

areas, the UFIs (with a country code in proximity) should be included in the inside pages

with the language or market area. The UFI relevant for each market area should be clearly

identifiable. It should be noted that no additional marker than “UFI:” should appear before

the actual UFI code. In exceptional circumstances, when the same label is used in different

countries where different UFIs are used, a country code should be used in proximity of the

UFI code.

Quality and design

There is no standard specified in CLP for label materials and performance of fold-out

labels. However, sufficient quality of the fold-out label needs to be ensured.

The exact manner in which this quality is ensured should be left to the discretion of the

supplier, but attention should be paid to the following aspects:

• Durability

Taking into account the different situations that may occur during normal

handling and use of the packaging (the contents of the package may dissolve the

printing or the users may read the label several times), it is clear that the fold-

out label must be sufficiently durable to maintain its functionality under repeated

use conditions (as applicable) for the entire life span of the product. This can be

achieved for example by protective coating of the label and using plasticised

pages.

The back page of a fold-out label should be firmly attached to the packaging to

resist normal handling and use. The pages should not be easily detachable from

each other.

• Readability

The information in the fold-out label should be easily read (see section 5.2 of this

guidance document). In the case of a booklet, page numbers can be considered.

The languages should be ordered in a logical way, e.g. alphabetically.

• Easy access to the information

The information on the fold-out label should be easily accessible by allowing easy

opening and reclosing of the label by the user. This can be ensured for example

by using a "Pull tab”, i.e. a small area of the label that allows lifting it easily from

its backing sheet. Easy access to the information (and readability) can also be

improved by featuring one language per inner page of the fold-out label.

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5.3.1.2 Outer packaging

When packaging is too small or in such a form or shape that the labelling requirements

of CLP Article 31 cannot be met, one of the options provided by CLP Article 29(1) is to

provide limited labelling information on the inner packaging (i.e., according to section

1.5.1.2 of Annex I to CLP, at least: hazard pictograms, product identifier and name and

telephone number of the supplier of the substance or mixture) while the full labelling

information (including the UFI) is provided on outer packaging. This may be useful in the

case of many small units within one outer packaging. In such cases, the requirements

that normally apply to labels (see CLP Articles 31 and 32) will also apply to the label area

on the outer packaging. When the outer packaging option is used, a distributor or

retailer has to take care that all the label elements required by the CLP Regulation are

available when he places the single package units individually on the market.

5.3.2 Omission of certain label elements

In situations where it is impossible to meet the labelling requirements of CLP Article 31

(because of the small size, shape or form) and the full label information

cannot be

provided in fold-out labels, on tie-on tags or on an outer packaging, the label information

may be reduced subject to certain conditions specified in section 1.5.2 of Annex I to

CLP. This can be the case for:

• packages where contents do not exceed 125 ml and the substance or mixture is

classified in one of the hazard categories listed in Table 7 below – this also refers

to situations when a substance or mixture is re-filled into small volume bottles

(125 ml or less) that are marketed afterwards, or when small volume bottles (125

ml or less) are no longer sold in outer packaging, but individually (see also section

5.3.2.1 of this guidance document);

• soluble packaging for single use where contents do not exceed 25 ml (see also

section 5.3.2.2 of this guidance document).

Label information may also be adapted for:

• inner packaging of substances and mixtures for scientific research and

development or quality control analysis when the contents do not exceed 10 ml

(see also section 5.3.2.3 of this guidance document);

• unpackaged hazardous substances or mixtures supplied to the general public (see

also section 5.3.2.4 of this guidance document);

• environmental labelling (see also section 5.3.2.5 of this guidance document).

5.3.2.1 Labelling of packages when the contents do not exceed 125 ml

The label elements mentioned in column 2 of Table 7 may be omitted from the label of

packages that do not exceed 125 ml of capacity when the substance or mixture is

classified for the hazard classes or categories listed in column 1.

However, when the substance or mixture is classified for further hazard classes not listed

in column 1 of Table 7, the label elements related to these other hazard classes still need

to be included. Please refer also to section 1.5.2.1 of Annex I to CLP.

i.e. the information required by CLP Article 17.

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It should be noted that the exemptions regarding the labelling of small packages of

aerosols classified as flammable (Directive 75/324/EEC

) apply to aerosol dispensers.

Table 7: Labelling exemptions for packages of a capacity of 125 ml or less

Classification of the substance or mixture

Allowed omissions according to

section 1.5.2 of Annex I to CLP

Oxidising gases cat. 1 (H270)

Gases under pressure (H280, H281)

Flammable liquids cat. 2 or 3 (H225, H226)

Flammable solids cat. 1 or 2 (H228)

Self-reactive substances or mixtures, types C, D, E or F (H242)

Self-heating substances or mixtures, cat. 2 (H252)

Substances and mixtures which, in contact with water, emit

flammable gases, cat. 1, 2 or 3 (H260, H261)

Oxidising liquids cat. 2 or 3 (H272)

Oxidising solids cat. 2 or 3 (H272)

Organic peroxides, types C, D, E or F (H242)

Acute toxicity cat. 4 (H302, H312, H332)

(if the substance or mixture is not supplied to the general public)

Skin irritation cat. 2 (H315)

Eye irritation cat. 2 (H319)

STOT-SE cat. 2 or 3 (H371, H335, H336)

(if the substance or mixture is not supplied to the general public)

STOT-RE cat. 2 (H373)

(if the substance or mixture is not supplied to the general public)

Hazardous to the aquatic environment – short-term (acute)

aquatic hazard, cat. Acute 1 (H400)

Hazardous to the aquatic environment – long-term (chronic)

aquatic hazard, cat. Chronic 1 or 2 (H410 or H411)

hazard and precautionary

statements for the hazard classes

listed in column 1

comment: the hazard pictogram

and signal word are required for

the denoted hazard categories

Flammable gases cat.2 (H221)

Reproductive toxicity: effects on or via lactation (H362)

Hazardous to the aquatic environment – long-term (chronic)

aquatic hazard, cat. Chronic 3 or 4 (H412 or H413)

precautionary statements linked to

the hazard classes listed in column 1

comment: the hazard statements

and signal word must be provided

as no hazard pictogram is required

for the denoted hazard categories

Corrosive to metals (H290)

hazard pictogram, signal word,

hazard and precautionary

Council Directive 75/324/EEC of 20 May 1975 on the approximation of the laws of the Member

States relating to aerosol dispensers, as amended.

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Classification of the substance or mixture

Allowed omissions according to

section 1.5.2 of Annex I to CLP

statements for this hazard class

5.3.2.2 Labelling of soluble packaging for single use which does not

exceed a volume of 25 ml

The soluble packaging exemption applies to soluble packaging when the content does

not exceed a volume of 25 ml. For such packaging, the CLP label elements required by

CLP Article 17 may be omitted provided the packaging is intended for single use and it is

contained within an outer packaging that bears all the label elements required by CLP

Article 17.

The exemption applies in cases where the substance or mixture contained is classified

exclusively for one or more of the hazards categories in sections 1.5.2.1.1 (b), 1.5.2.1.2

(b) or 1.5.2.1.3 (b) of Annex I to CLP (see Table 7 above). However, this exemption

does not apply to substances and mixtures within the scope of Regulation (EC)

1107/2009 (for plant protection products) or Regulation (EU) No 528/2012 (for biocidal

products).

5.3.2.3 Labelling of inner packaging when the contents do not exceed 10

The CLP label elements required by CLP Article 17 may be omitted from the inner

packaging provided that all the following conditions are met:

• the contents of inner packaging do not exceed a volume of 10 ml;

• the substance or mixture is placed on the market for supply to a distributor or

downstream user for scientific research and development (SR&D)

or quality

control analysis; and

• the inner packaging is contained within an outer packaging that contains all the

label elements required by CLP Article 17.

However, it should be noted that the label on inner packaging must contain the product

identifier and (if appropriate) the hazard pictograms; GHS01, GHS05, GHS06 and/or

GHS08. In case more than two pictograms are assigned, GHS06 and GHS08 may take

precedence over GHS01 and GHS05.

The exemption does not apply to substances and mixtures within the scope of Regulation

(EC) 1107/2009 (for plant protection products) or Regulation (EU) No 528/2012 (for

biocidal products).

5.3.2.4 Unpackaged hazardous substances or mixtures supplied to the

general public

Labelling information about unpackaged chemicals sold to the general public must be

made available to the customer, e.g. on an invoice or bill (see CLP Article 29(3)). When

the purchase of such substances or mixtures occurs at a different point in time than their

delivery to the customer, one might also consider providing a leaflet that contains the

For more information on substances manufactured, imported or used in scientific Research and

Development (SR&D) please consult ECHA Guidance on Scientific Research and Development

(SR&D) and Product and Process Orientated Research and Development (PPORD).

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relevant labelling information when delivering the substance or mixture, or sending the

information electronically before or upon delivery. CLP Article 29(3) provisions apply to

substances listed in Part 5 of Annex II to CLP).

5.3.2.5 Environmental labelling

CLP includes the possibility to introduce exemptions from certain provisions on

environmental labelling for certain mixtures classified as hazardous to the environment

when it can be demonstrated that there would be a reduction in the environmental

impact (see CLP Article 29(4)). However, no such exemptions or specific provisions have

been agreed to date. Once determined in accordance with the procedure referred to in

CLP Articles 53 and 54, such exemptions or specific provisions would be defined in Part 2

of Annex II to CLP.

5.3.3 Labelling exemptions for bespoke paints

An exemption for bespoke paints is provided for in CLP Annex VIII, part A, point 2.2a.,

allowing formulators (when they have the submitters’ obligations under Article 45 and

Annex VIII for mixtures classified for health or physical hazards) of such mixtures, when

they wish so, to opt not to submit information under Annex VIII for the final paint as

supplied to consumers or professional users. Therefore, in these cases there is also no

obligation to create and include a UFI for the final paint on the label. See further details

in Guidance on harmonised information relating to emergency health response – Annex

VIII to CLP.

Bespoke paints, for the purposes of Annex VIII, are paints where the addition of colour,

i.e. tinting, takes place on demand (by a specific customer – consumer or professional

user) at the point of sale. The mixture used to form the foundation for a paint is the

‘paint base’ and the substance or mixture used to colour the paint is the ‘tinter’

When information has not been submitted on the final bespoke paint (and therefore no

UFI has been generated for this final mixture), the UFI of the paint base and of all the

tinter mixtures subject to Annex VIII and added to the bespoke paint are required to be

included on the label of the bespoke paint. There is no need to include the UFIs of tinter

mixtures present in the final paint below a concentration of 0.1%.

It should be noted that if the concentration of a mixture with a UFI (regardless of its

function, i.e. tinter or paint base) in the bespoke paint exceeds 5 %, the concentration

(exact value or range) of that mixture must also be indicated next to its UFI, in

accordance with section 3.4. of Part B of Annex VIII.

The UFIs of all the bespoke paint’s components must be included in the supplemental

information on the label and listed in descending order of concentration. If the final

bespoke paint has a different classification than the paint base, the label of the bespoke

paint has to be updated to reflect it.

For practical reasons, it is also allowed to include on the label of the final mixture (often

this is the same as that of the paint base) only the UFI of the paint base, as long as UFIs

of the tinters are shown on the container, close to the other CLP label information. The

paint base normally constitutes the main part of the final mixture and is likely to be the

most relevant for emergency response. The UFIs of all the tinters that are required to be

indicated, can be indicated in a space left for them on the label of the paint base, or on a

More details and definitions are provided in the Guidance on Annex VIII.

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sticker placed on the container outside of the paint base label (see Example 14 in section

6.3 of this Guidance document). In practice, this means that it is possible to apply the

widely used practice of placing information on the colours used in the final paint on a

separate sticker, printed directly from the tinting machine, for including the relevant

UFIs of the used tinter mixtures on this same sticker. The sticker needs to be placed

next to the other label elements and in a location where the UFIs can easily be seen and

identified, also during the use of the product. In very specific situations, where the

container is too small to accommodate the information related to the tinters, and other

alternative options are not applicable (e.g. according to Article 29), it may be considered

to include the tinters’ UFIs on a sticker placed on the lid, as in such a situation

placement on the lid can also be considered as ‘right next to the other label elements’

and may be a better solution than covering other essential information. When using the

option of placing the tinter-information on the lid, it is strongly recommended to indicate

the colour code both on the container and on the lid, in order to allow the identification

of the correct lid in case the lid and the container get separated. This would reduce the

risk of providing misleading information to the emergency operator.

5.4 Interaction between the CLP and the transport labelling rules

5.4.1 Specific rules for labelling of outer packaging, inner packaging and

single packaging

Article 33 of the CLP Regulation sets out specific rules for situations where the packaging

of hazardous substances and mixtures is also required to meet the labelling provisions in

accordance with the rules on the transport of dangerous goods. The transport labelling

provisions are set out in the UN Recommendations on the Transport of Dangerous Goods

– Model Regulations. Transport labelling as referred to in CLP Article 33 includes all

labels and marks required by e.g. Directive 2008/68/EC

, for example the mark for

environmentally hazardous substances, elevated temperature marks and

limited/exempted quantities marks. A basic principle of the CLP Regulation is not to

override any labelling required by the transport rules while maintaining essential hazard

information on the relevant layer(s) of packaging.

When a package consists of an outer and an inner packaging, together with any

intermediate packaging, and the outer packaging meets the labelling provisions in

accordance with the rules on the transport of dangerous goods, the hazard pictograms

required by the CLP Regulation do not need to appear on the outer packaging. As

mentioned above, the limited/excepted quantity marks are considered as transport

Directive 2008/68/EC for the inland transport of dangerous goods (road and rail).

CLP labelling is normally required on every layer of a packaging intended for supply

and use.

Transport labelling will have to appear on the outer packaging of hazardous

substances and mixtures if these are “dangerous goods” according to the rules on the

transport of dangerous goods. In such cases, a CLP label may also appear on an outer

packaging.

Single packages need to carry both the CLP label and transport labelling. If a CLP

hazard pictogram on single or outer packaging relates to the same hazard as in the

rules for the transport of dangerous goods, the CLP pictogram may be omitted to

avoid unnecessary double labelling.

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labelling. Therefore, a CLP label is not required when those marks are carried on the

outer packaging. CLP labelling may however be used if desired, according to CLP Article

33(1).

Where the outer packaging is transparent, all CLP label elements can be omitted from it

where the CLP label beneath the transparent layer is clearly visible (CLP Article 33(2)).

The legal requirements of CLP Article 33 and the decisions involved when dealing with

them are depicted in Figure 3.

Figure 3: Decision flowchart for the application of CLP and transport labelling for

single packaging (left) and combination packaging (right)

5.4.2 Packaging used for consolidation of supply packaging during

transport

The CLP Regulation sets general packaging standards for suppliers to ensure the safe

supply of hazardous substances and mixtures.

‘Packaging’ is defined in the CLP Regulation as “one or more receptacles and any other

components or materials necessary for the receptacles to perform their containment and

other safety functions”. This means that the packaging of a substance or mixture can

comprise multiple layers, for instance a bottle and a box.

CLP rules apply to all layers of packaging used for supply purposes. Any further

packaging may then fall under the definition given in the transport legislation: “the

outer protection of a composite or combination packaging together with any absorbent

material, cushioning and any other components necessary to contain and protect inner

receptacles or inner packaging”. The function of outer packaging fulfilling this definition

will remain the same whether or not a transport label is affixed to it.

Transport

Inner (and any

intermediate) and outer

packaging

Transport

label

required?

Yes

Transport

label

required?

Transparent

outer

packaging?

Yes

Single packaging

CLP label

Transport label

and CLP label

CLP pictograms

covered by an

equivalent

transport

pictogram may

be omitted.

CLP label on

inner (and any

intermediate)

and outer

packaging (see

also section

5.4.2 below)

CLP label on

inner (and any

intermediate)

packaging

CLP label on

outer packaging

may be omitted.

Transport label on outer

packaging; CLP label on

inner (and any

intermediate)

packaging

The outer packaging

may additionally be CLP

labelled. If so, the CLP

pictograms covered by

an equivalent transport

pictogram may be

omitted.

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CLP Article 33(2) should be interpreted as meaning that labelling according to CLP is

required for the outermost layer of packaging that remains when the transport

packaging is removed (and, as the case may be, to the inner and intermediate

packaging). This type of ‘outer’ packaging (illustration (b) in Figure 4) requires a CLP

label (see also section 5.3.1.2 and section 5.4.1 of this guidance document).

Figure 4: Application of CLP labelling on packaging used for supply and transport

Normally, suppliers, including distributors, use one and typically more additional layers of

packaging to make the transport of multiple chemicals more convenient and to ensure that

the correct products are delivered to each location in good condition. Such transport

packaging (illustration (c) on Figure 4), used for the purpose of:

• protection of supply packages during transport and handling, and/or

• consolidation (combining several supply packages into a larger load for

transport),

is thus outside the scope of the CLP Regulation and does not require a CLP label.

Where substances or mixtures are stored on site without being removed from their

transport packaging as they are awaiting further transport, other labelling

obligations outside the scope of CLP and the transport legislation may continue to apply,

for example, a workplace risk assessment under the scope of the worker protection

Framework Directive (89/391/EEC) and associated individual directives including the

Chemical Agents Directive (98/24/EC

), Carcinogens and Mutagens Directive

(2004/37/EC

) and, as appropriate, the safety and/or health signs according to

Council Directive 98/24/EC of 7 April 1998 on the protection of the health and safety of workers

from the risks related to chemical agents at work (OJ L 131, 5.5.1998, p. 11–23), amended by

Directive 2007/308/EC and Directive 2014/27/EU.

Directive 2004/37/EC of the European Parliament and the Council of 29 April 2004 on the

protection of workers from the risks related to exposure to carcinogens or mutagens at work (OJ L

158, 30.4.2004, p. 50) amended by Directive 2007/308/EC and Directive 2014/27/EU.

(a)

inner packaging

for supply

(b)

outer packaging

for supply

(c)

transport packaging

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Directive 92/58/EC

. However, once the substances or mixtures are no longer in

transport they must be removed from the transport packaging to enable the CLP label

to be clearly seen, or a CLP label must be added to what was previously the transport

packaging.

Council Directive 92/58/EEC of 24 June 1992 on the minimum requirements for the provision of

safety and/or health signs at work (OJ L 245, 26.8.1992, p.23), amended by Directive

2007/308/EC and Directive 2014/27/EU.

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6. Example labels

In this section, 13 examples are provided to illustrate different situations that may be

encountered when designing labels.

Please note that each of the labels below serves only as an example of how to arrange

the elements on the label in a given situation. The examples given are not exhaustive

or mandatory in all aspects and do not reflect specific uses. The dimensions of labels and

label elements shown below are not necessarily the actual dimensions.

Example 1: Single language label for a substance (not for the

general public)

This example represents a simple label for a substance for supply and use which takes

into account the CLP label elements only. It shows the CLP terminology and pictograms

in accordance with CLP Article 17(a) and (c) to (g), i.e. the product identifiers, the

identity of the supplier, the signal word, the hazard pictograms, the hazard and the

precautionary statements. As the substance is not supplied to the general public, the

nominal quantity of the substance contained in the package is not required on the label.

Highly flammable liquid and vapour. May be fatal if swallowed and

enters airways. Causes skin irritation. May cause drowsiness or

dizziness. Very toxic to aquatic life with long lasting effects.

Keep away from heat, hot surfaces, sparks, open flames and

other ignition sources. No smoking. Keep container tightly closed.

Store in a well-ventilated place. Avoid breathing mist/vapours.

Wear protective gloves and eye and face protection.

IF INHALED: Remove person to fresh air and keep comfortable

for breathing. Avoid release to the environment.

Hazard pictograms

Product identifiers

Signal word

Supplier identity

Hazard statements

Precautionary

statements

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Considering the industrial/professional use, the combined statement P301 + P310 has

been omitted from the label. To further reduce the number of P-statements and the

amount of digestible information on the label, the statement P391 has also been omitted

from the label, as the prevention statements for the physical and health hazards appear

to contain the more urgent advice for the label. The final selection of the P-statements

resulted in six P-statements compared to the starting set of eight P-statements.

The selected P-statements would have to be included in the SDS, under heading 2.2

(“Label elements”). The de-selected statements can be introduced under the relevant

headings of the SDS to provide the industrial or professional user with sufficient

information to handle the substance safely.

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Example 2: Multi-language label for a substance containing non-

obligatory supplemental information (not for the general public)

The example label given below represents a multi-language label for supply and use. It

shows the CLP terminology and pictograms in accordance with CLP Article 17(a) and (c)

to (h), i.e. the product identifier, the identity of the supplier, the hazard pictograms, the

signal words and the hazard and precautionary statements in four languages.

As the substance is not supplied to the general public, the nominal quantity of the

substance contained in the package is not required on the label.

In accordance with CLP Article 32(3), the hazard and precautionary statements of one

language are located together on the label. A section for supplemental labelling is

included on the left-hand side of the label including non-obligatory supplemental

labelling information.

As to the lay-out, the label is an authentic label designed for a 2.5 litre bottle. Given that

the real dimensions are slightly larger than depicted here, there is still potential to

optimise the structuring of the information, e.g. by using a more prominent place for the

signal word or larger letters for H- and P-statements. Based on the minimum dimensions

for the label area, which would be at least 52 mm x 74 mm, the size of each of the

pictograms is supposed to be at least 257 mm

, corresponding to a side length of 16

mm, on the real label (see section 5.2 of this guidance document).

If the content of the part for supplemental labelling is increased (for example to

incorporate information related to the use of the substance), the overall area of the label

and the size of its elements may have to be increased as well, in particular the letter size

for the signal words, hazard and precautionary statements. Such an increase would

improve the legibility of the obligatory label information, which appears in multiple

languages. In this case, it may be wise also to increase the size of the pictograms.

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Hazard pictograms

Product identifiers

Signal word

Supplier identity

Section for

supplemental

labelling

information

(non-obligatory)

Hazard and

Precautionary

statements,

grouped by

language

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Example 3: Single language label for a mixture containing both

obligatory and non-obligatory supplemental information (supplied

to the general public)

The example label given below illustrates the supply and use label for a typical consumer

product (detergent).

All obligatory labelling information is shown, i.e. the product identifiers (trade name and

designation of the mixture; one of them would have been sufficient), the identity of the

supplier, the signal word, the hazard and precautionary statements and the obligatory

supplemental information, in accordance with Regulation (EC) No 648/2004 on

detergents, and including the UFI code. Please note that supplemental labelling

information according to CLP is grouped together whilst the other supplemental

information (in this case the bar code) is located in another place. The UFI can

alternatively be placed outside the label (e.g. printed or affixed on the inner packaging)

but right next to the other obligatory CLP label elements.

No P-statement on disposal is given as this is not required for a mixture classified as eye

irritant.

As the product is supplied to the general public, its nominal quantity is also provided on

the label. Beyond the obligatory supplemental information, also some non-obligatory

supplemental information is shown.

This label clearly separates the obligatory information as required by the CLP Regulation

and other Community legislation from the non-obligatory elements. The former is

delineated by two text boxes, with the “CLP box” being located in a central, eye-catching

position on the label. The non-obligatory label elements can be found in the lower part of

the label and in the upper part, under the headline “instructions for use”.

The label as depicted here has a real size of 165 mm x 72 mm; the area of the label that

contains the obligatory label elements, i.e. the two boxes and the nominal quantity, is

about 98 mm x 72 mm. In principle the area covered by the text block “For further

information visit …” must be subtracted; on the other hand, approximately the same

area covered by the line “trade name” should be added, so there is no change overall.

The label is larger than the minimum dimensions required by the CLP Regulation, which

is at least 52 mm x 74 mm for a 500 ml bottle. The pictogram complies with the

reference minimum area of 16 x 16 mm.

The label shown is primarily drafted for inner packaging. If the chemical is contained in

combination (= inner + outer) packaging, the same information has to be shown on the

outer packaging, unless the information on the inner packaging can be seen through the

outer packaging.

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Hazard pictogram

Product identifiers

(trade name and

designation of the

mixture)

Signal word

Supplier identity

Hazard statement

Precautionary

statements

Nominal quantity

Product identifier

(designation of the

mixture)

Non-obligatory

supplemental

information

(here: identified

uses)

Obligatory

supplemental

information

Non-obligatory

supplemental

information

UFI: VDU1-414F-1003-1862

UFI code

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Example 4: Single language label for a substance containing

supplemental hazard statements (not for the general public)

The example below illustrates a label for a substance for supply and use. A harmonised

classification (Water-react. cat. 1, Skin corr. cat. 1B) as well as the supplemental hazard

statement EUH014 are assigned through Annex VI to CLP. No other available, reliable

information was found that identified any further hazards. The substance is not intended

to be used by the general public; it is supplied in a 1 litre package.

All obligatory labelling information is shown, i.e. the product identifiers, the identity of

the supplier, the hazard pictograms, the signal word, the hazard and the supplemental

hazard statement EUH014, in accordance with Table 3 of Annex VI to CLP. Although

EUH014 is supposed to be supplemental information only, it is intentionally placed close

to the regular CLP hazard statements to reinforce the message provided by the latter.

Substance Z

EC No 123-123-1

Wear protective gloves / protective clothing / eye protection/face protection.

IF ON SKIN: Brush off loose particles from skin. Immerse in cool water. IF SWALLOWED:

Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor. IF

ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water

or shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy to do. Continue rinsing.

Company X, Street Y, CITY ABC,

phone number: +49 (0) 0000 00 00 00.

Hazard pictograms

Signal word

Supplier identity

Hazard statements

Precautionary

statements

Supplemental

hazard statement

EUH014

Product identifiers

Danger

Reacts violently with water.

In contact with water releases

flammable gases which may ignite

spontaneously.

Causes severe skin burns and eye

damage.

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Example 5: Multi-language label for a mixture containing both

obligatory and non-obligatory supplemental information (supplied

to the general public)

Example 5 represents a draft multi-language label for a typical consumer chemical

(decorative paint) for supply and use.

All obligatory labelling information is shown, i.e. the product identifiers, the identity of

the supplier, the signal word, the hazard and precautionary statements and the

obligatory supplemental information, in particular information in accordance with

Directive 2004/42/EC on the limitation of emissions of volatile organic compounds

(VOCs) due to the use of organic solvents in certain paints and varnishes and vehicle

refinishing products, and including the UFI code (in this example, the same UFI code has

been used in the submission in each Member State). The UFI can alternatively be placed

outside of the label (e.g. printed or affixed on the inner packaging) but right next to the

other obligatory CLP label elements. As regards to the multi-language label in several

MSs, it should be clearly stated on the label to which country the specific UFI applies,

unless the same apply(ies) to all countries where the mixture is placed on the market. In

cases where a different UFI is used in each Member State (not recommended), it has to

be clear which UFI is relevant for each Member State (e.g. the relevant UFI with a

country code should be placed with the label elements of the applicable language(s) of

that Member State).

In accordance with CLP Article 32(3), the hazard and precautionary statements of one

language are located together on the label. As the chemical is supplied to the general

public, its nominal quantity is also provided on the label. Beyond the obligatory label

elements, non-obligatory supplemental information is shown.

This example label separates the CLP label elements from the supplemental information.

The CLP label elements are located in a more eye-catching position on the label while the

supplemental information can be found rather in the margins of the label. The texts

reflecting the supplemental information appear in slightly smaller letters than the CLP

label elements.

The size of this label is intended to be 125 mm x 150 mm when applied on the

packaging. This means that the real label will be considerably larger than the minimum

label size for a 1 litre package (52 x 74 mm) required under the CLP Regulation. The

pictogram size of 19 x 19 mm is less than 1/15

of the area of the whole label, but

greater than 1/15

of the area dedicated to the information required by CLP Article 17.

Guidance on Labelling and Packaging

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UFI code

Signal word, hazard

and precautionary

statements in three

languages

Hazard pictogram

Product identifiers

Non-obligatory

supplemental

information

Supplier identity

Nominal quantity

Non-obligatory

supplemental

information

Obligatory supplemental

information according to

the VOC Directive

Signal word

00000

UFI: VDU1-414F-1003-1862

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Example 6: Fold-out label for a mixture (supplied to the general

public)

The example below represents a multilingual, fold-out label for a mixture for supply and

use, intended for the general public.

The label for this mixture is required to bear a large number of obligatory CLP label

elements, namely three hazard pictograms, three hazard statements and numerous

precautionary statements subject to the principles of precedence. It was impossible to

put all these label elements on the immediate container due to its shape and size (plastic

container of 100 ml capacity). The supplier cannot accommodate on a standard label the

required information in the official language of the Member State where the product is

placed on the market (Poland). Because of this, the supplier has chosen to use a fold-out

label. This way, the supplier can also include the two additional languages they consider

necessary in this case. The label elements are included on the label in the following way:

Front page

• trade name or designation,

• hazard pictograms,

• signal words in all languages of the label,

• nominal quantity, as the mixture is made available to the general public,

• contact details of supplier,

• reference to the full safety information inside (in this case the front page contains

the symbol of an arrow to illustrate that the full safety information is available on

inside pages),

• country codes indicating which languages are covered by the label,

• UFI code (in this case, the same UFI code has been included in the submission in

each Member State). The UFI can alternatively be placed outside of the label (e.g.

printed or affixed on the inner packaging) but right next to the other obligatory

CLP label elements.

Inside pages

• full product identifier (including hazardous compounds A, B and C in this

particular case),

• signal word,

• hazard statements,

• precautionary statements,

The full safety information on the inside pages is given in each language mentioned

on the front page and also grouped by language. The country codes are featured on

the top of each inner page to enable the user to quickly identify his language.

Back page (attached to the immediate container)

• trade name or designation,

• hazard pictograms,

• signal word,

• nominal quantity,

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• contact details of supplier,

• UFI code (only one code has been included in the submission in each Member

State).

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Version 4.2 – February 2021

UFI code

UFI: VDU1-414F-1003-1862

Signal

word

Supplier

identity

Hazard

statements

Trade name

Inside

pages

Language

code

Hazard

pictograms

Nominal

quantity

Precautionary

statements

Signal

word in all

languages of

the label

Language

codes

indicating

languages

covered by

the label

Front page

wrapped

around

the container

Symbol informing

the user that the label

can be opened and

indicating that the

additional information

is available on inside

pages

Product identifier

including three

hazardous

components that

contribute to the

classification of the

mixture

Back page

firmly affixed

to the

immediate

container

UFI code

UFI: VDU1-414F-1003-1862

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Version 4.2 – March 2021

6.1 Packaging that is small or difficult to label

The example labels in this section are authentic; they are applied on inner packaging

only because the package is transported in larger consignments with specific outside

labelling in accordance with the rules on the transport of dangerous goods. Please note

that the labelling exemptions only apply if the alternative labelling on fold-out labels, tie-

on tags or outer packaging is technically not feasible.

Example 7: Substance in a 8 ml bottle (not for the general public)

The example given below represents a two-language label in Finnish and Swedish for

small packaging for the substance. Both languages are required in Finland. According to

Annex VI to CLP, the substance is assigned the following classifications:

Flam. Liq. 2 H225 Highly flammable liquid and vapour

Repr. 2 H361 Suspected of damaging fertility or the unborn child (state

specific effect if known) (state route of exposure if it is conclusively

proven that no other routes of exposure cause the hazard))

Asp. Tox. 1 H304 May be fatal if swallowed and enters airways

STOT-RE 2 H373 May cause damage to organs (state all organs affected, if

known) through prolonged or repeated exposure (state route of

exposure if it is conclusively proven that no other routes of

exposure cause the hazard)

Skin Irrit. 2 H315 Causes skin irritation

STOT SE 3 H336 May cause drowsiness or dizziness

Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects

Based on CLP Article 17, many labelling elements would be required. The bottle

containing the substance is placed on the market individually. Since it is assumed for

this example that the labelling information cannot be accommodated on a fold-out label,

tie-on tag or on outer packaging, the supplier is allowed to apply the small packaging

exemptions outlined in section 1.5.2 of Annex I to CLP.

Accordingly, the hazard and precautionary statements pertaining to the following hazard

classes and categories:

Flam. Liq. 2, STOT-RE 2, Skin Irrit. 2, STOT-SE 3 and Aquatic Chronic 2

may be omitted from the label. However, and in line with the CLP Regulation, the hazard

pictograms:

GHS02, GHS07, GHS08 and GHS09

were retained for these hazards.

No small packaging exemptions apply to the following hazards classes and categories:

Repr.2 and Asp. Tox. 1. This means that the pictograms and the hazard and

precautionary statements pertaining to these hazard classes and categories have been

retained.

The precautionary statements have obviously been reduced, following CLP Articles 22

and 28. For example, the statement P501 (“Dispose of contents/container to…”) was not

included because the substance is not supplied to the general public and there are no

specific disposal requirements above the normal expectation for the disposal of

chemicals (see also section 7 of this guidance document). Out of a set of originally 20

different precautionary statements, only one single (combination) statement, namely

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P301+P310+P331 (“IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do

NOT induce vomiting.”) finally remains on the label.

In accordance with CLP Article 32(3), the hazard statements of one language as well as

the precautionary statements, respectively, are located together on the label. Finally, the

signal word “Danger” (Finnish: Vaara; Swedish: Fara) was selected, in line with the

applicable precedence rule.

If the real dimensions of the label are 32 mm x 95 mm, it can accommodate four

pictograms of the required minimum size of 1 cm

. This may not always be possible for

even smaller packaging volumes, e.g. a bottle volume of 4 ml (see below). In order to

maintain the required minimum size of 1 cm

for the hazard pictograms in such cases,

either the size of the label or the volume of the bottle as such will have to be increased.

It may not be warranted to reduce the letter size of the texts as this will very probably

decrease their legibility.

Small packaging exemptions:

reduced set of hazard and

precautionary statements, grouped

together on the label by language

No omissions, but full range of

hazard pictograms

Due to space constraints on small volume

packaging, pictograms of the required

minimum size of 1 cm

cannot always be

accommodated. In this case, either the

size of the label or the volume of the

bottle will have to be increased.

Guidance on Labelling and Packaging

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Example 8: Hazardous solid substance in a 100 ml bottle (not

intended for the general public)

This example represents a one-language label for small packaging for a solid substance

Y, which is assigned the following classifications:

Ox. Sol. 2 H272 May intensify fire; oxidiser

Carc. 1B H350 May cause cancer (state route of exposure if it is

conclusively proven that no other routes of exposure cause

the hazard)

Muta 1B H340 May cause genetic defects (state route of exposure if

it is conclusively proven that no other routes of exposure

cause the hazard)

Repr. 1B H360 May damage fertility or the unborn child (state specific

effect if known) (state route of exposure if it is conclusively

proven that no other routes of exposure cause the hazard)

Acute Tox. 2 (inhalation) H330 Fatal if inhaled

Acute Tox. 3 (oral) H301 Toxic if swallowed

STOT RE 1 H372 Causes damage to organs (state all organs affected, if

known) through prolonged or repeated exposure (state

route of exposure if it is conclusively proven that no other

routes of exposure cause the hazard)

Acute Tox. 4 (dermal) H312 Harmful in contact with skin

Skin Corr. 1B H314 Causes severe skin burns and eye damage

Resp. sens. 1 H334 May cause allergy or asthma symptoms or breathing

difficulties if inhaled

Skin sens. 1 H317 May cause an allergic skin reaction

Aquatic Acute 1 H400 Very toxic to aquatic life

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects

Pursuant to CLP Article 17, a lot of labelling information would be required. Similarly to

the previous example, it is assumed that the supplier is allowed to use the small

packaging exemptions outlined in section 1.5.2 of Annex I to CLP.

Substance Y is not presumed to be listed in Annex VI to CLP, nor in the Classification and

Labelling Inventory. Therefore, only the product identifiers referred to in CLP Article

18(2)(c) need to be provided, i.e. the CAS number (if available, see CLP Article

18(2)(d)) and the IUPAC or another international name.

In accordance with the small packaging exemptions outlined in section 1.5.2 of Annex I

to CLP, only the hazard and precautionary statements pertaining to the following hazard

classes and categories:

Ox. Sol. 2, Acute Tox. 4, Aquatic Acute 1, and Aquatic Chronic 1

may be omitted from the label. This means that for all the other hazards listed above all

the label elements that are required under CLP Title II have to appear on the label.

The precautionary statements on the example label below start with “Obtain special

instructions before use.” A significant reduction has been performed for the

precautionary statements, based on CLP Articles 22 and 28. After application of the small

packaging exemptions and the selection of the most appropriate set of precautionary

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statements, only five (combined) statements were chosen for the label, out of about 30

precautionary statements.

In addition to the hazard and precautionary statements, five different hazard pictograms

are required for the label, namely GHS03, GHS05, GHS06, GHS08 and GHS09.

Due to the severity of the hazards,

substantial reduction of the hazard

statements is not possible.

The number of the precautionary

statements however, has been

substantially reduced.

Guidance on Labelling and Packaging

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Example 9: Supply and transport label for a single package (not

intended for the general public)

This example illustrates the provisions of CLP Article 33(3) and represents a label for a

hazardous mixture that is assigned the following classification:

Flam. Liq. 2 H225 Highly flammable liquid and vapour

Acute Tox. (dermal) 3 H311 Toxic in contact with skin

Skin Irrit. 2 H315 Causes skin irritation

STOT SE 3 H335 May cause respiratory irritation

STOT SE 3 H336 May cause drowsiness or dizziness

STOT RE 2 H373 May cause damage to organs (state all organs

affected, if known) through prolonged or repeated exposure

(state route of exposure if it is conclusively proven that no

other routes of exposure cause the hazard)

Asp. Tox. 1 H304 May be fatal if swallowed and enters airways

Aquatic Acute 1 H400 Very toxic to aquatic life

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects

The mixture is intended to be supplied in single packaging, such as a 200-litre drum.

This means that both the CLP and the transport label elements must be shown on the

packaging. The mixture is for industrial use and not intended to be used by the general

public.

In this case, the supplier has chosen to include the transport label elements and marks

together with the CLP labelling elements on a joint label. This common label and the font

size used would be large enough to conform to the specifications set out in the European

Agreement concerning the International Carriage of Dangerous Goods by Road (ADR)

that has been implemented within the EU through Directive 2008/68/EC.

In relation to the CLP hazard pictograms GHS06 and GHS07, only GHS06 needs to be

displayed, in accordance with the precedence rule set out in CLP Article 26(1)(b).

However, the supplier has omitted the CLP hazard pictograms GHS06, GHS09 and

GHS02, as the underlying hazard classes and categories are already covered by the

corresponding transport pictograms.

In this example, the UFI is indicated on the label. However, for hazardous mixtures that

are subject to the submission of information under CLP Article 45, when they are

supplied for use at industrial sites the UFI can alternatively be indicated in the SDS only.

Guidance on Labelling and Packaging

Version 4.2 – March 2021

TOXIFLAM

(Contains X, Y)

UFI: VDU1-414F-1003-1862

Danger

Highly flammable liquid and vapour.

Toxic in contact with skin.

Causes skin irritation.

May cause respiratory irritation.

May cause damage to liver, testis through

prolonged or repeated exposure.

May be fatal if swallowed and enters airways.

Very toxic to aquatic life with long lasting effects.

May cause drowsiness or dizziness.

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources.

No smoking. Wear protective gloves and clothing

and eye protection. IF SWALLOWED: Immediately

call a POISON CENTER/doctor. Do NOT induce vomiting.

Avoid release to the environment.

Dispose of container to the municipal collection point.

See safety data sheet for further details regarding safe use.

Manufactured by

Company X,

Street Y,

Town Z

Code 00000,

Tel: +49(0)0000000000.

UNXXXX

[Proper Shipping Name]

Product

identifier

CLP hazard

pictogram

Transport

labelling

Supplier

identity

Signal word

Hazard

statements

Precautionary

statements

Space for

further

supplemental

information

(e.g.

instructions

for use)

Product

identifier

including

substances

that

contribute to

the

classification

of the mixture

as acutely

toxic, STOT-

RE and toxic

by aspiration

UFI code

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Example 10: Labelling for a mixture that is transported on land in

outer and inner packaging (not intended for the general public)

This example illustrates the labelling of a transported mixture classified as:

Flam. Liq 3 H226 Flammable liquid and vapour

Acute Tox. 4 H312 Harmful in contact with skin

Acute Tox. 4 H332 Harmful if inhaled

Skin Irrit. 2 H315 Causes skin irritation

The mixture is contained in an inner packaging (bottles) that is in turn contained in an

outer packaging (box), which is not transparent. The mixture is for professional users

and not intended to be used by the general public. The UFI can alternatively be placed

outside of the label (e.g. printed or affixed on the inner packaging) but close to the other

obligatory CLP label elements.

Supplier

identity

Precautionary

statements

Hazard

statements

Signal word

Product

identifier

CLP hazard

pictograms

Inner

packaging

Outer

packaging

Only transport label required

(CLP labelling optional)

for outer packaging.

UFI: VDU1-414F

1003-1862

UFI code

Guidance on Labelling and Packaging

Version 4.2 – March 2021

Example 11: Labelling for a mixture that is transported on land in

single packaging (not intended for the general public)

This example illustrates the provisions related to the labelling of single packaging in

accordance with CLP Article 33(3). It is an example of a mixture that is classified and

labelled in accordance with the rules on the transport of dangerous goods and under the

CLP Regulation. The mixture is transported on land in single packaging (drum). It is not

intended to be used by the general public.

In this example, the full CLP labelling information is provided by means of a separate

label, in addition to the transport labelling information (version 1).

The CLP hazard pictogram GHS09 may be omitted from the packaging because it relates

to the same hazards as the “dead tree – dead fish” transport mark (version 2).

Since the mixture is hazardous to the environ ment only, a UFI is not required.

Version 1:

UN 3082 ENVIRONMENTALLY

HAZARDOUS SUBSTANCE,

LIQUID, N.O.S.

(Contains X)

1A2/Y1.2/100/08/NL/TDV441

Mixture Z

(Contains X)

Warning

Very toxic to aquatic life with long lasting

effects

Avoid release to the environment. Collect

spillage. Dispose of contents/container to local

waste disposal company.

VOC content: EU limit for this product is (cat. A/d):

300 g/l. This product contains max 299 g/l VOC.

Company X, Street Y, Town Z,

Code 00000,

Tel: +49(0)0000000000

Single packaging with the

transport labelling …

Obligatory supplemental

information according to

the VOC Directive

… and the CLP labelling

information

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Version 4.2 – March 2021

Version 2:

1A2/Y1.2/100/08/NL/TDV

441

Mixture Z

(Contains X)

Warning

Very toxic to aquatic life with long lasting

effects

Avoid release to the environment. Collect

spillage. Dispose of contents/container to local

waste disposal company.

VOC content: EU limit for this product is (cat.

A/d): 300 g/l. This product contains max 299

g/l VOC.

Company X, Street Y, Town Z,

Code 00000,

Tel: +49(0)0000000000

UN 3082 ENVIRONMENTALLY

HAZARDOUS SUBSTANCE,

LIQUID , N.O.S.

(Contains X)

Single packaging with the

transport labelling …

… and the CLP labelling

information without the

CLP pictogram GHS09 for

the aquatic hazards

Obligatory supplemental

information according to

the VOC Directive

Guidance on Labelling and Packaging

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6.2 Specific case: labelling of two-component products

In certain specific cases the packaging of a product can be so unique that it is difficult to

meet the CLP labelling requirements. Examples of such situations are given below.

Please note that the examples only illustrate the general aspects of labelling of two-

component products and are not intended to present the correct selection of appropriate

label elements.

Example 12: Labelling of a two-component adhesive sold as a kit

The figure below shows an example of a popular two-component adhesive sold as a kit

consisting of two mixtures, namely an epoxy resin (Part A) and a hardener (Part B). The

two mixtures are placed in separate containers which are fixed together and sold as a kit

in transparent outer packaging. When used, the content of both containers is mixed after

or during extrusion. Part A and Part B react to produce a final mixture, which can be

used as an adhesive for a wide range of materials.

In this type of situation, two separate labels need to be affixed to the containers (one

label for each mixture (in a container)). The hazard information provided on the labels

must relate to the form/physical states in which both mixtures (Part A and Part B) are

placed on the market. On each label the UFI relevant for the specific mixture has to be

included. The outer packaging of the whole kit need not be labelled, as it is transparent

and permits the inner packaging (both containers) to be clearly seen.

If the product formed during end-use is hazardous (with different properties to the

mixtures in the containers), sufficient instructions to enable safe use must be provided

to the user. The instructions can for example be provided on the label or as a separate

leaflet in the package.

If such a product is not intended for the general public, two separate SDSs should be

provided to enable the users to meet their responsibilities in relation to the management

Please note:

A case-by-case judgement may be necessary when determining the labelling

requirements for similar, unique packaging. The information should not confuse the

user and the label should be easily understandable.

UFI: E600-30P1-S00Y-5079

UFI: VDU1-414F-1003-1862

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Version 4.2 – March 2021

of risks arising from the use of the reaction product that occur upon the end use of the

two mixtures (i.e. the adhesive).

As the adhesive in the example is also classified as hazardous, the relevant information

about the risk management measures should be provided in the SDSs.

Example 13: Labelling of a co-axial cartridge

A coaxial cartridge consists of a centre tube surrounded by an outer “doughnut” tube for

consistent two-component dispensing with a specified ratio of components (see figures

below). Normally, the two sections of the cartridge have their own moulded pistons. As

both pistons are pushed, the two components are pushed together to mix and react

through a static mix nozzle. A control valve located at the outlet prevents cross-

contamination. A divider plate keeps the components separate until they reach the

nozzle outlet.

In the case of a co-axial cartridge, there is an outer packaging – a single container

visible to the user. To ensure the safe use of the two-component product in the

cartridge, it should be labelled with one physical CLP label where the label elements for

each component mixture are clearly separated to differentiate between them.

The following mandatory elements of the CLP label should be shown (where applicable)

separately for each of the component mixtures:

• product identifier of the component mixture,

• hazard pictograms,

• signal word,

• hazard statements,

• precautionary statements,

• supplemental information specific to each mixture, including the UFI code.

Other mandatory elements of the CLP label, such as the identification of the supplier,

trade name and other supplemental information may be shown once on the label.

Coaxial outlet

Pistons

Component A

Component B

Centre tube

Cartridge body

Static mix

nozzle

Coaxial

cartridge

Guidance on Labelling and Packaging

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If the final blended mixture is not classified as hazardous, no additional information

needs to be included in the use instructions.

If the final blended mixture is more hazardous than the individual component mixtures,

or it has hazards not already addressed on the label, then information about this will

need to be included in the use instructions (e.g. on the label or provided inside an outer

packaging) and in Section 2.3 of the SDS(s).

Guidance on Labelling and Packaging

Version 4.2 – March 2021

00000

Trade name

FAST CURING ANCHORING ADHESIVE

Contains: Substance X

. Flammable liquid and

vapour. May be fatal if swallowed and enters

airways. Causes skin irritation. Causes serious

eye irritation.

Keep away from heat, hot surfaces, sparks, open

flames and other ignition sources. No smoking.

Wear protective gloves/eye protection/face

protection. IF SWALLOWED: Immediately call a

POISON CENTER or doctor/physician. IF ON

SKIN (or hair): Take off immediately all

contaminated clothing. Rinse skin with water/

shower. Do NOT induce vomiting. In case of fire:

Use dry sand, dry chemical or alcohol-resistant

foam to extinguish.

Contains: Substance Y

. May cause an allergic

skin reaction. Causes serious eye irritation. Very

toxic to aquatic life with long lasting effects.

Avoid breathing vapours. Avoid release to the

environment. Wear protective gloves/eye

protection/face protection. If skin irritation or rash

occurs: Get medical advice/ attention. If eye

irritation persists: Get medical advice/attention.

Take off contaminated clothing and wash it before

reuse.

Consult most current local Product Data Sheet

and Safety Data Sheets prior to any use.

Temperature

Gel time

Curing time

+30 °C

4 min

35 min

+25 °C – +30 °C

4 min

40 min

+20 °C – +25 °C

5 min

50 min

+10 °C – +20 °C

6 min

85 min

+5 °C – +10 °C

10 min

145 min

+5 °C

18 min

145 min

–10 °C

30 min

24 h

Minimum cartridge temperature: +5 °C

Company X

Street Y

Town Z

Code 01234

Country

Tel: +01(0)234567890

www.companyx.com

300 ml

500 g

Best before end of XX/2019

Supplier

identity

Hazard

statements for

Component

mixture A

Trade name

Hazard

pictograms

for

Component

mixture A

Nominal

quantity

Precautionary

statements

For

Component

mixture A

Space for

further

supplemental

information

(e.g.

instructions for

use)

Hazard

statements for

Component

mixture B

Hazard

pictograms

for

Component

mixture B

Precautionary

statements

For

Component

mixture B

UFI code for

Component

mixture A

UFI code for

Component

mixture B

Signal word

for

Component

mixture A

Signal word

for

Component

mixture B

Product type

Component A

Danger

Component B

Warning

UFI: VDU1-414F-1003-1862

UFI: E600-30P1-S00Y-5079

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6.3 Specific case: labelling of a bespoke paint

Example 14: Labelling of a bespoke paint where colours are added

on a tailor-made basis at the point of sale

The example below illustrates a label for a bespoke paint where colours are added to the

paint base on a tailor-made basis at the point of sale for supply and use. The product is

supplied in a one-litre paint can.

All obligatory labelling information of the paint base is shown on the paint base’s label.

Information on colours used are given on a separate sticker, printed directly from the

tinting machine, which includes the relevant UFIs (with concentrations if >5%) of the

used tinter mixtures on this same sticker. The sticker needs to be placed within the label

or in a location on the container in close proximity to the other label elements and where

the UFIs can be easily seen and identified, also during the use of the product.

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Version 4.2 – March 2021

7. Guidance on the selection of precautionary statements

for the CLP hazard label

7.1 Introduction

Based on the UN GHS, the CLP Regulation assigns precautionary statements to all hazard

classes for the purpose of the safe supply and use of a substance or mixture. Based on

CLP Article 4, suppliers have to select precautionary statements for the CLP hazard label.

Suppliers can be the following:

• manufacturers or importers of substances,

• importers of mixtures;

• downstream users of substances or mixtures (including formulators),

• distributors (including retailers) of substances or mixtures, and/or

• producers or importers of explosive articles as defined in section 2.1 of Annex I to

CLP.

The selection of precautionary statements must be done based on CLP Articles 22 and 28

and CLP Annex IV:

Article 22

Precautionary statements

1. The label shall include the relevant precautionary statements.

2. The precautionary statements shall be selected from those set out in the tables in

Parts 2 to 5 of Annex I indicating the label elements for each hazard class.

3. The precautionary statements shall be selected in accordance with the criteria laid

down in Part 1 of Annex IV taking into account the hazard statements and the

intended or identified use or uses of the substance or the mixture.

4. The precautionary statements shall be worded in accordance with Part 2 of Annex

IV.

Article 28

Principles of precedence for precautionary statements

1. Where the selection of the precautionary statements results in certain precautionary

statements being clearly redundant or unnecessary given the specific substance,

mixture or packaging, such statements shall be omitted from the label.

2. Where the substance or mixture is supplied to the general public, one precautionary

statement addressing the disposal of that substance or mixture as well as the

disposal of packaging shall appear on the label, unless not required under Article

22. In all other cases, a precautionary statement addressing disposal shall not be

required, where it is clear that the disposal of the substance or mixture or the

packaging does not present a hazard to human health or the environment.

3. Not more than six precautionary statements shall appear on the label, unless

necessary to reflect the nature and the severity of the hazards.

Annex IV

“In selecting the precautionary statements in accordance with Articles 22 and 28(3),

suppliers may combine the precautionary statements in the tables [of Annex IV],

having regard to clarity and comprehensibility of the precautionary advice. (…).”

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Neither the UN GHS nor the CLP Regulation provides for clear-cut rules on how to select

precautionary statements for the label (apart from the provisions of CLP Articles 22 and

28 and the basic instructions given in the columns specifying the conditions for use in

Tables 6.1-6.5 of Annex IV to CLP).

On the other hand, the number of precautionary statements under the CLP

Regulation/UN GHS has more than doubled when compared to the number of S-phrases

under the DSD. In a situation where selection rules are missing, an average hazardous

substance listed in Annex VI to CLP could easily be assigned more than 20 precautionary

statements on the label, based on the hazards of the substance (see section 3.4 of this

guidance document). The CLP Regulation requires that normally not more than six

precautionary statements must appear on the label, unless necessary to reflect the

nature and the severity of the hazards. Therefore, a substantial reduction of the number

of precautionary statements must be performed, based on effective selection rules.

7.2 Methodology

The selection of precautionary statements under the CLP Regulation is based on:

• the provisions set out in CLP Articles 22 and 28, and

• the basic instructions provided in the columns containing the conditions for use in

Tables 6.1-6.5 of Annex IV to CLP, and

• the instructions mentioned directly under the precautionary statements in the

selection tables (see section 7.3 of this guidance document).

The following approach was chosen for the selection of the precautionary statements

under the CLP Regulation:

• The P-statements

should be selected in accordance with the rules outlined in

CLP Article 28 and Part 1 of Annex IV to CLP;

• The selection of P-statements should take into account the underlying hazards

and identified or foreseen conditions for use of a substance or mixture;

• If the content of two P-statements is an obvious duplication, only the most

relevant statement should be selected;

• The P-statements assignment follows a “traffic light” system. The conditions for

use described in this guidance document distinguish between precautionary

statements that are “highly recommended”, “recommended”, “optional” and “not

to be used” for the hazard label;

• A particular recommendation should be seen in the light of the original CLP

conditions for use specified under the relevant precautionary statement in the

selection tables;

• Two target groups, i.e. the general public and the industrial/professional users,

are specified under the CLP Regulation. Where there is no explicit mention of the

target group, the conditions for use apply to both the general public and

industrial/professional users.

• Where the use of a particular precautionary statement is (highly) recommended

but some exemptions are indicated (“unless” condition), it should not be used

where the conditions specified in the “unless” clause apply:

Corresponding but not always identical to the former safety phrases (S-phrases) under the DSD.

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Vice versa, where a precautionary statement is only optional, it should be used

where the conditions specified in the “unless” clause apply:

• Similarly to the previous bullet point, where the use of a particular precautionary

statement is (highly) recommended under certain conditions

only, it should not be used where these conditions do not apply:

• For some hazards, the use of many specific precautionary statements will

normally have to be recommended. As a consequence, the number of

precautionary statements on the label will easily exceed the target number of six

even for simple substances.

On the other hand, the label, as compared to the SDS, is not always the only and

most appropriate means to convey a message to industrial/professional users,

e.g. for P241 (“Use explosion-proof electrical/ventilating/lighting/

…/equipment.”). In such cases, the guidance also refers to the SDS, typically by

phrasing a recommendation for both the label and the SDS. The recommendation

for inclusion on the label is then “weaker” than for the SDS, as for example P241

for flammable liquids or P373 (“DO NOT fight fire when fire reaches explosives”)

for explosive hazards. In some cases, it is even recommended to put the relevant

precautionary statements in the relevant section of SDS only;

• In relation to the physical hazards, it should always be determined whether

substances or mixtures displaying these hazards are supplied to or handled by

the general public. When this is not the case, the use of further precautionary

statements could be de-prioritised (“weaker” recommendation);

• For certain hazard classes listed in Table 6.5 of Annex IV, the CLP Regulation

requires at least one precautionary statement relating to disposal for substances

or mixtures supplied to the general public, as referred to under CLP Article 28(2);

For example:

P264 (“Wash … thoroughly after handling”) for the hazard class Skin

corrosion 1 should not be used for industrial/professional users where

P280 (“Wear protective gloves/protective clothing/eye protection/face

protection”) has already been selected for the hazard label of the

substance or mixture.

For example:

P410 (“Protect from sunlight”) for the hazard class Gases under pressure

should be applied in case the described gases are subject to (slow)

decomposition or polymerisation.

For example:

P260 (“Do not breathe dust/fume/gas/mist/vapours/spray”) would not be

recommended for skin corrosive substances or mixtures where inhalation

is unlikely to occur (e.g. for substances/mixtures that are not volatile and

where inhalable particles or mists do not occur during use).

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• Where it is proposed to combine two or more precautionary statements that could

also be used on their own, the conditions of use specify “(highly) recommended,

in combination with Pxxx”:

Such combined statements should be counted as one P-statement.

• Additional guidance is provided for the application of the precautionary

statements P101 (“If medical advice is needed, have product container or label at

hand”), P102 (“Keep out of reach of children”) and P103 (“Read label before use”)

for hazardous substances and mixtures supplied to the general public (see table

in section 7.3.1 of this guidance document).

It should be noted that for substances and mixtures that are classified for physical,

health and environmental hazards, a selection based on the rules outlined in this

guidance document may still lead to a final set that significantly exceeds the target

number of six statements for the label (see Example C in section 7.4 of this guidance

document). Even if this can in principle be justified by CLP Article 28(3), the question

remains whether the extent of the labelling information is still digestible, in particular

where long combination statements appear.

Therefore, when verifying the set of P-statements selected on the basis of this guidance

document, it is proposed to take into account the following principles:

• certain prevention and response statements provide more urgent advice than

other statements, as rapid action may be crucial. Therefore, where similar P-

statements having different priorities are assigned because of different hazards,

the most stringent P-statement should be selected. This judgement can only be

done on a case-by-case basis and will strongly depend on the hazards involved:

• de-selecting statements that appear less urgent from the label and putting them

in the SDS would be a better option;

• to reduce the number of P-statements, the content of the hazard statements can

also be taken into account:

For example:

“Highly recommended, in combination with P302 + P352 (“IF ON SKIN: Wash

with plenty of water/…”) for P310 (“Immediately call a POISON

CENTER/doctor/...”) for the hazard class Acute Tox. 1 and 2 (dermal).

For example:

For a substance classified as acutely toxic and carcinogenic, the first aid

measures for acute toxicity will take precedence over the longer term effects,

i.e. P310 (“Immediately call a POISON CENTER/doctor/...”) will take precedence

over P311 (“Call a POISON CENTER/doctor/...”), P312 (“Call a POISON

CENTRE/doctor/…/if you feel unwell”) and P313 (“Get medical

advice/attention”).

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When an SDS must be compiled, the precautionary statements selected for the CLP

hazard label have to be included in the SDS, under heading 2.2 “Label elements” (see

the Guidance on the compilation of safety data sheets). The de-selected statements can

be introduced under the relevant headings of the SDS instead, to provide the industrial

or professional user with sufficient information for handling the substance or mixture

safely.

7.3 Selection tables

The below selection tables (sections 7.3.1 to 7.3.5 of this guidance document) follow the

format as provided in Section 3 of Annex 3 to the UN GHS. The tables are arranged

according to the hazard class and category as appropriate.

This guidance document builds upon the generic provisions set out in CLP Articles 22 and

28, as well as the basic instructions provided in the columns containing the conditions for

use in Tables 6.1-6.5 of Annex IV to CLP. It takes into account i.a. the intended uses and

the physical properties of the substance or mixture.

The original CLP conditions for use are displayed in black colour under the relevant

precautionary statements in the selection tables below. In contrast, the conditions that

constitute EU guidance are marked with an asterisk () and in blue colour, in order to

distinguish them from the original CLP conditions for use (see also the columns

containing the conditions for use in Tables 6.1–6.5 of Annex IV to CLP).

When a forward slash or diagonal mark “/” appears in a precautionary statement

text, it indicates that a choice has to be made between the phrases it separates:

When three full stops “…” appear in the precautionary statement text, they indicate

that not all applicable conditions are listed. Therefore, the manufacturer or supplier

needs to add the required information as appropriate.

When square brackets “[…]” appear around some text in a precautionary statement,

they indicate that the text in square brackets is not appropriate in every case and should

For example:

P222 (“Do not allow contact with air”) for the hazard classes Pyrophoric liquids

and Pyrophoric solids can be omitted as the hazard statement H250 (“Catches fire

spontaneously if exposed to air”) is used.

For example:

P280 (“Wear protective gloves/protective clothing/eye protection/face

protection”) could read: “Wear eye protection” or “Wear eye and face

protection”.

For example:

In P312 (“Call a POISON CENTRE/doctor/…/if you feel unwell”), the use of “…”

indicates that any other choice needs to be specified by manufacturer or

supplier.

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be used only in certain circumstances. In these cases, conditions for use are included

explaining when the text should be used:

In selecting the precautionary statements in accordance with the conditions for use set

out in the tables, suppliers may combine these statements, having regard to clarity and

comprehensibility of the precautionary advice. In this case, the specific wording of the

component phrases must be retained in the combined phrases. The selection tables are

followed by four examples (A, B, C and D) of substances, illustrating the selection of

precautionary statements for the label (see section 7.4 of this guidance document).

For example:

P284 states: “[In case of inadequate ventilation] wear respiratory protection.”

This P-statement is given with the following condition for use: “- text in square

brackets may be used if additional information is provided with the chemical at

the point of use that explains what type of ventilation would be adequate for

safe use.”. The application of this condition should be interpreted as follows: if

additional information is provided with the chemical explaining what type of

ventilation would be adequate for safe use, the text in square brackets may be

used. In this case, P284 would read: “In case of inadequate ventilation wear

respiratory protection.” However, if the chemical is supplied without such

information, the text in square brackets should not be used, and P284 should

read: “wear respiratory protection”.

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7.3.1 General precautionary statements

Precautionary Statement

P101

If medical advice is needed, have product container or label at hand.

- Consumer products

 Highly recommended for all substances and mixtures classified for health hazards and that

are sold to the general public

P102

Keep out of reach of children.

- Consumer products

 Highly recommended for substances and mixtures sold to the general public, except for

those only classified as hazardous to the environment

 Applies also to packagings that are to be fitted with child resistant fastening (Annex II,

section 3.1.1.1)

P103

Read label before use.

- Consumer products

 Optional, but may be required by other EU legislation

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7.3.2 Specific precautionary statements for physical hazards

7.3.2.1 Explosives

Hazard category Signal word Hazard statement

Unstable explosive Danger H200 Unstable explosive

Precautionary Statements

Prevention

Response

Storage

Disposal

P201

Obtain special instructions before

use.

 Highly recommended

P250

Do not subject to

grinding/shock/friction/… .

 if the explosive is mechanically

sensitive

…Manufacturer/supplier to specify

applicable rough handling.

 Highly recommended if the

explosive is mechanically sensitive

 Optional if the explosive is not

mechanically sensitive

P370 + P372 + P380 + P373

In case of fire:

Explosion risk.

Evacuate area. DO NOT fight fire

when fire reaches explosives.

 Highly recommended

P401

Store in accordance with…

… Manufacturer/supplier to specify

local/regional/national/international

regulations as applicable.

 Highly recommended for

inclusion in the safety data

sheet. Specify the applicable

regulation.

P501

Dispose of

contents/container to …

… in accordance with local/

regional/national/international

regulations (to be specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Recommended for

inclusion in the safety data

sheet if there are specific

disposal requirements

above the normal

expectation for the

disposal of chemicals.

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended to apply the

full wording of P280

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7.3.2.1 Explosives (continued)

Hazard category Signal word Hazard statement

Division 1.1 Danger H201 Explosive; mass explosion hazard

Division 1.2 Danger H202 Explosive; severe projection hazard

Division 1.3 Danger H203 Explosive; fire, blast or projection hazard

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P230

Keep wetted with …

- for substances and mixtures which

are wetted, diluted, dissolved or

suspended with a phlegmatiser in order

to reduce or suppress their explosive

properties (desensitized explosives)

… Manufacturer/supplier to specify

appropriate material.

 Highly recommended

P234

Keep only in original packaging

 Highly recommended

P370 + P372 + P380 + P373

In case of fire:

Explosion risk.

Evacuate area. DO NOT fight fire

when fire reaches explosives.

 Highly recommended

P401

Store in accordance with…

… Manufacturer/supplier to specify

local/regional/national/international

regulations as applicable.

 Highly recommended for

inclusion in the safety data

sheet. Specify the applicable

regulation.

P501

Dispose of

contents/container to …

… in accordance with local/

regional/national/international

regulations (to be specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Recommended for inclusion

in the safety data sheet if

there are specific disposal

requirements above the

normal expectation for the

disposal of chemicals.

Specify the applicable

regulation.

 Mandatory when supplied

to the general public

(where the Member State

allows such supply).

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P240

Ground and bond container and

receiving equipment.

- if the explosive is electrostatically

sensitive.

 Optional unless other conditions

deem it necessary

 Recommended for inclusion in the

safety data sheet

P250

Do not subject to

grinding/shock/friction/… .

 if the explosive is mechanically

sensitive

…Manufacturer/supplier to specify

applicable rough handling.

 Highly recommended if the

explosive is mechanically sensitive

 Optional if the explosive is not

mechanically sensitive

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Protective gloves/protective

clothing/eye protection highly

recommended for

industrial/professional users

 Face protection highly

recommended for

industrial/professional users where

articles are able to form hazardous

fragments

 Recommended for explosives

supplied to the general public

(where Member States allows such

supply).

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7.3.2.1 Explosives (continued)

Hazard category Signal word Hazard statement

Division 1.4 Warning H204 Fire or projection hazard

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other ignition

sources. No smoking.

 Highly recommended

P234

Keep only in original packaging

 Highly recommended

P240

Ground and bond container and

receiving equipment.

- if the explosive is electrostatically

sensitive.

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety

data sheet

P370 + P372 + P380 + P373

In case of fire:

Explosion risk.

Evacuate area. DO NOT fight fire

when fire reaches explosives.

- except for explosives of division 1.4

(compatibility group S) in transport

packaging.

 Highly recommended

P370 + P380 + P375

In case of fire: Evacuate area.

Fight fire remotely due to the risk

of explosion.

- for explosives of division 1.4

(compatibility group S) in transport

packaging.

 Highly recommended

P401

Store in accordance with…

… Manufacturer/supplier to

specify

local/regional/national/internation

al regulations as applicable.

 Highly recommended for

inclusion in the safety data

sheet. Specify the applicable

regulation.

P501

Dispose of

contents/container to …

… in accordance with local/

regional/national/internationa

l regulations (to be

specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Recommended for

inclusion in the safety

data sheet if there are

specific disposal

requirements above the

normal expectation for

the disposal of chemicals.

Specify the applicable

regulation.

 Mandatory when supplied

to the general public

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P250

Do not subject to

grinding/shock/friction/… .

 if the explosive is mechanically sensitive

…Manufacturer/supplier to specify

applicable rough handling.

 Highly recommended if the explosive is

mechanically sensitive

 Optional if the explosive is not

mechanically sensitive

P280

Wear protective gloves/protective

clothing/ eye protection/ face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Protective gloves/protective clothing/eye

protection highly recommended for

industrial / professional users

 Face protection highly recommended for

industrial / professional users where

articles are able to form hazardous

fragments

 Recommended for explosives supplied to

the general public (where Member

States allows such supply).

(where the Member State

allows such supply).

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7.3.2.1 Explosives (continued)

Hazard category Signal word Hazard statement

Division 1.5 Danger H205 May mass explode in fire

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P230

Keep wetted with …

- for substances and mixtures which are

wetted, diluted, dissolved or suspended

with a phlegmatiser in order to reduce

or suppress their explosive properties

(desensitized explosives)

… Manufacturer/supplier to specify

appropriate material.

 Highly recommended

P234

Keep only in original packaging

 Highly recommended

P370 + P372 + P380 + P373

In case of fire:

Explosion risk.

Evacuate area. DO NOT fight fire

when fire reaches explosives.

 Highly recommended

P401

Store in accordance with…

… Manufacturer/supplier to specify

local/regional/national/international

regulations as applicable.

 Highly recommended for

inclusion in the safety data

sheet. Specify the applicable

regulation.

P501

Dispose of

contents/container to …

… in accordance with local/

regional/national/internation

al regulations (to be

specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Recommended for

inclusion in the safety

data sheet if there are

specific disposal

requirements above the

normal expectation for

the disposal of

chemicals. Specify the

applicable regulation.

 Mandatory when

supplied to the general

public (where the

Member State allows

such supply).

additional

hazard

pictogram

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P240

Ground and bond container and

receiving equipment.

- if the explosive is electrostatically

sensitive.

 Optional unless other conditions

deem it necessary

 Recommended for inclusion in the

safety data sheet

P250

Do not subject to

grinding/shock/friction/… .

- if the explosive is mechanically

sensitive

…Manufacturer/supplier to specify

applicable rough handling.

 Highly recommended if the explosive

is mechanically sensitive

 Optional if the explosive is not

mechanically sensitive

P280

Wear protective gloves/protective

clothing/eye protection/ face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

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 Protective gloves/protective

clothing/eye protection highly

recommended for industrial /

professional users

 Face protection highly recommended

for industrial / professional users

where articles are able to form

hazardous fragments

 Recommended for explosives

supplied to the general public

(where Member States allows such

supply)

Notes on the labelling of Explosives

1) Unpackaged explosives or explosives repackaged in packaging other than the original or similar packaging must include all of the following label

elements:

a) the pictogram: exploding bomb;

b) the signal word “Danger”; and

c) the hazard statement: ‘Explosive; mass explosion hazard’

unless the hazard is shown to correspond to one of the hazard categories listed in Table 2.1.2 of Annex I to CLP, in which case the corresponding

symbol, the signal word and/or the hazard statement must be assigned.

2) Substances and mixtures, as supplied, with a positive result in Test Series 2 in Part I, Section 12, of the UN RTDG, Manual of Tests and Criteria,

which are exempted from classification as explosives (based on a negative result in Test Series 6 in Part I, Section 16 of the UN RTDG, Manual of

Test and Criteria) still have explosive properties. The user must be informed of these intrinsic explosive properties because they have to be

considered for handling – especially if the substance or mixture is removed from its packaging or is repackaged – and for storage. For this

reason, the explosive properties of the substance or mixture must be communicated in Section 2 and Section 9 of the safety data sheet and

other sections of the safety data sheet, as appropriate.

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101

7.3.2.2 Flammable gases (including chemically unstable gases)

Hazard category Signal word Hazard statement

1 Danger H220 Extremely flammable gas

2 Warning H221 Flammable gas

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P377

Leaking gas fire: Do not extinguish,

unless leak can be stopped safely.

 Highly recommended

P381

In case of leakage, eliminate all

ignition sources.

 Recommended

P403

Store in a well-ventilated

place.

 Highly recommended

Pictogram

for hazard

category 1

only.

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7.3.2.2 Flammable gases (including chemically unstable gases) (continued)

Hazard category Signal word Hazard statement

A No additional signal word H230 May react explosively even in the absence of air

B No additional signal word H231 May react explosively even in the absence of air

at elevated pressure and/or temperature

Precautionary Statements

Prevention

Response

Storage

Disposal

P202

Do not handle until all safety

precautions have been read and

understood.

 Highly recommended

Note: This table lists only the precautionary statement that is assigned due to the chemical instability of the gas. For other precautionary

statements that are assigned based on the flammability see the respective table for flammable gases (of cat. 1 and 2) on the

previous page.

additional

hazard

pictogram

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103

7.3.2.3 Aerosols

Hazard category Signal word Hazard statement

1 Danger H222 Extremely flammable aerosol

H229 Pressurised container: May burst if heated

2 Warning H223 Flammable aerosol

H229 Pressurised container: May burst if heated

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks, open

flames and other ignition sources. No smoking.

 Assigned in accordance with Directive 75/324/EEC

P211

Do not spray on an open flame or other ignition

source.

 Assigned in accordance with Directive 75/324/EEC

P251

Do not pierce or burn, even after use.

 Assigned in accordance with Directive 75/324/EEC

P410 + P412

Protect from sunlight. Do not

expose to temperatures exceeding

50 ºC/122 ºF.

Manufacturer/supplier to use

applicable temperature scale

 Assigned in accordance with

Directive 75/324/EEC

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7.3.2.3 Aerosols (continued)

Hazard category Signal word Hazard statement

3 Warning H229 Pressurised container: May burst if heated

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks, open

flames and other ignition sources. No smoking.

 Assigned in accordance with Directive 75/324/EEC

P251

Do not pierce or burn, even after use.

 Assigned in accordance with Directive 75/324/EEC

P410 + P412

Protect from sunlight. Do not

expose to temperatures exceeding

50 ºC/ 122ºF.

Manufacturer/supplier to use

applicable temperature scale

 Assigned in accordance with

Directive 75/324/EEC

additional

hazard

pictogram

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7.3.2.4 Oxidising gases

Hazard category Signal word Hazard statement

1 Danger H270 May cause or intensify fire; oxidiser

Precautionary Statements

Prevention

Response

Storage

Disposal

P220

Keep away from clothing and other

combustible materials.

 Highly recommended

P244

Keep valves and fittings free from oil and

grease.

 Highly recommended

P370 + P376

In case of fire: Stop leak if safe to

do so.

 Optional

 Recommended for inclusion in the

safety data sheet.

P403

Store in a well-ventilated

place.

 Highly recommended

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7.3.2.5 Gases under pressure

Hazard category Signal word Hazard statement

Compressed gas Warning H280 Contains gas under pressure; may explode if heated

Liquefied gas Warning H280 Contains gas under pressure; may explode if heated

Dissolved gas Warning H280 Contains gas under pressure; may explode if heated

Precautionary Statements

Prevention

Response

Storage

Disposal

P410 + P403

Protect from sunlight. Store in a well-

ventilated place.

- P410 may be omitted for gases filled in

transportable gas cylinders in

accordance with packing instruction

P200 of the UN RTDG, unless those

gases are subject to (slow)

decomposition or polymerisation

 Optional

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7.3.2.5 Gases under pressure (continued)

Hazard category Signal word Hazard statement

Refrigerated liquefied gas Warning H281 Contains refrigerated gas; may cause cryogenic burns or injury

Precautionary Statements

Prevention

Response

Storage

Disposal

P282

Wear cold insulating gloves and

either face shield or eye protection.

 Highly recommended where liquid

splashes may occur, e.g. during

transfer of cryogenic liquids. In this

case the use of safety glasses with

side shields or a face shield should be

indicated in the safety data sheet.

P336 + P315

Thaw frosted parts with lukewarm

water. Do not rub affected area. Get

immediate medical advice/attention.

 Recommended

P403

Store in a well-

ventilated place.

 Optional

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7.3.2.6 Flammable liquids

Hazard category Signal word Hazard statement

1 Danger H224 Extremely flammable liquid and vapour

2 Danger H225 Highly flammable liquid and vapour

3 Warning H226 Flammable liquid and vapour

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P233

Keep container tightly closed.

- if the liquid is volatile and may generate an

explosive atmosphere

 Highly recommended for category 1, unless

P404 has already been assigned

 Recommended for category 2, unless P404

has already been assigned

 Optional for category 3

P303 + P361 + P353

IF ON SKIN (or hair): Take off

immediately all contaminated

clothing. Rinse skin with water [or

shower].

- text in square brackets to be included

where the manufacturer/supplier

considers it appropriate for the specific

chemical

 Optional unless deemed necessary,

e.g. due to the risk of generating a

potentially explosive atmosphere

P370 + P378

In case of fire: Use … to extinguish.

- if water increases risk.

…Manufacturer/supplier to specify

appropriate media.

P403 + P235

Store in a well-

ventilated place.

Keep cool.

- for flammable

liquids Category 1 and

other flammable

liquids that are

volatile and may

generate an explosive

atmosphere.

 Highly

recommended

P501

Dispose of

contents/container to …

… in accordance with

local/regional/

national/international regulations

(to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or

both.

 Mandatory for the general

public if the substance /

mixture is subject to

legislation on hazardous

waste. It is recommended to

specify the site of disposal

while a reference to the

applicable legislation is not

necessary.

 Recommended for industrial /

professional users if there

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P235

Keep cool.

- for flammable liquids category 1 and other

flammable liquids that are volatile and may

generate an explosive atmosphere

 Highly recommended, unless P403 + P235 is

assigned.

P240

Ground and bond container and receiving

equipment.

- if the liquid is volatile and may generate an

explosive atmosphere

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety

data sheet

P241

Use explosion-proof

[electrical/ventilating/ lighting/…]

equipment.

- if the liquid is volatile and may generate an

explosive atmosphere

- text in square brackets may be used to specify

specific electrical, ventilating, lighting or other

equipment if necessary and as appropriate.

 Optional unless other conditions deem it

necessary

 Highly recommended if specific

extinguishing media are required or

appropriate

are specific disposal

requirements above the

normal expectation for the

disposal of chemicals.

It is recommended to specify

the site of disposal while a

reference to the applicable

legislation is not necessary.

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 Recommended for inclusion in the safety

data sheet

P242

Use non-sparking tools.

- if the liquid is volatile and may generate an

explosive atmosphere and if the minimum

ignition energy is very low. (This applies to

substances and mixtures where the ignition

energy is <0.1 mJ, e.g. carbon disulphide).

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety

data sheet

P243

Take action to prevent static discharges.

- if the liquid is volatile and may generate an

explosive atmosphere

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety

data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face protection.

Manufacturer/supplier to specify the appropriate

type of equipment.

 Optional

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7.3.2.7 Flammable solids

Hazard category Signal word Hazard statement

1 Danger H228 Flammable solid

2 Warning H228 Flammable solid

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P240

Ground and bond container and receiving

equipment.

- if the solid is electrostatically sensitive

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety data

sheet

P370 + P378

In case of fire: Use … to extinguish.

- if water increases risk.

… Manufacturer/supplier to specify

appropriate media.

 Highly recommended if specific

extinguishing media are required or

appropriate

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P241

Use explosion-proof [electrical/ventilating/

lighting/…] equipment.

- if dust clouds can occur.

- text in square brackets may be used to specify

specific electrical, ventilating, lighting or other

equipment if necessary and as appropriate.

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety data

sheet

P280

Wear protective gloves/protective

clothing/eye protection/ face protection.

Manufacturer/supplier to specify the appropriate

type of equipment.

 Optional

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7.3.2.8 Self-reactive substances and mixtures

Hazard category Signal word Hazard statement

Type A Danger H240 Heating may cause an explosion

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended where the

packaging is important for preventing

or suppressing the effect of

dangerous reactions or explosion

P235

Keep cool.

- may be omitted if P411 is given on the

label

 Recommended

P370 + P372 + P380 + P373

In case of fire:

Explosion risk. Evacuate area. DO

NOT fight fire when fire reaches

explosives

 Highly recommended

P403

Store in a well-ventilated

place.

- except for temperature

controlled self-reactive

substances and mixtures or

organic peroxides because

condensation and consequent

freezing may take place

 Highly recommended

P411

Store at temperatures not

exceeding …ºC/…ºF.

- if temperature control is

required (according to CLP

Annex I, section 2.8.2.4 or

2.15.2.3) or if otherwise

deemed necessary.

… Manufacturer/supplier to

specify temperature using the

applicable temperature scale.

P501

Dispose of

contents/container to …

… in accordance with local/

regional/national/international

regulations (to be specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Recommended for inclusion

in the safety data sheet if

there are specific disposal

requirements above the

normal expectation for the

disposal of chemicals.

Specify the applicable

regulation.

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P240

Ground and bond container and

receiving equipment.

- if electrostatically sensitive and able to

generate an explosive atmosphere

 Optional unless other conditions deem

it necessary

 Recommended for inclusion in the

safety data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

P420

Store separately.

 Recommended where

incompatible materials are

likely to produce a

particular risk. If this

statement is used, text

clarifying the incompatible

materials should be added

as supplemental

information.

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115

7.3.2.8 Self-reactive substances and mixtures (continued)

Hazard category Signal word Hazard statement

Type B Danger H241 Heating may cause a fire or explosion

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other ignition

sources. No smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended

P235

Keep cool.

- may be omitted if P411 is given on the label

 Recommended

P240

P370 + P380 + P375 [+ P378]

In case of fire: Evacuate area.

Fight fire remotely due to the risk

of explosion. [Use … to

extinguish].

- text in square brackets to be used if

water increases risk.

…Manufacturer/supplier to specify

appropriate media.

 Highly recommended

 Text in square brackets is highly

recommended if specific

extinguishing media are required

or appropriate

P403

Store in a well-ventilated

place.

- except for temperature

controlled self-reactive

substances and mixtures or

organic peroxides because

condensation and consequent

freezing may take place

 Highly recommended

P411

Store at temperatures not

exceeding …ºC/…ºF.

- if temperature control is

required (according to CLP

Annex I, section 2.8.2.4 or

2.15.2.3) or if otherwise deemed

necessary.

P501

Dispose of

contents/container to …

… in accordance with

local/regional/

national/international

regulations (to be

specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or

both.

 Mandatory for the

general public if the

substance / mixture is

subject to legislation

on hazardous waste. It

is recommended to

specify the site of

disposal while a

The use of square brackets is explained in section 7.3 of this guidance document.

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Ground and bond container and receiving

equipment.

- if electrostatically sensitive and able to

generate an explosive atmosphere

 Optional unless other conditions deem it

necessary

 Recommended for inclusion in the safety

data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

… Manufacturer/supplier to

specify temperature.

 Highly recommended

P420

Store separately.

 Recommended where

incompatible materials are

likely to produce a particular

risk. If this statement is

used, text clarifying the

incompatible materials

should be added as

supplemental information

reference to the

applicable legislation is

not necessary.

 Recommended for

inclusion in the safety

data sheet if there are

specific disposal

requirements above

the normal expectation

for the disposal of

chemicals. Specify the

applicable regulation.

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7.3.2.8 Self-reactive substances and mixtures (continued)

Hazard category Signal word Hazard statement

Type C Danger H242 Heating may cause a fire

Type D Danger H242 Heating may cause a fire

Type E Warning H242 Heating may cause a fire

Type F Warning H242 Heating may cause a fire

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended

P235

Keep cool.

- may be omitted if P411 is given on the

label

 Recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

Manufacturer/supplier to specify

appropriate media.

 Highly recommended if specific

extinguishing media are required

or appropriate

P403

Store in a well-ventilated

place.

- except for temperature

controlled self-reactive

substances and mixtures or

organic peroxides because

condensation and

consequent freezing may

take place

 Highly recommended

P411

Store at temperatures not

exceeding …ºC/…ºF.

- if temperature control is

required (according to CLP

Annex I, section 2.8.2.4 or

2.15.2.3) or if otherwise

deemed necessary.

P501

Dispose of contents/container

to …

… in accordance with

local/regional/

national/international regulations

(to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or

both.

 Mandatory for the general

public if the substance/mixture

is subject to legislation on

hazardous waste. It is

recommended to specify the

site of disposal while a

reference to the applicable

legislation is not necessary.

 Recommended for inclusion in

the safety data sheet if there

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P240

Ground and bond container and

receiving equipment.

- if electrostatically sensitive and able to

generate an explosive atmosphere

 Optional unless other conditions deem

it necessary

 Recommended for inclusion in the

safety data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

… Manufacturer/supplier to

specify temperature.

 Highly recommended

P420

Store separately.

 Recommended where

incompatible materials

are likely to produce a

particular risk. If this

statement is used, text

clarifying the

incompatible materials

should be added as

supplemental

information

are specific disposal

requirements above the

normal expectation for the

disposal of chemicals. Specify

the applicable regulation.

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7.3.2.9 Pyrophoric liquids

Hazard category Signal word Hazard statement

1 Danger H250 Catches fire spontaneously if exposed to air

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P222

Do not allow contact with air.

- if emphasis of the hazard statement is deemed

necessary

 Optional

P231 + P232

Handle and store contents under inert

gas/…

Protect from moisture

…Manufacturer/supplier to specify appropriate

liquid or gas if “inert gas” is not appropriate.

 Recommended

 Highly recommended for inclusion in the

safety data sheet

P302 + P334

IF ON SKIN: Immerse in cool water or wrap

in wet bandages.

 Highly recommended

P370 + P378

In case of fire: Use … to extinguish.

- if water increases risk.

…Manufacturer/supplier to specify appropriate

media.

 Highly recommended if specific extinguishing

media are required or appropriate

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P233

Keep container tightly closed

 Highly recommended

P280

Wear protective gloves/protective

clothing/eye protection/face protection.

Manufacturer/supplier to specify the appropriate

type of equipment.

 Highly recommended

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7.3.2.10 Pyrophoric solids

Hazard category Signal word Hazard statement

1 Danger H250 Catches fire spontaneously if exposed to air

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P222

Do not allow contact with air.

-if emphasis of the hazard statement is deemed

necessary

 Optional

P231 + P232

Handle and store contents under inert

gas/…

Protect from moisture

…Manufacturer/supplier to specify appropriate

liquid or gas if “inert gas” is not appropriate.

 Recommended

P302 + P335 + P334

IF ON SKIN: Brush off loose particles from

skin. Immerse in cool water or wrap in

wet bandages.

 Highly recommended

P370 + P378

In case of fire: Use … to extinguish.

- if water increases risk.

…Manufacturer/supplier to specify appropriate

media.

 Highly recommended if specific

extinguishing media are required or

appropriate

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 Highly recommended for inclusion in the

safety data sheet

P233

Keep container tightly closed

 Highly recommended

P280

Wear protective gloves/protective

clothing/eye protection/face protection.

Manufacturer/supplier to specify the appropriate

type of equipment.

 Highly recommended

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123

7.3.2.11 Self-heating substances and mixtures

Hazard category Signal word Hazard statement

1 Danger H251 Self-heating; may catch fire

2 Warning H252 Self-heating in large quantities; may catch fire

Precautionary Statements

Prevention

Response

Storage

Disposal

P235

Keep cool.

- may be omitted if P413 is given on the

label

 Highly recommended for the general

public

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Optional

P407

Maintain air gap between stacks or pallets.

 Highly recommended

P413

Store bulk masses greater than … kg/…lbs at

temperatures not exceeding …ºC/…ºF.

… Manufacturer/supplier to specify mass and

temperature using applicable scale.

 Highly recommended if the manufacturer has

specific information

P420

Store separately.

 Recommended where incompatible materials are

likely to produce a particular risk. If this statement

is used, text clarifying the incompatible materials

should be added as supplemental information

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7.3.2.12 Substances and mixtures which, in contact with water, emit flammable gases

Hazard category Signal word Hazard statement

1 Danger H260 In contact with water releases flammable gases which may

ignite spontaneously

2 Danger H261 In contact with water releases flammable gases

Precautionary Statements

Prevention

Response

Storage

Disposal

P223

Do not allow contact with water.

- if emphasis of the hazard statement is deemed

necessary

 Optional

P231 + P232

Handle and store contents under inert gas/…

Protect from moisture.

- if the substance or mixture reacts readily with

moisture in air.

…Manufacturer/supplier to specify appropriate liquid

or gas if “inert gas” is not appropriate

 Highly recommended where special emphasis is

required

P302 + P335 + P334

IF ON SKIN: Brush off

loose particles from skin.

Immerse in cool water.

 Highly recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to

specify appropriate media.

 Highly recommended if

specific extinguishing

media are required or

appropriate

P402 + P404

Store in a dry place. Store

in a closed container.

 Recommended, unless

P231 has already been

assigned

 Highly recommended for

inclusion in the safety data

sheet

P501

Dispose of

contents/container to …

… in accordance with

local/regional/

national/international

regulations (to be specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Mandatory for the general

public if the substance /

mixture is subject to

legislation on hazardous

waste. It is recommended

to specify the site of

disposal while a reference

to the applicable legislation

is not necessary.

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P280

Wear protective gloves/protective clothing/eye

protection/face protection.

Manufacturer/supplier to specify the appropriate type

of equipment.

 Recommended

 Recommended for

inclusion in the safety data

sheet if there are specific

disposal requirements

above the normal

expectation for the

disposal of chemicals.

Specify the applicable

regulation.

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7.3.2.12 Substances and mixtures which, in contact with water, emit flammable gases

(continued)

Hazard category Signal word Hazard statement

3 Warning H261 In contact with water releases flammable gases

Precautionary Statements

Prevention

Response

Storage

Disposal

P231 + P232

Handle and store contents under

inert gas/...

Protect from moisture.

- if the substance or mixture reacts

readily with moisture in air.

…Manufacturer/supplier to specify

appropriate liquid or gas if “inert gas”

is not appropriate

 Highly recommended where special

emphasis is required

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to specify

appropriate media.

 Highly recommended if specific

extinguishing media are

required or appropriate

P402 + P404

Store in a dry place. Store in

a closed container.

 Recommended, unless P231

has already been assigned

 Highly recommended for

inclusion in the safety data

sheet

P501

Dispose of contents/container to

…

… in accordance with local/

regional/national/international

regulations (to be specified).

Manufacturer/supplier to specify

whether disposal requirements apply

to contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste.

It is recommended to specify the

site of disposal while a reference

to the applicable legislation is not

necessary.

 Recommended for inclusion in the

safety data sheet if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. Specify

the applicable regulation.

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7.3.2.13 Oxidising liquids

Hazard category Signal word Hazard statement

1 Danger H271 May cause fire or explosion; strong oxidizer

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot

surfaces, sparks, open flames

and other ignition sources. No

smoking.

 Highly recommended

P220

Keep away from clothing and

other combustible materials.

 Highly recommended

P280

Wear protective

gloves/protective clothing/eye

protection/ face protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Recommended

P306 + P360

IF ON CLOTHING: Rinse

immediately contaminated clothing

and skin with plenty of water

before removing clothes.

 Recommended

P371 + P380 + P375

In case of major fire and large

quantities: Evacuate area. Fight fire

remotely due to the risk of

explosion.

 Highly recommended

P370 + P378

In case of fire: Use … to extinguish.

- if water increases risk.

… Manufacturer/supplier to specify

appropriate media.

P420

Store separately.

 Recommended where

incompatible materials are

likely to produce a

particular risk. If this

statement is used, text

clarifying the incompatible

materials should be added

as supplemental

information

 Optional where P220 has

already been assigned

P501

Dispose of contents/container

to …

… in accordance with local/regional/

national/international regulations

(to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or both.

 Mandatory for the general public

if the substance / mixture is

subject to legislation on

hazardous waste. It is

recommended to specify the site

of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in

the safety data sheet if there

are specific disposal

requirements above the normal

expectation for the disposal of

chemicals

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P283

Wear fire resistant or flame

retardant clothing.

 Recommended for inclusion in

the safety data sheet

 Highly recommended if specific

extinguishing media are required or

appropriate

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7.3.2.13 Oxidising liquids (continued)

Hazard category Signal word Hazard statement

2 Danger H272 May intensify fire; oxidiser

3 Warning H272 May intensify fire; oxidiser

Precautionary Statements

Prevention

Response

Storage

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P220

Keep away from clothing and other

combustible materials.

 Highly recommended

P280

Wear protective gloves/protective

clothing/eye protection/ face protection.

Manufacturer/supplier to specify the appropriate

type of equipment.

 Recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to

specify appropriate media.

 Highly recommended if

specific extinguishing media

are required or appropriate

P501

Dispose of contents/container to

…

… in accordance with local/regional/

national/international regulations (to

be specified).

Manufacturer/supplier to specify

whether disposal requirements apply

to contents, container or both.

 Mandatory for the general public

if the substance / mixture is

subject to legislation on

hazardous waste. It is

recommended to specify the site

of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in the

safety data sheet if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. Specify

the applicable regulation.

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7.3.2.14 Oxidising solids

Hazard category Signal word Hazard statement

1 Danger H271 May cause fire or explosion; strong oxidizer

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces, sparks,

open flames and other ignition sources. No

smoking.

 Highly recommended

P220

Keep away from clothing and other combustible

materials.

 Highly recommended

P280

Wear protective gloves/protective clothing/eye

protection/face protection.

Manufacturer/supplier to specify the appropriate type

of equipment.

 Recommended

P283

Wear fire resistant or flame retardant clothing.

 Recommended for inclusion in the safety data

sheet

P306 + P360

IF ON CLOTHING: Rinse

immediately contaminated clothing

and skin with plenty of water

before removing clothes.

 Recommended

P371 + P380 + P375

In case of major fire and large

quantities: Evacuate area. Fight

fire remotely due to the risk of

explosion.

 Highly recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to specify

appropriate media.

 Highly recommended if specific

extinguishing media are required or

appropriate

P501

Dispose of contents/container

to …

… in accordance with local/regional/

national/international regulations

(to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or both.

 Mandatory for the general public

if the substance / mixture is

subject to legislation on

hazardous waste. It is

recommended to specify the site

of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in

the safety data sheet if there

are specific disposal

requirements above the normal

expectation for the disposal of

chemicals. Specify the

applicable regulation.

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7.3.2.14 Oxidising solids (continued)

Hazard category Signal word Hazard statement

2 Danger H272 May intensify fire; oxidiser

3 Warning H272 May intensify fire; oxidiser

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other ignition

sources. No smoking.

 Highly recommended

P220

Keep away from clothing and other

combustible materials.

 Highly recommended

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Recommended

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to specify

appropriate media.

 Highly recommended if specific

extinguishing media are required

or appropriate

P501

Dispose of contents/container to

…

… in accordance with

local/regional/national/

international regulations (to be

specified).

Manufacturer/supplier to specify

whether disposal requirements apply

to contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste.

It is recommended to specify the

site of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in the

safety data sheet if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. Specify

the applicable regulation.

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7.3.2.15 Organic peroxides

Hazard category Signal word Hazard statement

Type A Danger H240 Heating may cause an explosion

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended where the

packaging is important for

preventing or suppressing the

effect of dangerous reactions or

explosion

P235

Keep cool

- may be omitted if P411 is given on

the label

 Optional

P370 + P372 + P380 + P373

In case of fire:

Explosion risk.

Evacuate area. DO NOT fight

fire when fire reaches

explosives

 Highly recommended

P403

Store in a well-ventilated place.

- except for temperature controlled

self-reactive substances and mixtures

or organic peroxides because

condensation and consequent freezing

may take place

 Highly recommended, in

combination with P411 or P235

P410

Protect from sunlight.

 Optional if P411 or P235 has

already been assigned

P411

Store at temperatures not

exceeding …ºC/…ºF.

- if temperature control is required

(according to CLP Annex I, section

2.15.2.3) or if otherwise deemed

necessary.

P501

Dispose of

contents/container to …

… in accordance with

local/regional/

national/international regulations

(to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or

both.

 Recommended for inclusion

in the safety data sheet if

there are specific disposal

requirements above the

normal expectation for the

disposal of chemicals.

Specify the applicable

regulation.

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P240

Ground and bond container and

receiving equipment

- if electrostatically sensitive and able

to generate an explosive atmosphere

 Optional unless other conditions

deem it necessary

 Recommended for inclusion in the

safety data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

… Manufacturer/supplier to specify

temperature using the applicable

temperature scale.

 Highly recommended

P420

Store separately.

 Recommended where incompatible

materials are likely to produce a

particular risk. If this statement is

used, text clarifying the

incompatible materials should be

added as supplemental information

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7.3.2.15 Organic peroxides (continued)

Hazard category Signal word Hazard statement

Type B Danger H241 Heating may cause a fire or explosion

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot surfaces,

sparks, open flames and other

ignition sources. No smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended

P235

Keep cool

- may be omitted if P411 is given on the

label

 Optional

P240

Ground and bond container and

receiving equipment

- if electrostatically sensitive and able to

generate an explosive atmosphere

P370 + P380 + P375 [+ P378]

In case of fire: Evacuate area.

Fight fire remotely due to the risk

of explosion. [Use … to

extinguish].

… Manufacturer/supplier to specify

appropriate media.

- text in square brackets to be used if

water increases risk.

 Highly recommended

P403

Store in a well-ventilated place.

- except for temperature controlled

self-reactive substances and

mixtures or organic peroxides

because condensation and

consequent freezing may take place

 Highly recommended, in

combination with P411 or P235

P410

Protect from sunlight.

 Optional if P411 or P235 has

already been assigned

P411

Store at temperatures not

exceeding …ºC/…ºF.

- if temperature control is required

(according to CLP Annex I, section

2.15.2.3) or if otherwise deemed

necessary.

P501

Dispose of

contents/container to …

… in accordance with

local/regional/

national/international

regulations (to be specified).

Manufacturer/supplier to

specify whether disposal

requirements apply to

contents, container or both.

 Mandatory for the general

public if the substance /

mixture is subject to

legislation on hazardous

waste. It is recommended

to specify the site of

disposal while a reference

to the applicable

legislation is not

necessary.

 Recommended for

inclusion in the safety data

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 Optional unless other conditions

deem it necessary

 Recommended for inclusion in the

safety data sheet

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

… Manufacturer/supplier to specify

temperature using the applicable

temperature scale.

 Highly recommended

P420

Store separately.

 Recommended where

incompatible materials are likely

to produce a particular risk. If

this statement is used, text

clarifying the incompatible

materials should be added as

supplemental information

sheet if there are specific

disposal requirements

above the normal

expectation for the

disposal of chemicals.

Specify the applicable

regulation.

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7.3.2.15 Organic peroxides (continued)

Hazard category Signal word Hazard statement

Type C Danger H242 Heating may cause a fire

Type D Danger H242 Heating may cause a fire

Type E Warning H242 Heating may cause a fire

Type F Warning H242 Heating may cause a fire

Precautionary Statements

Prevention

Response

Storage

Disposal

P210

Keep away from heat, hot

surfaces, sparks, open flames

and other ignition sources. No

smoking.

 Highly recommended

P234

Keep only in original packaging.

 Highly recommended

P235

Keep cool

- may be omitted if P411 is given on

the label

 Optional

P370 + P378

In case of fire: Use … to

extinguish.

- if water increases risk.

… Manufacturer/supplier to

specify appropriate media.

 Highly recommended if

specific extinguishing

media are required or

appropriate

P403

Store in a well-ventilated place.

- except for temperature controlled self-

reactive substances and mixtures or

organic peroxides because condensation

and consequent freezing may take place

 Highly recommended, in combination

with P411 or P235

P410

Protect from sunlight.

 Optional if P411 or P235 has already

been assigned

P411

Store at temperatures not exceeding

…ºC/…ºF.

- if temperature control is required

(according to CLP Annex I, section

2.15.2.3) or if otherwise deemed

necessary.

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to

be specified).

Manufacturer/supplier to specify

whether disposal requirements apply to

contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste.

It is recommended to specify the

site of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in the

safety data sheet if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. Specify

the applicable regulation.

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P240

Ground and bond container and

receiving equipment

- if electrostatically sensitive and

able to generate an explosive

atmosphere

 Optional unless other conditions

deem it necessary

 Recommended for inclusion in

the safety data sheet

P280

Wear protective

gloves/protective clothing/eye

protection/face protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

… Manufacturer/supplier to specify

temperature using the applicable

temperature scale.

 Highly recommended

P420

Store separately.

 Recommended where incompatible

materials are likely to produce a

particular risk. If this statement is

used, text clarifying the incompatible

materials should be added as

supplemental information

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7.3.2.16 Corrosive to metals

Hazard category Signal word Hazard statement

1 Warning H290 May be corrosive to metals

Precautionary Statements

Prevention

Response

Storage

Disposal

P234

Keep only in original packaging.

 Recommended for the general public

 Optional for industrial / professional

users

 Recommended for inclusion in the

safety data sheet

P390

Absorb spillage to prevent

material damage.

 Recommended

P406

Store in a corrosion resistant/…

container with a resistant inner

liner.

- may be omitted if P234 is given on the

label

… Manufacturer/supplier to specify

other compatible materials.

 Optional

 Do not use if P234 has already been

assigned

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7.3.3 Specific precautionary statements for health hazards

7.3.3.1 Acute Toxicity – Oral

Hazard category Signal word Hazard statement

1 Danger H300 Fatal if swallowed

2 Danger H300 Fatal if swallowed

3 Danger H301 Toxic if swallowed

Precautionary Statements

Prevention

Response

Storage

Disposal

P264

Wash … thoroughly after

handling.

Manufacturer/supplier to specify parts

of the body to be washed after

handling.

 Highly recommended for the

general public

 Recommended for industrial /

professional users

P270

Do not eat, drink or smoke when

using this product.

 Highly recommended for the

general public for categories 1

and 2

P301 + P310

IF SWALLOWED: Immediately

call a POISON

CENTER/doctor/...

…Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Highly recommended

P321

Specific treatment (see … on

this label).

- if immediate administration of

antidote is required.

… Reference to supplemental first

aid instruction.

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with local/

regional/national/international

regulations (to be specified).

Manufacturer/supplier to specify

whether disposal requirements apply to

contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste. It

is recommended to specify the site

of disposal while a reference to the

applicable legislation is not

necessary.

 Recommended for industrial /

professional users if there are

specific disposal requirements

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 Recommended for the general

public for category 3

 Optional for industrial /

professional users

 Recommended for inclusion in the

safety data sheet

 Highly recommended only in

exceptional cases where

specific treatment is known and

required

P330 in combination with P301

Rinse mouth.

 Highly recommended for the

general public for categories 1

and 2 unless P301+P330+P331

is assigned

 Recommended for the general

public for category 3 unless

P301+P330+P331 is assigned

 Recommended for industrial /

professional users for

categories 1 and 2 unless

P301+P330+P331 is assigned

 Optional for industrial /

professional users for category

above the normal expectation for

the disposal of chemicals. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not

necessary.

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7.3.3.1 Acute Toxicity – Oral (continued)

Hazard category Signal word Hazard statement

4 Warning H302 Harmful if swallowed

Precautionary Statements

Prevention

Response

Storage

Disposal

P264

Wash … thoroughly after handling.

Manufacturer/supplier to specify parts of

the body to be washed after handling.

 Recommended

P270

Do not eat, drink or smoke when

using this product.

 Recommended for the general public

 Optional for industrial / professional

users

 Recommended for inclusion in the

safety data sheet

P301 + P312

IF SWALLOWED: Call a

POISON CENTRE/doctor/…if

you feel unwell.

…Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Optional

P330

Rinse mouth.

 Optional

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified)

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the normal

expectation for the disposal of chemicals.

It is recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

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7.3.3.1 Acute Toxicity – Dermal

Hazard category Signal word Hazard statement

1 Danger H310 Fatal in contact with skin

2 Danger H310 Fatal in contact with skin

Precautionary Statements

Prevention

Response

Storage

Disposal

P262

Do not get in eyes, on skin, or on

clothing.

 Highly recommended

P264

Wash … thoroughly after handling.

Manufacturer / supplier to specify parts of

the body to be washed after handling.

 Highly recommended

P270

Do not eat, drink or smoke when

using this product.

 Highly recommended for the general

public

 Optional for industrial / professional

users.

 Recommended for inclusion in the

safety data sheet

P302 + P352

IF ON SKIN: Wash with plenty of

water/…

…Manufacturer/supplier may specify

a cleansing agent if appropriate, or

may recommend an alternative

agent in exceptional cases if water

is clearly inappropriate.

 Recommended for the general

public

 Recommended for inclusion in

the safety data sheet

P310

Immediately call a POISON

CENTER/doctor/...

…Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Highly recommended, in

combination with P302+P352

P405

Store locked up.

 Highly recommended for

the general public

 Optional for

industrial/professional

users unless other

conditions (Member

State legislation) deem

it necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify

whether disposal requirements apply to

contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste.

It is recommended to specify the

site of disposal while a reference to

the applicable legislation is not

necessary.

 Recommended for inclusion in the

safety data sheet if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. Specify

the applicable regulation.

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

- Specify protective gloves/clothing.

Manufacturer/supplier may further specify

type of equipment where appropriate.

 Highly recommended

P321

Specific treatment (see … on

this label).

- if immediate measures, such as

specific cleansing agent, are

advised

…Reference to supplemental first

aid instruction.

 Highly recommended only in

exceptional cases where specific

treatment is known and

required

P361 + P364

Take off immediately all

contaminated clothing and wash

it before reuse

 Recommended

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7.3.3.1 Acute Toxicity – Dermal (continued)

Hazard category Signal word Hazard statement

3 Danger H311 Toxic in contact with skin

Precautionary Statements

Prevention

Response

Storage

Disposal

P280

Wear protective

gloves/protective

clothing/eye protection/face

protection.

- Specify protective

gloves/clothing.

Manufacturer/supplier may further

specify type of equipment where

appropriate.

 Highly recommended

P302 + P352

IF ON SKIN: Wash with plenty of

water/…

…Manufacturer/supplier may specify a

cleansing agent if appropriate, or may

recommend an alternative agent in

exceptional cases if water is clearly

inappropriate.

 Recommended for the general

public

 Recommended for inclusion in the

safety data sheet

P312

Call a POISON

CENTRE/doctor/…if you feel

unwell.

…Manufacturer/supplier to specify the

appropriate source of emergency

medical advice.

 Recommended

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the normal

expectation for the disposal of

chemicals. It is recommended to specify

the site of disposal while a reference to

the applicable legislation is not

necessary.

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P321

Specific treatment (see … on this

label).

- if immediate measures, such as

specific cleansing agent, are advised

…Reference to supplemental first aid

instruction.

 Highly recommended only in

exceptional cases where specific

treatment is known and required

P361+P364

Take off immediately all

contaminated clothing and wash

it before reuse.

 Recommended

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7.3.3.1 Acute Toxicity – Dermal (continued)

Hazard category Signal word Hazard statement

4 Warning H312 Harmful in contact with skin

Precautionary Statements

Prevention

Response

Storage

Disposal

P280

Wear protective gloves/ protective

clothing /eye protection/face

protection.

- Specify protective gloves/clothing.

Manufacturer/supplier may further

specify type of equipment where

appropriate.

 Recommended

P302 + P352

IF ON SKIN: Wash with plenty of

water/…

…Manufacturer/supplier may specify a

cleansing agent if appropriate, or may

recommend an alternative agent in

exceptional cases if water is clearly

inappropriate.

 Optional

P312

Call a POISON CENTRE/doctor/…if

you feel unwell.

…Manufacturer/supplier to specify the

appropriate source of emergency medical

advice.

 Recommended

P501

Dispose of contents/container to …

… in accordance with

local/regional/national/international

regulations (to be specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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P321

Specific treatment (see … on this

label).

- if immediate measures, such as specific

cleansing agent, are advised.

…Reference to supplemental first aid

instruction.

 Highly recommended only in

exceptional cases where specific

treatment is known and required

P362 + P364

Take off contaminated clothing and

wash it before reuse.

 Optional

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7.3.3.1 Acute Toxicity - Inhalation

Hazard category Signal word Hazard statement

1 Danger H330 Fatal if inhaled

2 Danger H330 Fatal if inhaled

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe

dust/fume/gas/mist/vapours/

spray.

Manufacturer/supplier to specify

applicable conditions.

 Highly recommended

P271

Use only outdoors or in a well-

ventilated area.

 Highly recommended for the

general public

 Optional for

industrial/professional users

P304 + P340

IF INHALED: Remove person

to fresh air and keep at rest

in a position comfortable for

breathing.

 Highly recommended

P310

Immediately call a POISON

CENTER/doctor/…

…Manufacturer/supplier to

specify the appropriate source of

emergency medical advice.

 Highly recommended, in

combination with P304+P340

P403 + P233

Store in a well-ventilated

place. Keep container tightly

closed.

- if the substance or mixture is

volatile and may generate a

hazardous atmosphere.

 Highly recommended unless

P404 has already been

assigned

P405

Store locked up.

 Highly recommended for the

general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with

local/regional/national/international

regulations (to be specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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P284

[In case of inadequate

ventilation] wear respiratory

protection.

- text in square brackets may be

used if additional information is

provided with the chemical at the

point of use that explains what type

of ventilation would be adequate for

safe use.

Manufacturer/supplier to specify

equipment.

 Recommended for

industrial/professional users in

exceptional cases where

inadequate

ventilation/organisational

measures cannot sufficiently

prevent inhalation

 Recommended for inclusion in the

safety data sheet

P320

Specific treatment is urgent

(see … on this label)

- if immediate administration of

antidote is required.

… Reference to supplemental

first aid instruction.

 Highly recommended only in

exceptional cases where

specific treatment is known

and required

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7.3.3.1 Acute Toxicity – Inhalation (continued)

Hazard category Signal word Hazard statement

3 Danger H331 Toxic if inhaled

Precautionary Statements

Prevention

Response

Storage

Disposal

P261

Avoid breathing

dust/fume/gas/mist/

vapours/spray.

- may be omitted if P260 is

given on the label.

Manufacturer/supplier to specify

applicable conditions.

 Recommended

P271

Use only outdoors or in a

well-ventilated area.

 Highly recommended for the

general public

 Optional for

industrial/professional users

P304 + P340

IF INHALED: Remove person to fresh

air and keep comfortable for breathing.

 Recommended

P311

Call a POISON CENTER/doctor/...

…Manufacturer/supplier to specify the

appropriate source of emergency medical

advice.

 Recommended, in combination with

P304+P340

P321

Specific treatment (see … on this label)

- if immediate specific measures are

required.

…Reference to supplemental first aid

instruction.

 Highly recommended only in exceptional

cases where specific treatment is known

and required

P403 + P233

Store in a well-ventilated

place. Keep container

tightly closed.

- if the substance or mixture

is volatile and may generate

a hazardous atmosphere.

 Highly recommended

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users

unless other conditions

(Member State

legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify

whether disposal requirements apply to

contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not

necessary.

 Recommended for industrial /

professional users if there are

specific disposal requirements above

the normal expectation for the

disposal of chemicals. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not

necessary.

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7.3.3.1 Acute Toxicity – Inhalation (continued)

Hazard category Signal word Hazard statement

4 Warning H332 Harmful if inhaled

Precautionary Statements

Prevention

Response

Storage

Disposal

P261

Avoid breathing

dust/fume/gas/mist/

vapours/spray.

- may be omitted if P260 is given on

the label.

Manufacturer/supplier to specify

applicable conditions.

 Recommended

P271

Use only outdoors or in a well-

ventilated area.

 Highly recommended for the general

public

 Optional for industrial/professional

users

P304 + P340

IF INHALED: Remove person to

fresh air and keep comfortable for

breathing.

 Optional

P312

Call a POISON CENTRE/doctor/…if

you feel unwell.

…Manufacturer/supplier to specify the

appropriate source of emergency

medical advice.

 Recommended

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7.3.3.2 Skin corrosion/irritation

Hazard category Signal word Hazard statement

Sub-categories 1A, 1B, 1C

and Category 1 Danger H314 Causes severe skin burns and eye damage

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe dust/fume/gas/mist/

vapours/spray.

Manufacturer/supplier to specify

applicable conditions.

- specify do not breathe dusts or mists.

- If inhalable particles of dusts or mists

may occur during use.

 Highly recommended

P264

Wash … thoroughly after handling.

Manufacturer/supplier to specify parts of

the body to be washed after handling.

 Highly recommended for the general

public, unless P280 has already been

assigned

P301 + P330 + P331

IF SWALLOWED: Rinse mouth. Do

NOT induce vomiting.

 Highly recommended for the general

public, provided that medical advice

indicates that the statement is

appropriate

 Recommended for industrial /

professional users, provided that

medical advice indicates that the

statement is appropriate

P303 + P361 + P353

IF ON SKIN (or hair): Take off

immediately all contaminated

clothing. Rinse skin with water [or

shower].

- text in square brackets to be included

where the manufacturer/supplier

considers it appropriate for the specific

chemical.

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of

contents/container to …

…in accordance with

local/regional/

national/international

regulations (to be specified).

Manufacturer/supplier to specify

whether disposal requirements

apply to contents, container or

both.

 Mandatory for the general

public if the substance /

mixture is subject to

legislation on hazardous

waste. It is recommended

to specify the site of

disposal while a reference to

the applicable legislation is

not necessary.

 Recommended for industrial

/ professional users if there

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 Highly recommended for industrial /

professional users, unless P280 has

already been assigned

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

- Specify protective gloves/clothing and

eye/face protection.

Manufacturer/supplier may further specify

type of equipment where appropriate.

 Highly recommended

P363

Wash contaminated clothing before

reuse.

 Recommended for the general public

 Recommended for inclusion in the

safety data sheet

P304 + P340

If INHALED: Remove person to fresh

air and keep comfortable for

breathing.

 Optional

P310

Immediately call a POISON

CENTER/doctor/...

…Manufacturer/supplier to specify the

appropriate source of emergency

medical advice.

 Highly recommended, in

combination with P303+P361+P353,

P305+P351+ P338 or P301 + P330

+ P331

P321

Specific treatment (see … on this

label).

…Reference to supplemental first aid

instruction.

Manufacturer/supplier may specify a

cleansing agent if appropriate.

are specific disposal

requirements above the

normal expectation for the

disposal of chemicals. It is

recommended to specify the

site of disposal while a

reference to the applicable

legislation is not necessary.

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 Highly recommended only in

exceptional cases where specific

treatment is known and required

P305 + P351 + P338

IF IN EYES: Rinse cautiously with

water for several minutes. Remove

contact lenses, if present and easy

to do. Continue rinsing.

 Highly recommended

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7.3.3.2 Skin corrosion/irritation (continued)

Hazard category Signal word Hazard statement

2 Warning H315 Causes skin irritation

Precautionary Statements

Prevention

Response

Storage

Disposal

P264

Wash … thoroughly after

handling.

… Manufacturer/supplier to specify

parts of the body to be washed after

handling.

 Recommended

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

- Specify protective gloves.

Manufacturer/supplier may further

specify type of equipment where

appropriate.

 Recommended

P302 + P352

IF ON SKIN: Wash with plenty of water/...

…Manufacturer/supplier may specify a cleansing

agent if appropriate, or may recommend an

alternative agent in exceptional cases if water is

clearly inappropriate.

 Optional for the general public

 Recommended for inclusion in the safety data

sheet

P321

Specific treatment (see … on this label).

…Reference to supplemental first aid instruction.

Manufacturer/supplier may specify a cleansing

agent if appropriate.

 Recommended only in exceptional cases where

specific treatment is known and required

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P332 + P313

If skin irritation occurs: Get medical

advice/attention.

- may be omitted when P333 + P313 is given on

the label.

 Optional

P362 + P364

Take off contaminated clothing and wash it

before reuse.

 Optional

 Recommended for inclusion in the safety data

sheet

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7.3.3.3 Serious eye damage - only

Hazard category Signal word Hazard statement

1 Danger H318 Causes serious eye damage

Precautionary Statements

Prevention

Response

Storage

Disposal

P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

- Specify eye/face protection.

Manufacturer/supplier may further

specify type of equipment where

appropriate.

 Highly recommended

P305 + P351 + P338

IF IN EYES: Rinse cautiously with

water for several minutes. Remove

contact lenses, if present and easy to

do. Continue rinsing.

 Highly recommended

P310

Immediately call a POISON CENTER/

doctor/...

…Manufacturer/supplier to specify the

appropriate source of emergency medical

advice.

 Highly recommended, in combination

with P305+P351+P338

Where a chemical is classified as skin corrosion Sub-Category 1A, 1B, 1C or Category 1, labelling for serious eye damage/eye irritation can be omitted as this information

is already included in the hazard statement for skin corrosion Category 1 (H314).

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7.3.3.3 Eye irritation – only

Hazard category Signal word Hazard statement

2 Warning H319 Causes serious eye irritation

Precautionary Statements

Prevention

Response

Storage

Disposal

P264

Wash … thoroughly after handling.

… Manufacturer/supplier to specify parts of the body to

be washed after handling.

 Optional for the industrial/ professional users

 Recommended for the general public

P280

Wear protective gloves/protective clothing/eye

protection/face protection.

- Specify eye/face protection.

Manufacturer/supplier may further specify type of

equipment where appropriate.

 Recommended

P305 + P351 + P338

IF IN EYES: Rinse cautiously

with water for several

minutes. Remove contact

lenses, if present and easy to

do. Continue rinsing.

 Recommended for the general

public

 Recommended for inclusion in

the safety data sheet

P337 + P313

If eye irritation persists: Get

medical advice/attention.

 Recommended

Where a chemical is classified as skin corrosion Sub-Category 1A, 1B, 1C or Category 1, labelling for serious eye damage/eye irritation can be omitted as this information

is already included in the hazard statement for skin corrosion Category 1 (H314).

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7.3.3.4 Respiratory sensitisation

Hazard category Signal word Hazard statement

1, 1A, 1B Danger H334 May cause allergy or asthma symptoms or breathing

difficulties if inhaled

Precautionary Statements

Prevention

Response

Storage

Disposal

P261

Avoid breathing dust/fume/gas/mist/

vapours/spray.

- may be omitted if P260 is given on the label.

Manufacturer/supplier to specify applicable conditions.

 Highly recommended

P284

[In case of inadequate ventilation] wear

respiratory protection.

- text in square brackets may be used if additional

information is provided with the chemical at the

point of use that explains what type of ventilation

would be adequate for safe use.

Manufacturer/supplier to specify equipment.

 Recommended for industrial/professional users in

exceptional cases where inadequate

ventilation/organisational measures cannot

sufficiently prevent inhalation

 Recommended for inclusion in the safety data

sheet

P304 + P340

IF INHALED: Remove

person to fresh air and

keep comfortable for

breathing.

 Highly recommended

P342 + P311

If experiencing

respiratory symptoms:

Call a POISON CENTER or

doctor/physician.

 Highly recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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7.3.3.4 Skin sensitisation

Hazard category Signal word Hazard statement

1, 1A, 1B Warning H317 May cause an allergic skin reaction

Precautionary Statements

Prevention

Response

Storage

Disposal

P261

Avoid breathing dust/fume/gas/mist/

vapours/spray.

- may be omitted if P260 is given on the

label.

Manufacturer/supplier to specify applicable

conditions.

 Recommended

P272

Contaminated work clothing should not

be allowed out of the workplace.

 Not intended to be used for the general

public

 Optional for industrial/professional users

P302 + P352

IF ON SKIN: Wash with plenty of

water/...

…Manufacturer/supplier may specify a

cleansing agent if appropriate, or may

recommend an alternative agent in

exceptional cases if water is clearly

inappropriate.

 Recommended for the general

public

 Recommended for inclusion in the

safety data sheet

P333 + P313

If skin irritation or rash occurs: Get

medical advice/attention.

 Recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

- Specify protective gloves.

Manufacturer/supplier may further specify

type of equipment where appropriate.

 Highly recommended

P321

Specific treatment (see … on this

label)

… Reference to supplemental first aid

instruction.

Manufacturer/supplier may specify a

cleansing agent if appropriate.

 Highly recommended only in

exceptional cases where specific

treatment is known and required

P362+P364

Take off contaminated clothing and

wash it before reuse.

 Recommended

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7.3.3.5 Germ cell mutagenicity

Hazard category Signal word Hazard statement

1A and 1B Danger H340 May cause genetic defects (state route of exposure if it is

conclusively proven that no other routes of exposure cause

the hazard)

2 Warning H341 Suspected of causing genetic defects (state route of exposure

if it is conclusively proven that no other routes of exposure cause

the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P201

Obtain special instructions before use.

 Highly recommended for category 1A

and 1B

 Recommended for category 2

P202

Do not handle until all safety

precautions have been read and

understood.

 Optional where P201 is assigned

P308 + P313

IF exposed or concerned: Get

medical advice/attention.

 Highly recommended for

category 1A and 1B

 Recommended for category 2

P405

Store locked up.

 Highly recommended for the

general public

 Optional for

industrial/professional users

unless other conditions

(Member State legislation)

deem it necessary

P501

Dispose of contents/container to

…

… in accordance with local/regional/

national/international regulations (to

be specified).

Manufacturer/supplier to specify

whether disposal requirements apply

to contents, container or both.

 Mandatory for the general public if

the substance / mixture is subject

to legislation on hazardous waste.

It is recommended to specify the

site of disposal while a reference

to the applicable legislation is not

Substances and mixtures which are listed in Appendix 1-6 of Annex XVII to Regulation (EC) No 1907/2006 (REACH) and which are assigned H340,

H350 or H360 are restricted to industrial / professional users and normally not supplied to the general public (see entry 28, 29 and 30 in Annex XVII to

REACH, as amended). The list of subsequent amendments of Annex XVII is accessible at http://echa.europa.eu/web/guest/regulations/reach/legislation.

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

necessary.

 Recommended for industrial /

professional users if there are

specific disposal requirements

above the normal expectation for

the disposal of chemicals. It is

recommended to specify the site

of disposal while a reference to

the applicable legislation is not

necessary.

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7.3.3.6 Carcinogenicity

Hazard category Signal word Hazard statement

1A and 1B Danger H350 May cause cancer (state route of exposure if it is conclusively

proven that no other routes of exposure cause the hazard)

2 Warning H351 Suspected of causing cancer (state route of exposure if it is

conclusively proven that no other routes of exposure cause the

hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P201

Obtain special instructions before

use.

 Highly recommended for category

1A and 1B

 Recommended for category 2

P202

Do not handle until all safety

precautions have been read and

understood.

 Optional where P201 is assigned

P308 + P313

IF exposed or concerned: Get

medical advice/attention.

 Highly recommended for

category 1A and 1B

 Recommended for category

P405

Store locked up.

 Highly recommended for the

general public

 Optional for

industrial/professional users

unless other conditions

(Member State legislation)

deem it necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if

the substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not

necessary.

Substances and mixtures which are listed in Appendix 1-6 of Annex XVII to Regulation (EC) No 1907/2006 (REACH) and which are assigned H340, H350

or H360 are restricted to industrial / professional users and normally not supplied to the general public (see entry 28, 29 and 30 in Annex XVII to REACH

as amended). The list of subsequent amendments of Annex XVII is accessible at: http://echa.europa.eu/web/guest/regulations/reach/legislation.

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P280

Wear protective gloves/protective

clothing/eye protection/face

protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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7.3.3.7 Reproductive toxicity

Hazard category Signal word Hazard statement

1A and 1B Danger H360 May damage fertility or the unborn child

(state specific effect if known)

(state route of exposure if it is conclusively proven

that no other routes of exposure cause the hazard)

2 Warning H361 Suspected of damaging fertility or the unborn child

(state specific effect if known)

(state route of exposure if it is conclusively proven that

no other routes of exposure cause the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P201

Obtain special instructions

before use.

 Highly recommended for

category 1A and 1B

 Recommended for category 2

P202

Do not handle until all safety

precautions have been read and

understood.

P308 + P313

IF exposed or concerned: Get

medical advice/attention.

 Highly recommended for

category 1A and 1B

 Recommended for category 2

P405

Store locked up.

 Highly recommended

for the general

public

 Optional for

industrial /

professional users

unless other

conditions (Member

State legislation)

deem it necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation

on hazardous waste. It is recommended to

specify the site of disposal while a reference

Substances and mixtures which are listed in Appendix 1-6 of Annex XVII to Regulation (EC) No 1907/2006 (REACH) and which are assigned H340,

H350 or H360 are restricted to industrial / professional users and normally not supplied to the general public (see entry 28, 29 and 30 in Annex XVII to

REACH as amended). The list of subsequent amendments of Annex XVII is accessible at ECHA website:

http://echa.europa.eu/web/guest/regulations/reach/legislation).

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 Optional where P201 is assigned

P280

Wear protective

gloves/protective clothing/eye

protection/face protection.

Manufacturer/supplier to specify the

appropriate type of equipment.

 Highly recommended

to the applicable legislation is not necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal expectation

for the disposal of chemicals. It is

recommended to specify the site of disposal

while a reference to the applicable legislation

is not necessary.

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7.3.3.7 Reproductive toxicity (continued)

Hazard category Signal word Hazard statement

Additional category for effects on

or via lactation No signal word H362 May cause harm to breast-fed children

Precautionary Statements

Prevention

Response

Storage

Disposal

P201

Obtain special instructions before use.

 Highly recommended

P260

Do not breathe dust/fume/gas/mist/

vapours/spray.

Manufacturer/supplier to specify applicable

conditions.

- Specify do not breathe dusts or mists.

- if inhalable particles of dusts or mists may

occur during use.

 Highly recommended

P263

Avoid contact during pregnancy and

while nursing.

 Highly recommended

P308 + P313

IF exposed or concerned: Get

medical advice/attention.

 Recommended

No hazard

pictogram

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P264

Wash … thoroughly after handling.

… Manufacturer / supplier to specify parts of

the body to be washed after handling.

 Optional

P270

Do not eat, drink or smoke when using

this product.

 Recommended for the general public

 Optional for industrial / professional users

 Recommended for inclusion in the safety

data sheet

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7.3.3.8 Specific target organ toxicity after single exposure

Hazard category Signal word Hazard statement

1 Danger H370 Causes damage to organs (or state all organs affected, if known)

(state route of exposure if it is conclusively proven that no other

routes of exposure cause the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe

dust/fume/gas/mist/

vapours/spray.

Manufacturer/supplier to specify

applicable conditions.

 Highly recommended where the

substance / mixture is volatile or a

gas or where exposure via

inhalation is possible, e.g. through

spraying or inhalable dust or in

case H370 indicates inhalation as a

route of exposure

P264

Wash … thoroughly after handling.

… Manufacturer / supplier to specify

parts of the body to be washed after

handling.

 Optional

P308 + P311

IF exposed or concerned: Call

a POISON CENTER/doctor…

Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Highly recommended

P321

Specific treatment (see … on

this label)

- if immediate measures are

required.

… Reference to supplemental first

aid instruction.

 Highly recommended only in

exceptional cases where

specific treatment is known

and required

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

is not necessary.

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P270

Do not eat, drink or smoke when

using this product.

 Recommended for the general

public

 Optional for industrial / professional

users

 Recommended for inclusion in the

safety data sheet

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7.3.3.8 Specific target organ toxicity after single exposure (continued)

Hazard category Signal word Hazard statement

2 Warning H371 May cause damage to organs (or state all organs affected, if

known)

(state route of exposure if it is conclusively proven that no other

routes of exposure cause the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe

dust/fume/gas/mist/

vapours/spray.

Manufacturer/supplier to specify

applicable conditions.

 Highly recommended where the

substance / mixture is volatile or a

gas or where exposure via

inhalation is possible, e.g. through

spraying or inhalable dust or in

case H371 indicates inhalation as a

route of exposure

P264

Wash … thoroughly after handling.

… Manufacturer / supplier to specify

parts of the body to be washed after

handling.

 Optional

P308 + P311

IF exposed or concerned: Call

a POISON CENTER/ doctor/...

Manufacturer/supplier to specify

the appropriate source of

emergency medical advice

 Recommended

P405

Store locked up.

 Highly recommended for

the general public

 Optional for industrial /

professional users unless

other conditions (Member

State legislation) deem it

necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the

normal expectation for the disposal of

chemicals. It is recommended to

specify the site of disposal while a

reference to the applicable legislation

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P270

Do not eat, drink or smoke when

using this product.

 Recommended for the general

public

 Optional for industrial / professional

users

 Recommended for inclusion in the

safety data sheet

is not necessary.

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7.3.3.8 Specific target organ toxicity after single exposure (continued)

Hazard category Signal word Hazard statement

3 Warning H335 May cause respiratory irritation; or

H336 May cause drowsiness or dizziness

Precautionary Statements

Prevention

Response

Storage

Disposal

P261

Avoid breathing

dust/fume/gas/mist/

vapours/spray.

- may be omitted if P260 is

given on the label.

Manufacturer/supplier to specify

applicable conditions.

 Recommended

P271

Use only outdoors or in a

well-ventilated area.

 Highly recommended for the

general public

 Optional for industrial /

professional users

P304 + P340

IF INHALED: Remove person to

fresh air and keep comfortable

for breathing.

 Optional

P312

Call a POISON

CENTRE/doctor/…if you feel

unwell.

…Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Recommended

P403 + P233

Store in a well-ventilated

place. Keep container tightly

closed.

- if the substance or mixture is

volatile and may generate a

hazardous atmosphere.

 Recommended unless P404 is

assigned

P405

Store locked up.

 Highly recommended for the

general public

 Optional for industrial /

professional users unless other

conditions (Member State

legislation) deem it necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the normal

expectation for the disposal of

chemicals. It is recommended to specify

the site of disposal while a reference to

the applicable legislation is not

necessary.

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7.3.3.9 Specific target organ toxicity after repeated exposure

Hazard category Signal word Hazard statement

1 Danger H372 Causes damage to organs (state all organs affected, if known)

through prolonged or repeated exposure (state route of

exposure if it is conclusively proven that no other routes of

exposure cause the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe dust/fume/gas/mist/

vapours/spray.

Manufacturer/supplier to specify

applicable conditions.

 Highly recommended where the

substance / mixture is volatile or a

gas or where exposure via inhalation

is possible, e.g. through spraying or

inhalable dust or in case H372

indicates inhalation as a route of

exposure

P264

Wash … thoroughly after handling.

… Manufacturer / supplier to specify parts

of the body to be washed after handling.

 Optional

P314

Get medical advice/attention

if you feel unwell.

 Recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether disposal

requirements apply to contents, container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation

on hazardous waste. It is recommended to

specify the site of disposal while a reference

to the applicable legislation is not necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal expectation

for the disposal of chemicals. It is

recommended to specify the site of disposal

while a reference to the applicable legislation

is not necessary.

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P270

Do not eat, drink or smoke when

using this product.

 Recommended for the general public

 Optional for industrial / professional

users

 Recommended for inclusion in the

safety data sheet

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7.3.3.9 Specific target organ toxicity after repeated exposure (continued)

Hazard category Signal word Hazard statement

2 Warning H373 May cause damage to organs (state all organs affected, if

known) through prolonged or repeated exposure (state route of

exposure if it is conclusively proven that no other routes of

exposure

cause the hazard)

Precautionary Statements

Prevention

Response

Storage

Disposal

P260

Do not breathe

dust/fume/gas/mist/vapours/spray.

Manufacturer/supplier to specify

applicable conditions.

 Highly recommended where the

substance / mixture is highly volatile

or a gas or where exposure via

inhalation is possible, e.g. through

spraying or inhalable dust or in case

H373 indicates inhalation as a route

of exposure

P314

Get medical advice/attention

if you feel unwell.

 Recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to

legislation on hazardous waste. It is

recommended to specify the site of

disposal while a reference to the

applicable legislation is not necessary.

 Recommended for industrial /

professional users if there are specific

disposal requirements above the normal

expectation for the disposal of

chemicals. It is recommended to specify

the site of disposal while a reference to

the applicable legislation is not

necessary.

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7.3.3.10 Aspiration hazard

Hazard category Signal word Hazard statement

1 Danger H304 May be fatal if swallowed and enters airways

Precautionary Statements

Prevention

Response

Storage

Disposal

P301 + P310

IF SWALLOWED: Immediately

call a POISON CENTER/

doctor/...

…Manufacturer/supplier to specify

the appropriate source of

emergency medical advice.

 Highly recommended, in

combination with P331

P331

Do NOT induce vomiting.

 Highly recommended, in

combination with P301 +P310

P405

Store locked up.

 Highly recommended for the

general public

 Optional for industrial /

professional users unless other

conditions (Member State

legislation) deem it necessary

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be specified).

Manufacturer/supplier to specify whether disposal

requirements apply to contents, container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation on

hazardous waste. It is recommended to

specify the site of disposal while a reference to

the applicable legislation is not necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal expectation

for the disposal of chemicals. It is

recommended to specify the site of disposal

while a reference to the applicable legislation

is not necessary.

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7.3.4 Specific precautionary statements for environmental hazards

7.3.4.1 Hazardous to the aquatic environment – short-term (acute) aquatic hazard

Hazard category Signal word Hazard statement

1 Warning H400 Very toxic to aquatic life

Precautionary Statements

Prevention

Response

Storage

Disposal

P273

Avoid release to the environment.

- if this is not the intended use.

 Highly recommended

P391

Collect spillage.

 Highly recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation

on hazardous waste. It is recommended to

specify the site of disposal while a reference

to the applicable legislation is not necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal expectation

for the disposal of chemicals. It is

recommended to specify the site of disposal

while a reference to the applicable legislation

is not necessary.

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7.3.4.1 Hazardous to the aquatic environment – long-term (chronic) aquatic hazard

Hazard category Signal word Hazard statement

1 Warning H410 Very toxic to aquatic life with long lasting effects

2 No signal word H411 Toxic to aquatic life with long lasting effects

Precautionary Statements

Prevention

Response

Storage

Disposal

P273

Avoid release to the environment.

- if this is not the intended use.

 Highly recommended

P391

Collect spillage.

 Highly recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation

on hazardous waste. It is recommended to

specify the site of disposal while a

reference to the applicable legislation is not

necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal

expectation for the disposal of chemicals. It

is recommended to specify the site of

disposal while a reference to the applicable

legislation is not necessary.

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7.3.4.1 Hazardous to the aquatic environment – long-term (chronic) aquatic hazard (continued)

Hazard category Signal word Hazard statement

3 No signal word H412 Harmful to aquatic life with long lasting effects

4 No signal word H413 May cause long lasting harmful effects to aquatic life

Precautionary Statements

Prevention

Response

Storage

Disposal

P273

Avoid release to the environment.

- if this is not the intended use.

 Recommended

P501

Dispose of contents/container to …

… in accordance with local/regional/

national/international regulations (to be

specified).

Manufacturer/supplier to specify whether

disposal requirements apply to contents,

container or both.

 Mandatory for the general public if the

substance / mixture is subject to legislation

on hazardous waste. It is recommended to

specify the site of disposal while a reference

to the applicable legislation is not necessary.

 Recommended for industrial / professional

users if there are specific disposal

requirements above the normal expectation

for the disposal of chemicals. It is

recommended to specify the site of disposal

while a reference to the applicable legislation

is not necessary.

No hazard

pictogram

is used

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7.3.5 Additional hazards

7.3.5.1 Hazardous to the ozone layer

Hazard category Signal word Hazard statement

1 Warning H420 Harms public health and the environment by destroying ozone

in the upper atmosphere

Precautionary Statements

Prevention

Response

Storage

Disposal

P502

Refer to manufacturer or supplier for

information on recovery or recycling

 Mandatory for the general public

 Highly recommended for industrial /

professional users

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7.4. Examples for the selection of precautionary statements for

the label

This section provides practical examples on how to select precautionary statements for

various model substances. The set of precautionary statements to be prioritised for the

label is highlighted in bold underlined (highly recommended) and underlined

(recommended), while the optional statements appear in normal letters (no highlighting)

and the statements not to be used/unless condition applies/ inclusion on safety data

sheet only are marked in grey colour.

Please note that even if a substance or mixture has the same hazards as one of the

following examples, another set of precautionary statements might be appropriate based

on the specific conditions for use given in the tables above.

Example A. Substance X assigned a physical and various health hazard

classifications

A. Classification and hazard statements:

Flam. Liq. 2 H225 Highly flammable liquid and vapour

Acute Tox. 3 (oral) H301 Toxic if swallowed

Acute Tox. 3 (dermal) H311 Toxic in contact with skin

Acute Tox. 3 (inhalation) H331 Toxic if inhaled

STOT-SE 1 H370 Causes damage to liver through dermal exposure

B. Further information:

Substance X is presumed to be volatile, but not so as to generate a potentially explosive

atmosphere.

There is possible exposure via inhalation.

Specific extinguishing media are not necessary. Specific treatment/measures is/are not

urgently required.

No specific disposal precautionary statements are required since the substance is not

intended to be used by the general public, but only by industrial/professional users.

C. Precautionary statements on the basis of the classification (see Annexes I and IV to

CLP) and according to this guidance document:

Acute Tox. 3

(Oral)

Acute Tox. 3

(Dermal)

Acute Tox. 3

(Inhalation)

STOT-SE 1

Flam. Liq. 2

P264

P270

P280

P261

P271

P260

P264

P270

P210

P233

P240

P241

P242

P243

P280

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Acute Tox. 3

(Oral)

Acute Tox. 3

(Dermal)

Acute Tox. 3

(Inhalation)

STOT-SE 1

Flam. Liq. 2

P301 + P310

P321

P330

P312

P321

P361 + P364

P363

P302 + P352

P304 + P340

P311

P321

P308 + P311

P321

P303 + P361 + P353

P370 + P378

P405

P403 + P233

P405

P403 + P235

P501

Explanation on use of bolding, underline and grey marker:

PXXX = highly recommended; PXXX = recommended; PXXX = optional; PXXX = not to be

used/unless condition applies/inclusion on safety data sheet only

D. Selection of highly recommended and recommended precautionary statements:

When the same statement is assigned to different hazards, but with a different priority,

the most conservative approach is taken. Where appropriate, precautionary statements

are combined into a single combination statement. Duplication of individual phrases is

avoided. The selection results in the following set of P-statements:

P210 Keep away from heat, hot surfaces, sparks, open flames and

other ignition sources. No smoking.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye

protection/face protection.

P301+P310 IF SWALLOWED: Immediately call a POISON

CENTER/doctor/…

P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor/...

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for

breathing.

P403+P233 Store in a well-ventilated place. Keep container tightly

closed.

E. Result:

Selection in line with the guidance results in seven precautionary statements. A

substantial reduction is achieved compared to the starting set of potentially

applicable statements for the hazard label, assignable on the basis of the

underlying hazards. For example: P261 can be omitted, as P260 is already

assigned for the label.

The selected precautionary statements must be placed on the CLP hazard label. As an

SDS needs to be prepared, the statements would also have to be included in the SDS,

under heading 2.2 “Label elements” (see the Guidance on the compilation of safety data

sheets). The de-selected statements can be introduced under the relevant headings of

the SDS to provide the industrial or professional user with sufficient information to

handle the substance safely.

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Example B. Substance Y assigned a severe physical and health hazard

classification

A. Classification and hazard statements:

Ox. Sol. 1 H271 May cause fire or explosion; strong oxidiser

Skin Corr. 1A H314 Causes severe skin burns and eye damage

B. Further information:

Substance Y is a granular solid and is presumed to be non-volatile. Dust exposure during

handling and use is possible.

Specific extinguishing media are not necessary.

Specific treatment/measures is/are not urgently required. No specific disposal

precautionary statements are required since the substance is not intended to be used by

the general public, but only by industrial/professional users.

C. Precautionary statements on the basis of the classification (see Annexes I and IV to

CLP) and according to this guidance document:

Ox. Sol. 1

Skin Corr. 1A

P210

P220

P280

P283

P260

P264

P280

P306+P360

P371+P380+P375

P370+P378

P301+P330+P331

P303+P361+P353

P363

P304+P340

P310

P321

P305+P351+P338

P405

P501

D. Selection of highly recommended and recommended precautionary statements:

When the same statement is assigned to different hazards, but with a different priority,

the most conservative approach is taken (i.e. the highest priority must be taken into

account). Where appropriate, precautionary statements are combined into a single

combination statement. Duplication of individual phrases is avoided. The selection results

in the following set of P-statements:

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P210 Keep away from heat, hot surfaces, sparks, open

flames and other ignition sources. No smoking.

P220 Keep away from clothing and other combustible

materials

P260 Do not breathe

dust/fume/gas/mist/vapours/spray.

P280 Wear protective gloves/protective clothing/eye

protection/ face protection.

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353+310 IF ON SKIN (or hair): Take off immediately all

contaminated clothing. Rinse skin with water [or

shower]. Immediately call a POISON

CENTER/doctor/...

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several

minutes. Remove contact lenses, if present and easy

to do. Continue rinsing.

P371+P380+P375 In case of major fire and large quantities: Evacuate

area. Fight fire remotely due to the risk of explosion.

E. Result:

Selection in line with this guidance document results in eight, mostly combined,

precautionary statements. A substantial reduction is achieved compared to the

starting set of potentially applicable statements for the CLP hazard label,

assignable on the basis of the underlying hazards.

The selected precautionary statements must be placed on the CLP hazard label. As an

SDS needs to be prepared, they would also have to be included in the SDS, under

heading 2.2 “Label elements” (see the Guidance on the compilation of safety data

sheets).

The de-selected statements can be introduced under the relevant headings of the SDS to

provide the industrial or professional user with sufficient information to handle the

substance safely.

Example C. Substance Z assigned physical, health and environmental

classifications

A. Classification and hazard statements:

Pyr. Liq. 1 H250 Catches fire spontaneously if exposed to air

Water-react. 1 H260 In contact with water releases flammable gases which may

ignite spontaneously

Skin Corr. 1B H314 Causes severe skin burns and eye damage

Aquatic Acute 1 H400 Very toxic to aquatic life

Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects

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B. Further information:

Substance Z should be regarded as volatile. Therefore, there is a possible exposure via

inhalation. Specific extinguishing media are necessary, because water will increase the

risk when used for the extinguishing of fire.

As the disposal of the packaging presents a hazard to human health or the environment,

specific disposal precautionary statements are required (although the substance is not

intended to be used by the general public, but only by industrial/professional users). The

hazard statement H400 is omitted from the label to avoid duplication with H411.

C. Precautionary statements on the basis of the classification (see Annexes I and IV to

CLP) and according to this guidance document:

Pyr. Liq.1

Water-react. 1

Skin Corr. 1B

Aquatic

Acute 1

Aquatic

Chronic 1

P210

P222

P233

P280

P231+P232

P223

P231+P232

P280

P260

P264

P280

P273

P302+P334

P370+P378

P302+P335+P334

P370+P378

P301+P330+P331

P303+P361+P353

P363

P304+P340

P310

P321

P305+P351+P338

P391

P402+P404

P405

P501

D. Selection of highly recommended and recommended precautionary statements:

When the same statement is assigned to different hazards, but with a different priority,

the most conservative approach is taken (i.e. the highest priority must be taken into

account). Where appropriate, precautionary statements are combined into a single

combination statement. Duplication of individual phrases is avoided.

P303+ P361+P353 IF ON SKIN (or hair): Take off immediately all

contaminated clothing. Rinse skin with water [or shower].

and

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P302+P335+P334+P310 IF ON SKIN: Brush off loose particles from skin. Immerse

in cool water

. Immediately call a POISON

CENTER/doctor/…)

were merged into one single combination phrase:

P303+ P335+P334+P310+P361 where duplication of the message was avoided.

The selection results in the following set of P-statements:

P210 Keep away from heat, hot surfaces,

sparks, open flames and other ignition

sources. No smoking.

P260 Do not breathe dust/fume/gas/mist/

vapours/spray.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective

clothing/eye protection/face protection.

P231+P232 Handle and store under inert gas. Protect

from moisture.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce

vomiting.

P303+ P335+P334+P310+P361 IF ON SKIN (or hair): Brush off loose

particles from skin. Immerse in cool

water

. Immediately call a POISON

CENTER/doctor/… Take off immediately

all contaminated clothing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water

for several minutes. Remove contact

lenses, if present and easy to do.

Continue rinsing.

P370+P378 In case of fire: Use … to extinguish.

E. Result:

Selection in line with this guidance document results in nine, partly combined,

precautionary statements.

A substantial reduction is achieved compared to the starting set of potentially

applicable statements for the CLP hazard label, assignable on the basis of the

underlying hazards. For example, P264 has not been selected, because P280 is

more relevant.

To further reduce the number of the P-statements and the amount of digestible

information on the label, the statements P391 and P501 have been put in the

SDS, as the prevention and response statements for the physical and health

hazards appear to contain the more urgent advice for the label.

The sub-phrase of P334 “or wrap in wet bandages” is not to be used for water-reactive

substances and mixtures category 1 (Table 7.3.2.12 in section 7.3 of this guidance document).

The sub-phrase of P334 “or wrap in wet bandages” is not to be used for water-reactive

substances and mixtures category 1 (Table 7.3.2.12 in section 7.3 of this guidance document).

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The selected precautionary statements must be placed on the CLP hazard label. As an

SDS needs to be prepared, they would also have to be included in the SDS, under

heading 2.2 “Label elements” (see the Guidance on the compilation of safety data

sheets). The de-selected statements can be introduced under the relevant headings of

the SDS to provide the industrial or professional user with sufficient information to

handle the substance safely.

Example D. Mixture ABC for use by the general public

A. Classification and hazard statements:

Flam. Liq. 2 H225 Highly flammable liquid and vapour

Acute Tox. 4 (oral) H302 Harmful if swallowed

Skin irrit. 2 H315 Causes skin irritation

B. Further information:

Mixture ABC is presumed to be volatile, but not so as to generate a potentially explosive

atmosphere. Specific extinguishing media are not necessary. Specific treatment is not

urgently required.

There are no specific disposal requirements. The mixture is intended to be used by the

general public.

C. Precautionary statements on the basis of the classification (see Annexes I and IV to

CLP) and according to this guidance document:

Flam. Liq. 2

Acute Tox. 4 (Oral)

Skin Irrit. 2

P101, P102

P210

P233

P240

P241

P242

P243

P280

P264

P270

P264

P280

P303 + P361 + P353

P370 + P378

P301+P312

P330

P302+P352

P321

P332+P313

P362+P364

P403 + P235

P501

D. Selection of highly recommended and recommended precautionary statements:

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When the same statement is assigned to different hazards, but with a different priority,

the most conservative approach is taken. Where appropriate, precautionary statements

are combined into a single combination statement. Duplication of individual phrases is

avoided. The selection results in the following set of P-statements:

P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P210 Keep away from heat, hot surfaces, sparks, open flames and other

ignition sources. No smoking.

P233 Keep container tightly closed.

P264 Wash … thoroughly after handling.

P280 Wear protective gloves.

P501 Dispose of contents/container to …

E. Result:

Selection in line with this guidance document results in seven precautionary

statements. A substantial reduction is achieved compared to the starting set of

potentially applicable statements for the CLP hazard label, assignable on the

basis of the underlying hazards.

The selected precautionary statements must be placed on the CLP hazard label. As an

SDS needs to be prepared, they would also have to be included in the SDS, under

heading 2.2 “Label elements” (see the Guidance on the compilation of safety data

sheets).

The de-selected statements can be introduced under the relevant headings of the SDS to

provide the industrial or professional user with sufficient information to handle the

substance safely.

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Appendix: Glossary of selected terms used in this

guidance document

ADR the European Agreement concerning the

International Carriage of Dangerous Goods by

Road (concluded in Geneva on 30 September

1957) that has been implemented within the

EU through Directive 2008/68/EC;

Acute toxicity those adverse effects occurring following oral

or dermal administration of a single dose of a

substance or a mixture, or multiple doses

given within 24 hours, or an inhalation

exposure of 4 hours;

Acute aquatic toxicity the intrinsic property of a substance to be

injurious to an organism in a short term

exposure to that substance;

Aerosols this means aerosol dispensers, are any non-

refillable receptacles made of metal, glass or

plastics and containing a gas compressed,

liquefied or dissolved under pressure, with or

without a liquid, paste or powder, and fitted

with a release device allowing the contents to

be ejected as solid or liquid particles in

suspension in a gas, as a foam, paste or

powder or in a liquid state or in a gaseous

state;

Alloy a metallic material, homogeneous on a

macroscopic scale, consisting of two or more

elements so combined that they cannot be

readily separated by mechanical means;

alloys are considered to be mixtures for the

purposes of the CLP Regulation;

Article an object which during production is given a

special shape, surface or design which

determines its function to a greater degree

than does its chemical composition;

Aspiration the entry of a liquid or solid substance or

mixture directly through the oral or nasal

cavity, or indirectly from vomiting, into the

trachea and lower respiratory system;

BPR Regulation (EU) No 528/2012 of the European

Parliament and of the Council of 22 May 2012

concerning the making available on the

market and use of biocidal products (Biocidal

Products Regulation);

Carcinogen a substance or a mixture of substances which

induces cancer or increases its incidence;

CAS Chemical Abstract Service;

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Chemically unstable gas a flammable gas that is able to react

explosively even in the absence of air or

oxygen;

Chronic aquatic toxicity the intrinsic property of a substance to cause

adverse effects to aquatic organisms during

exposures which are determined in relation to

the life-cycle of the organism;

CLP or CLP Regulation Regulation (EC) No 1272/2008 on

Classification, Labelling and Packaging of

Substances and Mixtures;

CMR a substance or mixture which is carcinogenic,

mutagenic or toxic to reproduction;

Competent authority (CA) the authority or authorities or bodies

established by the member states to carry out

the obligations arising from the CLP

Regulation;

Corrosive to metals a substance or a mixture which by chemical

action will materially damage, or even destroy

metals;

CRC child-resistant closure;

CRF child-resistant fastening;

Distributor any natural or legal person established within

the Community, including a retailer, who only

stores and places on the market a substance,

on its own or in a mixture, for third parties;

Downstream user any natural or legal person established within

the Community, other than the manufacturer

or the importer, who uses a substance, either

on its own or in a mixture, in the course of his

industrial or professional activities. A

distributor or a consumer is not a downstream

user. A re-importer, exempted pursuant to

Article 2(7)(c) REACH Regulation, shall be

regarded as a downstream user;

DPD Dangerous Preparations Directive

(1999/45/EC);

DSD Dangerous Substances Directive

(67/548/EEC);

ECHA European Chemicals Agency or “the Agency,”

established under the REACH Regulation;

EU European Union;

Explosive article an article containing one or more explosive

substances or mixtures;

Explosive substance or mixtures a solid or liquid substance or mixture of

substances which is in itself capable by

chemical reaction of producing gas at such a

temperature and pressure and at such a

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speed as to cause damage to the

surroundings. Pyrotechnic substances are

included even when they do not evolve gases;

Eye irritation the production of changes in the eye following

the application of test substance to the

anterior surface of the eye, which are fully

reversible within 21 days of application;

Flammable gas a gas or gas mixture having a flammable

range with air at 20 °C and a standard

pressure of 101.3 kPa;

Flammable liquid a liquid having a flash point of not more than

60°C;

Flash point the lowest temperature (corrected to a

standard pressure of 101.3 kPa) at which the

application of an ignition source causes the

vapours of a liquid to ignite under specified

test conditions;

Flammable solid a solid which is readily combustible, or may

cause or contribute to fire through friction.

Readily combustible solids are powdered,

granular, or pasty substances or mixtures

which are dangerous if they can be easily

ignited by brief contact with an ignition

source, such as a burning match, and if the

flame spreads rapidly;

GHS Globally Harmonised System of Classification

and Labelling of Chemicals developed within

the United Nations (UN) structure - the

international criteria agreed by the United

Nation Economic and Social Council (UN

ECOSOC) for the classification and labelling of

hazardous substances and mixtures;

Hazard category the division of criteria within each hazard

class, specifying hazard severity;

Hazard class the nature of the physical, health or

environmental hazard;

Hazard pictogram graphical composition that includes a symbol

plus other graphic elements, such as a border,

background pattern or colour that is intended

to convey specific information about the

hazard concerned;

Hazard statement a phrase assigned to a hazard class and

category that describes the nature of the

hazards of a hazardous substance or mixture,

including, where appropriate, the degree of

hazard;

Hazardous means fulfilling the criteria relating to physical

hazards, health hazards or environmental

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hazards, laid down in Parts 2 to 5 of Annex I

to the CLP Regulation;

IMDG Code International Maritime Dangerous Goods Code

for the transport of dangerous goods by sea;

Import the physical introduction into the customs

territory of the Community;

Importer any natural or legal person established within

the Community who is responsible for import;

INCI International Nomenclature of Cosmetic

Ingredients;

Intermediate packaging packaging placed between inner packaging,

or articles, and outer packaging;

IUCLID International Uniform Chemical Information

Database;

IUPAC International Union of Pure and Applied

Chemistry;

Label an appropriate group of written, printed or

graphic information elements concerning a

hazardous substances or mixture, selected as

relevant to the target sector (s), that is

affixed to, printed on, or attached to the

immediate container of a hazardous

substance or mixture, or to the outside

packaging of a hazardous substances or

mixture (definition follows Chapter 1.2 of the

UN GHS);

Label element one type of information that has been

harmonised for use in a label, e.g. hazard

pictogram, signal word;

Manufacturer any natural or legal person established within

the Community who manufactures a

substance within the Community;

Manufacturing production or extraction of substances in the

natural state;

Mixture means a mixture or solution composed of two

or more substances. The UN GHS Chapter

1.2 includes the phrase, “in which they do

not react” at the end of an otherwise

identical definition;

Mutagen an agent giving rise to an increased

occurrence of mutations in populations of

cells and /or organisms;

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Organic peroxides liquid or solid organic substances which

contain the bivalent -O-O- structure and may

be considered derivatives of hydrogen

peroxide, where one or both of the hydrogen

atoms have been replaced by organic

radicals. The term organic peroxide includes

organic peroxide mixtures (formulations)

containing at least one organic peroxide

Organic peroxides are thermally unstable

substances or mixtures, which can undergo

exothermic self-accelerating decomposition.

In addition, they can have one or more of the

following properties:

(i) be liable to explosive decomposition;

(ii) burn rapidly;

(iii) be sensitive to impact or friction;

(iv) react dangerously with other substances;

Oxidising gas any gas or gas mixture which may, generally

by providing oxygen, cause or contribute to

the combustion of other material more than

air does;

Oxidising liquid a liquid substance or mixture which, while in

itself not necessarily combustible, may,

generally by yielding oxygen, cause, or

contribute to, the combustion of other

material;

Oxidising solid a solid substance or mixture which, while in

itself not necessarily combustible, may,

generally by yielding oxygen, cause, or

contribute to, the combustion of other

material;

Package the complete product of the packing

operation, consisting of the packaging and its

contents;

Packaging one or more receptacles and any other

components or materials necessary for the

receptacles to perform their containment and

other safety functions;

Placing on the market supplying or making available, whether in

return for payment or free of charge, to a

third party. Import shall be deemed to be

placing on the market;

PPPR Regulation (EC) No 1107/2009 of the

European Parliament and of the Council of 21

October 2009 concerning the placing of plant

protection products on the market and

repealing Council Directives 79/117/EEC and

91/414/EEC;

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Precautionary statement a phrase that describes recommended

measure(s) to minimise or prevent adverse

effects resulting from exposure to a

hazardous substance or mixture due to its

use or disposal;

Product identifier details permitting the identification of the

substance or mixture;

Pyrophoric liquid a liquid substance or mixture which, even in

small quantities, is liable to ignite within five

minutes after coming into contact with air;

Pyrophoric solid a solid substance or mixture which, even in

small quantities, is liable to ignite within five

minutes after coming into contact with air;

Pyrotechnic article an article containing one or more pyrotechnic

substances or mixtures;

Pyrotechnic substance or mixture a substance or mixture of substances

designed to produce an effect by heat, light,

sound, gas or smoke or a combination of

these as the result of non-detonative self-

sustaining exothermic chemical reactions;

REACH or REACH Regulation Regulation (EC) No 1907/2006 concerning

the Registration, Evaluation, Authorisation

and Restriction of Chemicals;

Registrant the manufacturer or the importer of a

substance or the producer or importer of an

article submitting a registration for a

substance under the REACH Regulation;

Reproductive toxicity includes adverse effects on sexual function

and fertility in adult males and females, as

well as developmental toxicity in the

offspring and effects on or via lactation;

Respiratory sensitiser a substance that will lead to hypersensitivity

of the airways following inhalation of the

substance;

SDS safety data sheet;

Self-heating substance or mixture a liquid or solid substance or mixture, other

than a pyrophoric liquid or solid, which, by

reaction with air and without energy supply,

is liable to self-heat; this substance or

mixture differs from a pyrophoric liquid or

solid in that it will ignite only when in large

amounts (kilograms) and after long periods

of time (hours or days);

Self-reactive substances or mixtures thermally unstable liquid or solid substances

or mixtures liable to undergo a strongly

exothermic decomposition even without

participation of oxygen (air). This definition

excludes substances and mixtures classified

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according to the CLP Regulation as

explosives, organic peroxides or as oxidising;

Serious eye damage the production of tissue damage in the eye,

or serious physical decay of vision, following

application of a test substance to the anterior

surface of the eye, which is not fully

reversible within 21 days of application;

Signal word a word that indicates the relative level of

severity of hazards to alert the potential

reader of the hazard; the following two levels

are distinguished:

a) Danger means a signal word indicating the

more severe hazard categories; and

b) Warning means a signal word indicating

the less severe hazard categories;

Skin corrosion the production of irreversible damage to the

skin, namely visible necrosis through the

epidermis and into the dermis, following the

application of a test substance up to 4 hours;

Skin irritation the production of reversible damage to the

skin following the application of a test

substance for up to 4 hours;

Skin sensitiser a substance that will lead to an allergic

response following skin contact;

Specific target organ toxicity specific target organ toxicity, cf. STOT,

STOT-SE and STOT-RE;

STOT-SE specific, non lethal target organ toxicity

arising from a single exposure to a substance

or mixture;

STOT-RE specific, target organ toxicity arising from a

repeated exposure to a substance or

mixture;

Substance a chemical element and its compounds in the

natural state or obtained by any

manufacturing process, including any

additive necessary to preserve its stability

and any identified impurity deriving from the

process used, but excluding any solvent

which may be separated without affecting the

stability of the substance or changing its

composition;

Supplier any manufacturer, importer, downstream

user or distributor placing on the market a

substance, on its own or in a mixture, or a

mixture;

Trade name a designation under which a substance or

mixture is placed on the market;

TWD tactile warnings of danger;

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UFI Unique Formula Identifier;

UN United Nations;

UN RTDG the United Nations Recommendations on the

Transport of Dangerous Goods;

Unstable explosive an explosive substance or mixture which is

thermally unstable and/or too sensitive for

normal handling, transport and use;

Use any processing, formulation, consumption,

storage, keeping, treatment, filling into

containers, transfer from one container to

another, mixing, production of an article or

any other utilisation.

EUROPEAN CHEMICALS AGENCY

ANNANKATU 18, P.O. BOX 400,

FI-00121 HELSINKI, FINLAND

ECHA.EUROPA.EU

Signal word Supplier

identity

Hazard

statements

Trade name Inside

pages

Language

code

Hazard

pictograms

Nominal

quantity

Precautiona

statements

Signal

word in all

languages

of the label

Language

codes

indicating

languages

covered by

the label

Front page

wrapped

around

the

container

Symbol

informing

the user

that the

label can be

opened and

indicating

that the

additional

information

is available

on inside

pages

Product

identifier

including

three

hazardous

components

that

contribute

to the

classificatio

n of the

mixture

Back page

firmly

affixed to

the

immediate

container

UFI code